Abstract
In this study, thin films containing poly(vinyl alcohol) (PVA) and graphene nanoplatelets (GNPs), stabilized with poly(4-styrene-sulfonic acid) (PSS), were assembled by a simple and cost-effective layer-by-layer (LbL) technique in order to introduce the anti-flammability to cotton. These antiflammable layers were characterized by using UV-vis spectrometry and quartz crystal microbalance as a function of the number of bilayers deposited. Scanning electron microscopy was used to visualize the morphology of the thin film coatings on the cotton fabric. The graphene-polymer thin films introduced anti-flammable properties through thermally stable carbonaceous layers at a high temperature. The thermal stability and flame retardant property of graphene-coated cotton was demonstrated by thermogravimetric analysis, cone calorimetry, and vertical flame test. The results indicate that LbL-assembled graphene-polymer thin films can be applied largely in the field of flame retardant.
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References
E. Lecoeur, I. Vroman, S. Bourbigot, T. M. Lam and R. Delobel, Polymer Degradation and Stability 74, 487 (2001).
J. Alongi, F. Carosio, A. Frache and G. Malucelli, Carbohydrate Polymers 92, 114 (2013).
M. Sain, S. H. Park, F. Suhara and S. Law, Polymer Degradation and Stability 83, 363 (2004).
F. Laoutid, L. Bonnaud, M. Alexandre, J-M. Lopez-Cuesta and Ph. Dubois, Materials Science and Engineering: R: Reports 63, 100 (2009).
H. Qin, S. Zhang, C. Zhao, G. Hu and M. Yang, Polymer 46, 8386 (2005).
Å. Bergman et al., Environment International 49, 57 (2012).
M. Rakotomalala, S. Wagner and M. Döring, Materials 3, 4300 (2010).
P. O. Darnerud, Environment International 29, 841 (2003).
M. Ema, S. Fujii, M. Hirata-Koizumi and M. Matsumoto, Reproductive Toxicology 25, 335 (2008).
S. Kemmlein, D. Herzke and R. J. Law, J Chromatography A 1216, 320 (2009).
Q. L. Li, X. L. Wang, D. Y. Wang, Y. Z. Wang, X. N. Feng and G. H. Zheng, J Applied Polymer Science 122, 342 (2011).
H. Lu, L. Song and Y. Hu, Polymers for Advanced Technologies 22, 379 (2011).
H. Pan, Y. Pan, W. Wang, L. Song, Y. Hu and K. M. Liew, Industrial & Engineering Chemistry Research 53, 14315 (2014).
X. Ding et al., Surface and Coatings Technology 305, 184 (2016).
Y. S. Kim, R. Davis, A. A. Cain and J. C. Grunlan, Polymer 52, 2847 (2011).
Y. C. Li et al., ACS Nano 4, 3325 (2010).
F. Carosio, G. Laufer, J. Alongi, G. Camino and J. C. Grunlan, Polymer Degradation and Stability 96, 745 (2011).
G. Laufer, F. Carosio, R. Martinez, G. Camino and J. C. Grunlan, J Colloid and Interface Science 356, 69 (2011).
Y. T. Park et al., Advanced Functional Materials 25, 575 (2015).
G. Decher, Y. Lvov and J. Schmitt, Thin Solid Films 244, 772 (1994).
P. T. Hammond, Advanced Materials 16, 1271 (2004).
M. K. Gheith et al., Advanced Materials 18, 2975 (2006).
Y. T. Park, A. Y. Ham and J. C. Grunlan, J Physical Chemistry C 114, 6325 (2010).
Y. T. Park, A. Y. Ham and J. C. Grunlan, Journal of Materials Chemistry 21, 363 (2011).
Y. T. Park, A. Y. Ham, Y. H. Yang and J. C. Grunlan, RSC Advances 1, 662 (2011).
J. C. Grunlan, J. K. Choi and A. Lin, Biomacromolecules 6, 1149 (2005).
S. Y. Wong et al., Biomacromolecules 13, 719 (2012).
M. A. Priolo, D. Gamboa, K. M. Holder and J. C. Grunlan, Nano Letters 10, 4970 (2010).
Y. H. Yang, M. Haile, A. Malek, Y. T Park and J. C Grunlan, Macromolecules 44, 1450 (2011).
J. J Park, W. J. Hyun, S. C. Mun, Y. T. Park and O. O. Park, ACS Applied Materials & Interfaces 7, 6317 (2015).
M. Zhou and S. Dong, Accounts of Chemical Research 44, 1232 (2011).
P. T. Hammond, Materials Today 15, 196 (2012).
I. J. Chung et al., J Materials Chemistry A 6, 3108 (2018).
S. Seo, S. Lee and Y. T. Park, Review of Scientific Instruments 87, 5 (2016).
G. Laufer, C. Kirkland, A. A. Cain and J. C. Grunlan, ACS Applied Materials and Interfaces 4, 1643 (2012).
F. Carosio, A. Di Blasio, J. Alongi and G. Malucelli, Polymer 54, 5148 (2013).
Y. S. Kim, Y. C. Li, W. M. Pitts, M. Werrel and R. D. Davis, ACS Applied Materials and Interfaces 6, 2146 (2014).
Y. C. Li, Y. S. Kim, J. Shields and R. Davis, J. Materials Chemistry A 1, 12987 (2013).
J. C. Yang, W. Liao, S. B. Deng, Z. J. Cao and Y. Z. Wang, Carbohydrate Polymers 151, 434 (2016).
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Jang, W., Chung, I.J., Kim, J. et al. Improving Fire Resistance of Cotton Fabric through Layer-by-Layer Assembled Graphene Multilayer Nanocoating. J. Korean Phys. Soc. 72, 1052–1057 (2018). https://doi.org/10.3938/jkps.72.1052
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DOI: https://doi.org/10.3938/jkps.72.1052