Ionic Conduction Behavior of CMC Based Green Polymer Electrolytes

M.I.N. Isa; A. S. Samsudin

doi:10.4028/www.scientific.net/AMR.802.194

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 802Ionic Conduction Behavior of CMC Based Green...

Ionic Conduction Behavior of CMC Based Green Polymer Electrolytes

Abstract:

The present work deals with the findings on the ionic conduction behavior based on ethylene carbonate (EC) as plasticizer in carboxymethyl cellulose (CMC) – dodecyltrimethyl ammonium bromide (DTAB) for green polymer electrolytes (GPEs) that were prepared via solution casting technique. The highest ionic conductivity obtained for CMC-DTAB film was 7.72 x 10^-4 S/cm and enhanced to 2.37 x 10^-3 S/cm with addition 10wt. % of EC. The conductivity-temperature of GPEs system obeys the Arrhenius relation where the ionic conductivity increases with temperature. The temperature dependence of the power law exponent for plasticized CMC-DTAB based GPEs system follows the quantum mechanical tunneling (QMT) model for conduction mechanism.

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Periodical:

Advanced Materials Research (Volume 802)

Pages:

194-198

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.802.194

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Online since:

September 2013

Authors:

M.I.N. Isa, A. S. Samsudin

Keywords:

Cellulose Derivative, Green Polymer Electrolytes, Ionic Conductivity

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References

[1] M.M.E. Jacob and A.K. Arof in: B.V.R. Chowdari, S. Chandra, S. Singh, P. C Srivastava (Eds.), Solid State Ionics: Science and Technology, World Scientific, Singapore (1998) p.457.

Google Scholar

[2] A.S. Samsudin, Wan M. Khairul, and M.I.N. Isa, J. Non-Cryst. Solids. 358 (2012) 1104-1112.

Google Scholar

[3] M. Forsyth, P. Meakin and D.R. MacFarlane, J. Mater. Chem. 7 (1997) 193-203.

Google Scholar

[4] N.S. Mohamed, M.Z. Zakaria, A.M.M. Ali and A.K. Arof, J. Power Sources 66 (1997) 169-172.

Google Scholar

[5] A.S. Samsudin and M.I.N. Isa, J. Appl. Sci. 12 (2012) 174-179.

Google Scholar

[6] M.A. Ratner in: J.R. MacCallum, C.A. Vincent (Eds.), Polymer Electrolytes Reviews-1, Elsevier, London, (1987) pp.173-236.

Google Scholar

[7] S. Ramesh and A.K. Arof, Mater. Sci. Eng., B 85 (2001) 11-15.

Google Scholar

[8] A.S. Samsudin and M.I.N. Isa, Int. J. Polym. Mater. 61 (2012) 30-40.

Google Scholar

[9] S.R. Majid and A.K. Arof, Physica B 390 (2007) 209-215.

Google Scholar

[10] B.J. Ingram, M.I. Bertoni, K.R. Poeppelmeier and T.O. Mason, Thin Solid Films 486 (2005) 86-93.

DOI: 10.1016/j.tsf.2004.10.060

Google Scholar

[11] A.M. Farid, H.E. Atyia and N.A. Hegab, Vacuum 80 (2005) 284-294.

Google Scholar