doiSerbia

Kinetic and isotherm studies for nickel ions’ biosorption by jute fabrics

Ivanovska Aleksandra (University of Belgrade, Innovation Center of the Faculty of Technology and Metallurgy, Belgrade, Serbia), aivanovska@tmf.bg.ac.rs
Pavun Leposava (University of Belgrade, Faculty of Pharmacy, Belgrade, Serbia)
Dojčinović Biljana (University of Belgrade, Institute of Chemistry, Technology and Metallurgy, Belgrade, Serbia)
Kostić Mirjana (University of Belgrade, Faculty of Technology and Metallurgy, Belgrade, Serbiа)

Raw jute fabric was chemically modified with 1 % NaOH for 30 min, 17.5 % NaOH for 5 min or with 0.7 % NaClO2 for 30 and 60 min to study the influence of changes in the chemical composition of the fabrics and quantity of carboxyl groups on the biosorption capacity of the fabrics for nickel ions. The effects of contact time and initial concentration of nickel ions on the biosorption capacity of the fabrics were also investigated. The obtained results revealed that the biosorption of nickel ions can be explained by the pseudo-second- order kinetic model, while the experimental isotherm data fit better with the Langmuir model. The calculated ratios between maximal biosorption capacity (6.30–12.06 mg g-1) of the jute fabrics and carboxyl group quantity indicated that approximately half of the carboxyl groups of the fabrics’ would be involved in binding nickel ions during biosorption. Therefore, the quantity of carboxyl groups can be used to predict the maximal biosorption capacity of jute fabrics toward nickel ions. In the case of oxidized jute fabrics, the lignin removal, and consequently increased content of cellulose and hemicelluloses, also contributed to a higher biosorption capacity.

Keywords: chemical composition, carboxyl groups, hemicelluloses, lignin, pseudo-second-order, Langmuir model

Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. 451-03-9/2021-14/200287 and Grant no. 451-03-9/2021-14/200135