Synthesis and characterization of alkyd resin based on soybean oil and glycerin using zirconium octoate as catalyst

Mohamed E. Elba; Elsayed M. Abdel Rehim; Ramadan E. Ashery

doi:10.32571/ijct.347670

Research Article

Year 2018, Volume: 2 Issue: 1, 34 - 43, 12.05.2018

Mohamed E. Elba Elsayed M. Abdel Rehim Ramadan E. Ashery

https://doi.org/10.32571/ijct.347670

Cited By: 12

Abstract

References

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2. European Coutings Handbook, Brock., T.; Groteklaes, M.; Mischke, P. 2000, 16-85.
3. Erhan, S.Z. .Indnstrial uses of vegetable oil. AOCS publishing, 2005.
4. Tuck, N. Wiley, CV. \sit A ser. Technol. 2000.
5. Gaykar, D.V. Paint India 7. 2001, 55-60.
6. Pramanik, S.; Sagar, K.; Konwar, B.K.; Karak, N. Prog. Org. Coat .2012, 75 (4), 569-578.
7. Turner, G.P.A. Introduction to paint chemistry and principles of paint technology, 3rd ed.; Champman and Hall, London, 1988.
8. Kyenge, B.A.; Anhwange, B.A.; Ageh, J.T.; Igbum, G.O. Int .J. Mod. Org Chem. 2012, 1 (2), 66-71.
9. Solomon, D.H.; Swift, J.D. J. Oil Colour Chem. Assoc. 1966, 49, 915-927.
10. Aydin, S.; Akcay, H.; Evren, O.; Seniha Guner, F.; Tuncer Erciyes, A. Prog. Org. Coats. 2004, 51(4), 273-279.
11. Wholf, R.H. Coconut oil modified alkyd reirns and copolymers There of witl an alkyl acrylate. U.S. Patent 3, 374, 194, Mar. 19, 1968.
12. Wicks, Z.; Jones, F.; Pappas, S.P. Organic Coating Science and Technology. John Wiley & Sons, New York, 1999.
13. Taft Jr, R.W.; Newman, M.S.; Verhoek, F.H. .J. Am. Chem. Soc. 1950, 72, 4511-4519.
15. Lazzari, M.; Chiantore, O. Polym. Degrad. Stabil. 1999, 65 (2), 303-313.
16. Köckritz, A.; Martin, A. Eur. J. Lipid Sci. Tecnol. 2008, 110, 812-824.
17. Warwel, S. Rusch gen Klass, M. Lipid Technol. 1997, 9, 10-14.
18. Dobson, G.; Christie, W.W.; Sebedio, J.L. J. Chromatogr. 1996, 723, 349-354.
19. Asemani, H.R.; Ahmadi, P.; Sarabi, A.A.; Eivaz Mohammadloo, H. Prog. Org. Coat. 2016, 94, 18-27.
20. Singha Mahapatra, S.; Karak, N. Prog. Org. Coat. 2004, 51, 103-108.
21. Deligny, P.K.T.; Tuck, N. Alkyds and polyesters. In Resins for Surface Coatings; Oldring, P.K.T., Ed.; John Wiley & Sons, New York, 2000. Vol 2, p. 15. 22. Sharma, B.; Dolui, S.K.; Sharma, A.K.. J. Sci. Ind. Res.. 2001, 60, 153-158.
23. Privett, O.S. J. Am. Oil Chem. Soc. 1959, 36 (10), 507-512.
24. Porter, N.A.; Wujek, D.G. J. Am. Chem. Soc. 1984, 106 (9), 2626-2629.
25. R usina, A.; Vlcek, A.A. Nature 1965, 206, 295-296.
26. Stenberg, C.; Svensson, M.; Johansson, M. Ind. Crop. Prod. .2005, 21 (2), 263-272.
27. Russell, G.A. J. .Am. Chem. Soc. 1957, 79 (14), 3871-3877.

Synthesis and characterization of alkyd resin based on soybean oil and glycerin using zirconium octoate as catalyst

Year 2018, Volume: 2 Issue: 1, 34 - 43, 12.05.2018

Mohamed E. Elba Elsayed M. Abdel Rehim Ramadan E. Ashery

https://doi.org/10.32571/ijct.347670

Cited By: 12

Abstract

A one
pot synthesis of alkyd resins based on the soybean oil and glycerin with the zirconium octoate (zirconium 2-ethyl
hexanoate) as a new renewable raw material was performed. The alcoholysis
reaction of soybean oil and glycerin carried out in absence of nitrogen gas
inlet in the presence of zirconium octoate. The alkyd resin was obtained from polycondensation
of the alcoholysis products with phthalic anhydrid at 250 °C. The structure
confirmed by FT-IR and H¹-NMR spectroscopy. Flexibility, drying
time, hardness, adhesion test, impact resistance, gloss test and chemical
resistance of synthesized alkyd resins was invesitigated. The prepared resin
was formulated in white lacqure and yellowing resistance
tested with commercial resins.

Keywords

Phthalic anhydride, soybean oil, zirconium ocotate, alkyd resin

References

1. Gandini, A. Green Chem. 2011, 13 (5), 1061-1083.
2. European Coutings Handbook, Brock., T.; Groteklaes, M.; Mischke, P. 2000, 16-85.
3. Erhan, S.Z. .Indnstrial uses of vegetable oil. AOCS publishing, 2005.
4. Tuck, N. Wiley, CV. \sit A ser. Technol. 2000.
5. Gaykar, D.V. Paint India 7. 2001, 55-60.
6. Pramanik, S.; Sagar, K.; Konwar, B.K.; Karak, N. Prog. Org. Coat .2012, 75 (4), 569-578.
7. Turner, G.P.A. Introduction to paint chemistry and principles of paint technology, 3rd ed.; Champman and Hall, London, 1988.
8. Kyenge, B.A.; Anhwange, B.A.; Ageh, J.T.; Igbum, G.O. Int .J. Mod. Org Chem. 2012, 1 (2), 66-71.
9. Solomon, D.H.; Swift, J.D. J. Oil Colour Chem. Assoc. 1966, 49, 915-927.
10. Aydin, S.; Akcay, H.; Evren, O.; Seniha Guner, F.; Tuncer Erciyes, A. Prog. Org. Coats. 2004, 51(4), 273-279.
11. Wholf, R.H. Coconut oil modified alkyd reirns and copolymers There of witl an alkyl acrylate. U.S. Patent 3, 374, 194, Mar. 19, 1968.
12. Wicks, Z.; Jones, F.; Pappas, S.P. Organic Coating Science and Technology. John Wiley & Sons, New York, 1999.
13. Taft Jr, R.W.; Newman, M.S.; Verhoek, F.H. .J. Am. Chem. Soc. 1950, 72, 4511-4519.
15. Lazzari, M.; Chiantore, O. Polym. Degrad. Stabil. 1999, 65 (2), 303-313.
16. Köckritz, A.; Martin, A. Eur. J. Lipid Sci. Tecnol. 2008, 110, 812-824.
17. Warwel, S. Rusch gen Klass, M. Lipid Technol. 1997, 9, 10-14.
18. Dobson, G.; Christie, W.W.; Sebedio, J.L. J. Chromatogr. 1996, 723, 349-354.
19. Asemani, H.R.; Ahmadi, P.; Sarabi, A.A.; Eivaz Mohammadloo, H. Prog. Org. Coat. 2016, 94, 18-27.
20. Singha Mahapatra, S.; Karak, N. Prog. Org. Coat. 2004, 51, 103-108.
21. Deligny, P.K.T.; Tuck, N. Alkyds and polyesters. In Resins for Surface Coatings; Oldring, P.K.T., Ed.; John Wiley & Sons, New York, 2000. Vol 2, p. 15. 22. Sharma, B.; Dolui, S.K.; Sharma, A.K.. J. Sci. Ind. Res.. 2001, 60, 153-158.
23. Privett, O.S. J. Am. Oil Chem. Soc. 1959, 36 (10), 507-512.
24. Porter, N.A.; Wujek, D.G. J. Am. Chem. Soc. 1984, 106 (9), 2626-2629.
25. R usina, A.; Vlcek, A.A. Nature 1965, 206, 295-296.
26. Stenberg, C.; Svensson, M.; Johansson, M. Ind. Crop. Prod. .2005, 21 (2), 263-272.
27. Russell, G.A. J. .Am. Chem. Soc. 1957, 79 (14), 3871-3877.

There are 25 citations in total.

Details

Primary Language	English
Subjects	Chemical Engineering
Journal Section	Research Articles
Authors	Mohamed E. Elba This is me Elsayed M. Abdel Rehim This is me Ramadan E. Ashery
Publication Date	May 12, 2018
Published in Issue	Year 2018 Volume: 2 Issue: 1

Cite

APA	Elba, M. E., Abdel Rehim, E. M., & Ashery, R. E. (2018). Synthesis and characterization of alkyd resin based on soybean oil and glycerin using zirconium octoate as catalyst. International Journal of Chemistry and Technology, 2(1), 34-43. https://doi.org/10.32571/ijct.347670
AMA	Elba ME, Abdel Rehim EM, Ashery RE. Synthesis and characterization of alkyd resin based on soybean oil and glycerin using zirconium octoate as catalyst. Int. J. Chem. Technol. June 2018;2(1):34-43. doi:10.32571/ijct.347670
Chicago	Elba, Mohamed E., Elsayed M. Abdel Rehim, and Ramadan E. Ashery. “Synthesis and Characterization of Alkyd Resin Based on Soybean Oil and Glycerin Using Zirconium Octoate As Catalyst”. International Journal of Chemistry and Technology 2, no. 1 (June 2018): 34-43. https://doi.org/10.32571/ijct.347670.
EndNote	Elba ME, Abdel Rehim EM, Ashery RE (June 1, 2018) Synthesis and characterization of alkyd resin based on soybean oil and glycerin using zirconium octoate as catalyst. International Journal of Chemistry and Technology 2 1 34–43.
IEEE	M. E. Elba, E. M. Abdel Rehim, and R. E. Ashery, “Synthesis and characterization of alkyd resin based on soybean oil and glycerin using zirconium octoate as catalyst”, Int. J. Chem. Technol., vol. 2, no. 1, pp. 34–43, 2018, doi: 10.32571/ijct.347670.
ISNAD	Elba, Mohamed E. et al. “Synthesis and Characterization of Alkyd Resin Based on Soybean Oil and Glycerin Using Zirconium Octoate As Catalyst”. International Journal of Chemistry and Technology 2/1 (June 2018), 34-43. https://doi.org/10.32571/ijct.347670.
JAMA	Elba ME, Abdel Rehim EM, Ashery RE. Synthesis and characterization of alkyd resin based on soybean oil and glycerin using zirconium octoate as catalyst. Int. J. Chem. Technol. 2018;2:34–43.
MLA	Elba, Mohamed E. et al. “Synthesis and Characterization of Alkyd Resin Based on Soybean Oil and Glycerin Using Zirconium Octoate As Catalyst”. International Journal of Chemistry and Technology, vol. 2, no. 1, 2018, pp. 34-43, doi:10.32571/ijct.347670.
Vancouver	Elba ME, Abdel Rehim EM, Ashery RE. Synthesis and characterization of alkyd resin based on soybean oil and glycerin using zirconium octoate as catalyst. Int. J. Chem. Technol. 2018;2(1):34-43.