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A study of defects and impurities in doped detonation nanodiamonds by EPR, Raman scattering, and XRD methods

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Abstract

Samples of detonation nanodiamonds modified during the synthesis by adding doping elements in various ways have been studied by spectroscopic methods (electron paramagnetic resonance, Raman scattering, and X-ray diffraction). For the first time, the presence of P1 centers in detonation nanodiamond crystals has been indirectly demonstrated. The authors discuss the nature and distribution of spins as observed by the electron paramagnetic resonance, the composition of phases and size of the coherent scattering region, and crystal density (calculated by the X-ray method) of the detonation nanodiamond samples at hand.

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Authors and Affiliations

  1. Federal State Unitary Enterprise Special Design-Technology Bureau (FSUE SDTB) Tekhnolog, Sovetskii pr., 33a, St. Petersburg, 192076, Russian Federation

    V. Yu. Dolmatov

  2. Belarusian State University, pr. Nezavisimosti, 4, Minsk, 220030, Republic of Belarus

    N. M. Lapchuk, T. M. Lapchuk & B. T. T. Nguyen

  3. Carbodeon Oy. Ltd., Vantaa, Finland

    V. Myllymäki & A. Vehanen

  4. Academician I. P. Pavlov Ryazan State Medical University, ul. Vysokovol’tnaya, 9, Ryazan, 390026, Russian Federation

    R. Yu. Yakovlev

Authors
  1. V. Yu. Dolmatov
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  2. N. M. Lapchuk
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  3. T. M. Lapchuk
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  4. B. T. T. Nguyen
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  5. V. Myllymäki
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  6. A. Vehanen
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  7. R. Yu. Yakovlev
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Correspondence to V. Yu. Dolmatov.

Additional information

Original Russian Text © V.Yu. Dolmatov, N.M. Lapchuk, T.M. Lapchuk, B.T.T. Nguyen, V. Myllymäki, A. Vehanen, R.Yu. Yakovlev, 2016, published in Sverkhtverdye Materialy, 2016, Vol. 38, No. 4, pp. 3–16.

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Dolmatov, V.Y., Lapchuk, N.M., Lapchuk, T.M. et al. A study of defects and impurities in doped detonation nanodiamonds by EPR, Raman scattering, and XRD methods. J. Superhard Mater. 38, 219–229 (2016). https://doi.org/10.3103/S1063457616040018

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  • DOI: https://doi.org/10.3103/S1063457616040018

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