Fabrication, Characterization and Photocatalytic Activity of TiO2/Cellulose Composite Aerogel

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Abstract:

nanoTiO2/cellulose composite gels have been uniformly blended during the dissolving process of cellulose in ionic liquids (ILs). After the regeneration process, the obtained hydrogel was finally dried through supercritical CO2 to obtain the TiO2/cellulose composite aerogel. The structure and properties of the composite aerogel were characterized by XRD, SEM, FT-IR, UV-vis, and photocatalytic degradation tests. The porous structure and hydroxyl groups in the regenerated cellulose matrix provided cavities and affinity for the immobilization of TiO2 in the cellulose gels through electrostatic and hydrogen bonding interactions. The TiO2/cellulose composite gels exhibited a good photocatalytic activity for photodegradation of Rhodamine B (RhB) under UV light irradiation. This research highlights another opportunity for the development of the portable and flexible photocatalyst.

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Periodical:

Key Engineering Materials (Volumes 609-610)

Pages:

542-546

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Online since:

April 2014

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* - Corresponding Author

[1] Y. Lu, Q. Sun, D. Yang, X. She, X. Yao, G. Zhu, Y. Liu, H. Zhao, J. Li, Fabrication of mesoporous lignocellulose aerogels from wood via cyclic liquid nitrogen freezing–thawing in ionic liquid solution, J. Mater. Chem. 22 (2012) 13548-13557.

DOI: 10.1039/c2jm31310c

Google Scholar

[2] X. Chen, S. S. Mao, Titanium Dioxide Nanomaterials:  Synthesis, Properties, Modifications, and Applications, Chem. Rev. 107 (2007) 2891-2959.

DOI: 10.1021/cr0500535

Google Scholar

[3] D. Yang, H. Liu, Z. Zheng, Y. Yuan, J. Zhao, E. R. Waclawik, X. Ke, H. Zhu, An Efficient Photocatalyst Structure: TiO2(B) Nanofibers with a Shell of Anatase Nanocrystals, J. Am. Chem. Soc. 131 (2009) 17885-17893.

DOI: 10.1021/ja906774k

Google Scholar

[4] A. Fujishima, K. Honda, Electrochemical photolysis of water at a semiconductor electrode, Nature 238 (1972) 37-38.

DOI: 10.1038/238037a0

Google Scholar

[5] MAB. Barata, MC. Neves, C. Pascoal Neto, T. Trindade, Growth of BiVO4 particles in cellulosic fibres by in situ reaction, Dyes Pigm. 65(2005) 125-127.

DOI: 10.1016/j.dyepig.2004.07.005

Google Scholar

[6] J. Zeng , S. Liu , J. Cai, L. Zhang, TiO2 Immobilized in Cellulose Matrix for Photocatalytic Degradation of Phenol under Weak UV Light Irradiation, J. Phys. Chem. C 114 (2010) 7806–7811.

DOI: 10.1021/jp1005617

Google Scholar