In the present study, the weldability, microstructures and mechanical properties of dissimilar welds (2205 austeno-ferritic and 316L austenitic stainless steel) was investigated by using shielded metal arc welding (SMAW) with the help of two different electrodes namely duplex (E2209) and austenitic (E309L). After welding, the microstructure of the different zones of joints was evaluated by using optical microscopy and scanning electron microscopy (SEM), while, the localized chemical information was obtained by energy dispersive spectrometer (EDS) attached to the SEM. In E2209 weld metal, the solidification was observed as the primary ferrite mode. While, 309L weld metal was observed as the primary ferrite with austenitic matrix. Optimum ferrite content was observed in both the electrode. Finally, it was concluded that for the joints between the 2205 austeno-ferritic and 316L austenitic stainless steel, the E2209 electrode was dominant property wise.