Effect of Titania (TiO2) Addition to Zirconia Toughened Alumina (ZTA) Phases, Hardness and Microstructure

Article Preview

Abstract:

Ceramic composites consist of zirconia toughened alumina (ZTA) with TiO2 as additive was fabricated via solid state sintering route. Numerous studies have indicated that TiO2 can be used as sintering additives for Al2O3 and the ability of microstructural control introduce by TIO2. The Vickers hardness of the obtained ZTA-TiO2 was evaluated as a function of different TiO2 addition. Each sample was dry mixed, uniaxially pressed and sintered at 1600 °C for 4 hours in pressureless condition. It is noticed that the presence of TiO2 greatly influence the microstructure of Al2O3. Al2O3 grains tend to increase in size with more addition of TiO2. Characteristics of Vickers hardness increases increases from 1516.13 HV (0 wt% TiO2) to 1615.8 HV (3 wt% TiO2). Addition of TiO2 also increases the bulk density of ZTA-TiO2 from 3.90 g/cm3 (0 wt% TiO2) to 4.10 g/cm3 (3 wt% TiO2).

You might also be interested in these eBooks

Info:

Periodical:

Pages:

293-298

Citation:

Online since:

February 2015

Export:

Price:

* - Corresponding Author

[1] G. Chen, Y. Zu, J. Luo, X. Fu, W. Zhou, Microstructure and superplastic behavior of TiO2-doped Al2O3–ZrO2 (3Y) composite ceramics, Materials Science and Engineering: A. 554 (2012) 6-11.

DOI: 10.1016/j.msea.2012.05.079

Google Scholar

[2] B. Smuk, M. Szutkowska, J. Walter, Alumina ceramics with partially stabilized zirconia for cutting tools, Journal of Materials Processing Technology. 133 (2003) 195-198.

DOI: 10.1016/s0924-0136(02)00232-7

Google Scholar

[3] A.Z.A. Azhar, M.M. Ratnam, Z.A. Ahmad, Effect of Al2O3/YSZ microstructures on wear and mechanical properties of cutting inserts, Journal of Alloys and Compounds. 478 (2009) 608-614.

DOI: 10.1016/j.jallcom.2008.11.156

Google Scholar

[4] A.Z.A Azhar, L.C. Choong, H. Mohamed, M.M. Ratnam, Z.A. Ahmad, Effects of Cr2O3 addition on the mechanical properties, microstructure and wear performance of zirconia-toughened-alumina (ZTA) cutting inserts, Journal of Alloys and Compounds. 513 (2012) 91-96.

DOI: 10.1016/j.jallcom.2011.09.092

Google Scholar

[5] G. Magnani, A. Brillante, Effect of the composition and sintering process on mechanical properties and residual stresses in zirconia-alumina composites, Journal of the European Ceramic Society. 25 (2005) 3383-3392.

DOI: 10.1016/j.jeurceramsoc.2004.09.025

Google Scholar

[6] B. Basu, J. Vleugels, O.V.D. Biest, Toughness tailoring of yttria-doped zirconia ceramics, Materials Science and Engineering: A. 380 (2004) 215-221.

DOI: 10.1016/j.msea.2004.03.065

Google Scholar

[7] C. Huang, H. Zhu, J. Wang, X. Li, The Effects of MgO Content on the Mechanical Properties and Microstructures of Al2O3-TiN-TiC Ceramic Materials, Advanced Materials Research. 500 (2012) 623-628.

DOI: 10.4028/www.scientific.net/amr.500.623

Google Scholar

[8] A. Rittidech, R. Somrit, T. Tunkasiri, Effect of adding Y2O3 on structural and mechanical properties of Al2O3–ZrO2 ceramics, Ceramics International. 39 (2013) 433-436.

DOI: 10.1016/j.ceramint.2012.10.108

Google Scholar

[9] Y. Zu, G. Chen, X. Fu, K. Luo, C. Wang, S. Song, W. Zhou, Effects of liquid phases on densification of TiO2-doped Al2O3–ZrO2 composite ceramics, Ceramics International. 40 (2014) 3989-3993.

DOI: 10.1016/j.ceramint.2013.08.049

Google Scholar

[10] C.J. Wang, C.Y. Huang, Effect of TiO2 addition on the sintering behavior, hardness and fracture toughness of an ultrafine alumina, Materials Science and Engineering: A. 492 (2008) 306-310.

DOI: 10.1016/j.msea.2008.04.048

Google Scholar