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Synthesis of Indole Derivatives Using Biosynthesized ZnO-CaO Nanoparticles as an Efficient Catalyst

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Abstract:

The principal aim of this research is using biosynthesized ZnO-CaO nanoparticles (NPs) for preparation of indole derivatives. ZnO-CaO NPs have been prepared using Zn(CH3COO)2 and eggshell waste powder in solvent-free conditions. Morphology and structure of NPs were determined by FT-IR, X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and energy dispersive spectra (EDS). It was used as a highly efficient catalyst for the synthesis of indole derivatives. Some indole derivatives were synthesized by the reaction of indole, formaldehyde, aromatic and aliphatic amines in the presence of ZnO-CaO NPs (5 mol%) in ethanol under reflux conditions. The assigned structure was further established by CHN analyses, NMR, and FT-IR spectra. Because of excellent capacity, the exceedingly simple workup and good yield, eco-friendly catalyst ZnO-CaO NPs were proved to be a good catalyst for this reaction.

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Journal of Nano Research Vol. 66 View Preview

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Periodical:

Journal of Nano Research (Volume 66)

Pages:

61-71

DOI:

https://doi.org/10.4028/www.scientific.net/JNanoR.66.61

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Online since:

February 2021

Authors:

Tahereh Heidarzadeh, Navabeh Nami*, Daryoush Zareyee

Keywords:

Eco-Friendly Catalyst, Indole Derivative, Quail Eggshell, ZnO-CaO Nanoparticles

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