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BY-NC-ND 3.0 license Open Access Published by De Gruyter Open Access March 13, 2014

Silica/lignosulfonate hybrid materials: Preparation and characterization

  • Łukasz Klapiszewski EMAIL logo , Jakub Zdarta , Tomasz Szatkowski , Marcin Wysokowski , Magdalena Nowacka , Karolina Szwarc-Rzepka , Przemysław Bartczak , Katarzyna Siwińska-Stefańska , Hermann Ehrlich and Teofil Jesionowski
From the journal Open Chemistry

Abstract

The research reported here concerns the synthesis, characterization and potential applications of silica/lignosulfonate hybrid materials. Three types of silica were used (Aerosil®200, Syloid®244 and hydrated silica), along with magnesium lignosulfonate. The effectiveness of the hybrid material synthesis methodology was confirmed indirectly, using Fourier transform infrared spectroscopy, elemental and colorimetric analysis. Dispersive-morphological analysis indicates that the products with the best properties were obtained using 10 parts by weight of magnesium lignosulfonate per 100 parts of Syloid®244 silica. The relatively high thermal stability recorded for the majority of the synthesized products indicates the potential use of this kind of a material as a polymer filler. Results indicating the high electrokinetic stability of the materials are also of great importance. Additionally, the very good porous structure properties indicate the potential use of silica/lignosulfonate systems as biosorbents of hazardous metal ions and harmful organic compounds.

[1] S.A. Gundersen, J. Sjöblom, Colloid Polym. Sci. 277, 462 (1999) http://dx.doi.org/10.1007/s00396005040910.1007/s003960050409Search in Google Scholar

[2] N. E.E. Mansouri, J. Salvado, Ind. Crop. Prod. 24, 8 (2006) http://dx.doi.org/10.1016/j.indcrop.2005.10.00210.1016/j.indcrop.2005.10.002Search in Google Scholar

[3] A. Aoyama, R. Kurane, K. Nagai, J. Biosci. Bioeng. 115, 279 (2013) http://dx.doi.org/10.1016/j.jbiosc.2012.09.01910.1016/j.jbiosc.2012.09.019Search in Google Scholar

[4] W.O.S. Doherty, P. Mousavioun, C.M. Fellows, Ind. Crop. Prod. 33, 259 (2011) http://dx.doi.org/10.1016/j.indcrop.2010.10.02210.1016/j.indcrop.2010.10.022Search in Google Scholar

[5] J. Rencoret, G. Marques, A. Gutiérrez, L. Nieto, J. Jiménez-Barbero, A.T. Martínez, J.C. del Río, Ind. Crop. Prod. 30, 137 (2009) http://dx.doi.org/10.1016/j.indcrop.2009.03.00410.1016/j.indcrop.2009.03.004Search in Google Scholar

[6] Ł. Klapiszewski, M. Mądrawska, T. Jesionowski, Physicochem. Probl. Miner. Process. 48, 463 (2012) Search in Google Scholar

[7] Ł. Klapiszewski, M. Nowacka, G. Milczarek, T. Jesionowski, Carbohydrate Polym. 94, 345 (2013) http://dx.doi.org/10.1016/j.carbpol.2013.01.05810.1016/j.carbpol.2013.01.058Search in Google Scholar

[8] X. Ouyang, X. Qiu, P. Chen, Colloids Surf. A 282–283, 489 (2006) http://dx.doi.org/10.1016/j.colsurfa.2005.12.02010.1016/j.colsurfa.2005.12.020Search in Google Scholar

[9] S. Brudin, P. Schoenmakers, J. Sep. Sci. 33, 439 (2010) http://dx.doi.org/10.1002/jssc.20090069110.1002/jssc.200900691Search in Google Scholar

[10] A. Rezanowich, D.A.I. Göring, J. Colloid Sci. 15, 452 (1960) http://dx.doi.org/10.1016/0095-8522(60)90049-010.1016/0095-8522(60)90049-0Search in Google Scholar

[11] W.Q. Yean, A. Rezanowich, D.A.I. Göring, Actes du Symposium International de Grenoble, pp. 327–343 (1964) (in French) Search in Google Scholar

[12] D.A.I. Göring, in: K.V. Sarkanen, C.H. Ludwig (Eds.), Polymer properties of lignin and lignin derivatives (Wiley Interscience, New York, 1971) Search in Google Scholar

[13] W.C. Browning, Appl. Polym. Symp. 28, 109 (1975) Search in Google Scholar

[14] J.C. Le Bell, Colloids Surf. 9, 237 (1984) http://dx.doi.org/10.1016/0166-6622(84)80166-310.1016/0166-6622(84)80166-3Search in Google Scholar

[15] B.O. Myrvold, Ind. Crop. Prod. 27, 214 (2008) http://dx.doi.org/10.1016/j.indcrop.2007.07.01010.1016/j.indcrop.2007.07.010Search in Google Scholar

[16] F. Pla, A. Robert, J. Biol. Chem. Phys. Technol. Wood 38, 37 (1984) 10.1515/hfsg.1984.38.1.37Search in Google Scholar

[17] G. Telysheva, T. Dizhbite, E. Paegle, A. Shapatin, I. Demidov, J. Appl. Polym. Sci. 82, 1013 (2001) http://dx.doi.org/10.1002/app.193510.1002/app.1935Search in Google Scholar

[18] M.V. Alonso, M. Oliet, F. Rodriguez, G. Astarloa, J.M. Echeverria, J. Appl. Polym. Sci. 94, 643 (2004) http://dx.doi.org/10.1002/app.2088710.1002/app.20887Search in Google Scholar

[19] C.I. Chiwetelu, V. Hornof, G.H. Neale, A.E. George, Can. J. Chem. Eng. 72, 534 (1994) http://dx.doi.org/10.1002/cjce.545072032010.1002/cjce.5450720320Search in Google Scholar

[20] A. Ansari, M. Pawlik, Miner. Eng. 20, 600 (2007) http://dx.doi.org/10.1016/j.mineng.2006.12.00710.1016/j.mineng.2006.12.007Search in Google Scholar

[21] G. Wypych, Handbook of Fillers (ChemTec Publishing, Toronto, 2010) Search in Google Scholar

[22] W. Stöber, A. Fink, E. Bohn, J. Colloid Interface Sci. 26, 62 (1968) http://dx.doi.org/10.1016/0021-9797(68)90272-510.1016/0021-9797(68)90272-5Search in Google Scholar

[23] I.A.M. Ibrahim, A.A.F. Zikry, M.A. Sharaf, J. Am. Sci. 6, 985 (2010) Search in Google Scholar

[24] J. Żurawska, A. Krysztafkiewicz, T. Jesionowski, J. Chem. Technol. Biotechnol. 78, 534 (2003) http://dx.doi.org/10.1002/jctb.82610.1002/jctb.826Search in Google Scholar

[25] T. Jesionowski, Colloids Surf. A 190, 153 (2001) http://dx.doi.org/10.1016/S0927-7757(01)00675-610.1016/S0927-7757(01)00675-6Search in Google Scholar

[26] T. Jesionowski, J. Mater. Process. Technol. 203, 121 (2008) http://dx.doi.org/10.1016/j.jmatprotec.2007.10.00810.1016/j.jmatprotec.2007.10.008Search in Google Scholar

[27] Y. Qu, Y. Tian, B. Zou, J. Zhang, Y. Zheng, L. Wang, Y. Li, C. Rong, Z. Wang, Bioresource Technol. 101, 8402 (2010) http://dx.doi.org/10.1016/j.biortech.2010.05.06710.1016/j.biortech.2010.05.067Search in Google Scholar

[28] Y. Kajiwara, Y. Chujo, Polym. Bull. 66, 1039 (2011) http://dx.doi.org/10.1007/s00289-010-0337-310.1007/s00289-010-0337-3Search in Google Scholar

[29] I. Hasegawa, Y.S. Fujii, K. Yamada, C. Kariya, T. Takayama, J. Appl. Polym. Sci. 73, 1321 (1999) http://dx.doi.org/10.1002/(SICI)1097-4628(19990815)73:7<1321::AID-APP25>3.0.CO;2-010.1002/(SICI)1097-4628(19990815)73:7<1321::AID-APP25>3.0.CO;2-0Search in Google Scholar

[30] Ł. Klapiszewski, M. Nowacka, K. Szwarc-Rzepka, T. Jesionowski, Physicochem. Probl. Miner. Process. 49, 497 (2013) 10.1155/2013/425726Search in Google Scholar

[31] T. Jesionowski, J. Żurawska, A. Krysztafkiewicz, M. Pokora, D. Waszak, W. Tylus, Appl. Surf. Sci. 205, 212 (2003) http://dx.doi.org/10.1016/S0169-4332(02)01090-510.1016/S0169-4332(02)01090-5Search in Google Scholar

[32] S. Lagergren, K. Sven, Vetenskapsakad. Handl. 24, 1 (1898) (in German) Search in Google Scholar

[33] Y.S. Ho, G. McKay, Process Biochem. 34, 451 (1999) http://dx.doi.org/10.1016/S0032-9592(98)00112-510.1016/S0032-9592(98)00112-5Search in Google Scholar

[34] K. Szwarc-Rzepka, B. Marciniec, T. Jesionowski, Adsorption 19, 483 (2013) http://dx.doi.org/10.1007/s10450-013-9470-210.1007/s10450-013-9470-2Search in Google Scholar

[35] A. Moubarik, N. Grimi, N. Boussetta, A. Pizzi, Ind. Crop. Prod. 45, 296 (2013) http://dx.doi.org/10.1016/j.indcrop.2012.12.04010.1016/j.indcrop.2012.12.040Search in Google Scholar

[36] I. Mohammed-Ziegler, A. Holmgren, W. Forsling, M. Lindberg, M. Ranheimer, Vib. Spectrosc. 36, 65 (2004) http://dx.doi.org/10.1016/j.vibspec.2004.03.00110.1016/j.vibspec.2004.03.001Search in Google Scholar

[37] D.Z. Ye, M.H. Zhang, L. Gan, Q. Li, X. Zhang, Int. J. Biol. Macromol. 60, 77 (2013) http://dx.doi.org/10.1016/j.ijbiomac.2013.05.01610.1016/j.ijbiomac.2013.05.016Search in Google Scholar

[38] R. Zhang, X. Xiao, Q. Tai, H. Huang, J. Yang, Y. Hu, High Perform. Polym. 24, 738 (2012) http://dx.doi.org/10.1177/095400831245147610.1177/0954008312451476Search in Google Scholar

[39] M. Zhou, X. Qiu, D. Yang, H. Lou, J. Dispersion Sci. Technol. 27, 851 (2006) http://dx.doi.org/10.1080/0193269060071916410.1080/01932690600719164Search in Google Scholar

[40] M. Brebu, G. Cazacu, O. Chirila, Cellul. Chem. Technol. 45, 43 (2011) Search in Google Scholar

[41] A. Lemes, M. Soto-Oviedo, W. Waldman, L. Innocentini-Mei, N. Durán, J. Polym. Environ. 18, 250 (2012) http://dx.doi.org/10.1007/s10924-010-0170-710.1007/s10924-010-0170-7Search in Google Scholar

[42] S.K. Srivastava, A.K. Singh, A. Sharma, Environ. Technol. 15, 353 (1994) http://dx.doi.org/10.1080/0959333940938543810.1080/09593339409385438Search in Google Scholar

[43] S. Babel, T.A. Kurniwan, J. Hazard. Mater. 97, 219 (2003) http://dx.doi.org/10.1016/S0304-3894(02)00263-710.1016/S0304-3894(02)00263-7Search in Google Scholar

[44] D. Mohan, C.U. Pittman, P.H. Steele, J. Colloid Interface Sci. 297, 489 (2006) http://dx.doi.org/10.1016/j.jcis.2005.11.02310.1016/j.jcis.2005.11.023Search in Google Scholar PubMed

[45] X. Guo, S. Zhang, X.Q. Shan, J. Hazard. Mater. 151, 134 (2008) http://dx.doi.org/10.1016/j.jhazmat.2007.05.06510.1016/j.jhazmat.2007.05.065Search in Google Scholar PubMed

[46] I. Mohammed-Ziegler, I. Tánczos, Z. Hórvölgyi, B. Agoston, Colloids Surf. A 319, 204 (2008) http://dx.doi.org/10.1016/j.colsurfa.2007.06.06310.1016/j.colsurfa.2007.06.063Search in Google Scholar

Published Online: 2014-3-13
Published in Print: 2014-6-1

© 2014 Versita Warsaw

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