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Eco-Friendly Acetaminophen Sequestration Using Waste Cotton Seeds: Equilibrium, Optimization and Validation Studies

  • Physical Chemistry of Water Treatment Processes
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Abstract

Adsorbent was prepared from waste cotton seeds and utilized to remove acetaminophen from aqueous solutions. The main and interactive effects of five process variables such as, adsorbent dose, initial acetaminophen concentration, contact time, pH and temperature were investigated via response surface methodology based on Box-Behnken statistical design. The optimum values of the selected variables were estimated using Derringer’s desired function. The batch adsorption data obeyed smith isotherm. Kinetic investigation showed that the acetaminophen was chemisorbed on waste cotton seed activated biomass surface following pseudo second order model. The fixed-bed adsorption breakthrough curves at different bed heights were well correlated by BDST model. Exhausted adsorbent could be regenerated eight times efficiently using microwave irradiation.

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References

  1. Adamson, A.W. and Gas, A.P., Physical Chemistry of Surfaces, [16 ed.], New York: Wiley-Interscience, 1997.

    Google Scholar 

  2. Al-Ahmad, A., Daschner, R.D., and Kummerer, K., Arch. Environ. Contam. Toxicol., 1999, vol. 37, pp.158–163.

    Article  CAS  Google Scholar 

  3. Gabrita, I., Ruiz, B., Mestre, A.S., et al., Chem. Eng. J., 2010, vol. 163, pp. 249–255.

    Article  CAS  Google Scholar 

  4. Cunha, C.O., Silva, R.C.R., Amorim, C.G., et al., Electroanalysis, 2010, vol. 22, pp. 2967–2972.

    Article  CAS  Google Scholar 

  5. Daughton, C.G. and Ternes, T.A., Environ. Health. Perspect., 1999, vol. 107, pp. 979–938.

    Article  Google Scholar 

  6. Murray, K.E., Thomas, S.M., and Bodour, A.A., Environ. Pollut., 2010, vol. 158, pp. 3462–3471.

    Article  CAS  Google Scholar 

  7. Ana, S.M., Ricardo, A.P., Ivo, A., et al., Chem. Eng. J., 2014, vol. 253, pp. 408–417

    Article  CAS  Google Scholar 

  8. Sivarajasekar, N., Srileka, S., Samson Arun Prasath, S., and Rabinson, S., Carbon. Lett., 2008, vol. 9, no. 3, pp. 181–187. https://doi.org/10.5714/CL.200008.9.3.181.

    Article  Google Scholar 

  9. Sivarajasekar, N. and Basar, R., J. Chem. and Pharm. Res., 2015, vol. 7, no. 9, pp. 737–748.

    CAS  Google Scholar 

  10. Sivarajasekar, N. Balakrishnan, V., and Baskar, B., Univ. J. Chem. Technol. Metal., 2009, vol. 44, pp. 157–164.

    CAS  Google Scholar 

  11. Karthik, V., Saravanan, K., Sivarajasekar, N., and Suriyanarayanan, N., Ecol. Environ. and Conser., 2016, vol. 22, pp. 423–434

    Google Scholar 

  12. Karthik, V., Saravanan, K., Sivarajasekar, N., and Suriyanarayanan, N., Ecol. Environ. and Conser., 2016b, vol. 22, pp. 435–440.

    Google Scholar 

  13. Sivarajasekar, N., Mohanraj, N., Sivamani, S., and Ganesh Moorthy, I., J. Environ. and Biochnol. Res., 2017, vol. 6, no. 1, pp. 88–95.

    Google Scholar 

  14. Sivarajasekar, N., Paramasivan, T., Muthusaravanan, S. et al., J. Environ. and Biochnol. Res., 2017, vol. 6, no. 1, pp. 186–198.

    Google Scholar 

  15. Sivarajasekar, N., Carbon Lett., 2007, vol. 8, no. 3, pp.199–206, https://doi.org/10.5714/CL.2007.8.3.199.

    Article  Google Scholar 

  16. Sivarajasekar, N. and Baskar, R., Desalin. Water Treat., 2013, vol. 52, no. 40/42, pp. 743–7765, https://doi.org/10.1080/19443994.2013.8345518.

    Google Scholar 

  17. Sivarajasekar, N. and Baskar, R., Chin. J. Chem. Eng., 2015, vol. 23, pp. 1610–1619.

    Article  CAS  Google Scholar 

  18. Sivarajasekar, N. and Baskar, R., J. Ind. Eng. Chem., 2014, vol. 20, pp. 2699–2709.

    Article  CAS  Google Scholar 

  19. Sivarajasekar, N., Baskar, R., Ragu, T., et al., Appl. Water Sci., https://doi.org/10.1007/s13201-016-0379-2.

  20. Lanmuir, I., J. Amer.Chem.Soc., 1918, vol. 40, pp. 1361–1403.

    Article  Google Scholar 

  21. Smith, S.E., J. Amer.Chem.Soc., 1947, vol. 69, pp. 645–651.

    Google Scholar 

  22. Ho, Y.S., Ng, J.C.Y., and McKay, G., Sep. Purif. Method, 2000, vol. 29, pp. 189–232.

    Article  CAS  Google Scholar 

  23. Ho, Y.S., Water Res., 2006, vol. 40, pp. 119–125.

    Article  CAS  Google Scholar 

  24. Sivarajasekar, N. and Baskar, R., Arab. J. Chem, https://doi.org/10.1016/j.aabjc.2014.10.040.

  25. Liu Xing-gao and Ji-xin Qian, Chem. Eng.Technol., 2000, vol. 23, pp. 235–241.

    Article  CAS  Google Scholar 

  26. Mohajeri, L., Aziz, H.A., Isa, M.H., and Zahed, M.A., Biores. Technol., 2010, vol. 101, pp. 893–900.

    Article  CAS  Google Scholar 

  27. Murugesan, K., Dhamija, A., Nam, I.H., et al., Dyes Pigments, 2007, vol. 75, pp. 176–184.

    Article  CAS  Google Scholar 

  28. Sivarajasekar, N., Balasubramani, K., Mohanraj, N., et al., J. Mol. Liq., 2017, https://doi.org/10.1016/j.molliq.2017.06.064.

    Google Scholar 

  29. Prakash Moran J. Priya, B., Naif Abdullah Al-Dhabi, et al, Ultrason. SonoChemm., 2017, vol. 35, pp. 204–209.

    Article  CAS  Google Scholar 

  30. Sivarajasekar, N., Ramasubbu, S., Prakash Moran, J., and Priya, B., Cationic Dyes Sequesration from Aqueous Phase Using Bio-Surfactant Based Reverse Micelles, Book chapter, Recent Advances in Chemical Engineering, 2016, pp. 67–74, https://doi.org/10.1007/978-981-10-1633-2-8.

    Google Scholar 

  31. Sivarajasekar, N., Mohanraji, N., Basar, R., et al., Arab. J. Sci. Eng., https://doi.org/10.1007/s13369-017-2565-4.

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Correspondence to N. Sivarajasekar.

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Sivarajasekar, N., Balasubramani, K., Baskar, R. et al. Eco-Friendly Acetaminophen Sequestration Using Waste Cotton Seeds: Equilibrium, Optimization and Validation Studies. J. Water Chem. Technol. 40, 334–342 (2018). https://doi.org/10.3103/S1063455X18060048

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  • DOI: https://doi.org/10.3103/S1063455X18060048

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