doiSerbia

Influence of diatomite microstructure on its adsorption capacity for Pb(II)

Nenadović S. (Vinca Institute of Nuclear Sciences, Laboratory for Materials Sciences, Belgrade)
Nenadović M. (Vinca Institute of Nuclear Sciences, Laboratory for Atomic Physics, Belgrade)
Kovačević R. (Institute for Mining and Metallurgy, Laboratory for ICP, Bor)
Matović Lj. (Vinca Institute of Nuclear Sciences, Laboratory for Materials Sciences, Belgrade)
Matović B. (Vinca Institute of Nuclear Sciences, Laboratory for Materials Sciences, Belgrade)
Jovanović Z. (Vinca Institute of Nuclear Sciences, Laboratory of Physics, Belgrade)
Novaković-Grbović J. (Vinca Institute of Nuclear Sciences, Belgrade)

The effect of microstructural changes caused by mechanical modification on adsorption properties of diatomite samples were investigated. The microstructure has been characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM) while the degree of metal adsorption was evaluated by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP AES). The results show that metal sorption capacity of diatomite is considerably improved after mechanical modification and it can be attributed to amorphysation of the material. Immobilization efficiency increased from 22% for untreated to 81% for the treated sample after 5h at BPR 4.This qualifies natural diatomite as a material for wastewater remediation.

Keywords: waste water remediation, diatomite, microstrucructure, Ball milling, AFM