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Study of Thermal Properties of Curing of DGEBA Epoxy Resin with Hexakis-(4-Aminophenoxy)-Cyclotriphosphazene

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Abstract:

Hexakis-(4-aminophenoxy)-cyclotriphosphazene (PN-NH2) was synthesized through nucleophilic substitution of the chloride atoms of hexachlorocyclotriphosphazene (HCCP) and reduction of the nitro group, and its chemical structure was characterized. As a curing agents for commercial epoxy resin Diglycidyl ether of bisphenol-A (DGEBA) PN-NH2 was compared with conventional curing agents 4,4-diaminodiphenylsulfone(DDS) and 4,4-diaminodiphenylmethane (DDM). The thermal properties and thermal degradation behaviors of these thermosetted resins were investigated by using thermogravimetric analysis (TGA). TGA studies demonstrated that the thermal properties of the PN-NH2-containing cured epoxy resin were higher than those of others. The phosphorus-nitrogen containing curing agent can result in a great improvement of the flame retardance for their thermosetted epoxy resins.

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Info:

Periodical:

Advanced Materials Research (Volumes 284-286)

Pages:

365-368

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.284-286.365

Citation:

Cite this paper

Online since:

July 2011

Authors:

Jing Zhu, Yong Wu, Lei Zhao, Hong Liang Wei, Hui Juan Chu, Juan He

Keywords:

Epoxy Resin (ER), Flame Retardance, Phosphazene, Synthesis, Thermal Stablity

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References

[1] A.Hauk, M. Sklorz, G. Bergmann, O. Hutzinger. J Anal Appl Pyrolysis.Vol. 31(2) (1995), p.141

Google Scholar

[2] W. X. Zhang. Eur Polym J. Vol. 40 (2004), p.385

Google Scholar

[3] H. Ren, J.Z. Sun, B.J. Wu, Q.Y. Polym Degrad Stab.Vol. 92 (2007), p.956

Google Scholar

[4] A. Toldy, N. Toth, P. Anna, G. Marosi. Polym Degrad Stab. Vol. 91 (2006), p.585

Google Scholar

[5] S. S. Krishnamurthy, A.C. Sau, M. Woods, editors. Advances in inorganic chemistry and radiochemistry (Academic Press, New York 1978)

Google Scholar

[6] C.W. Allen. Chem Rev. Vol. 91(1991), p.119

Google Scholar

[7] G. F. Levchik, Y.V. Grigoriev, A.I. Balabanovich, S.V. Levchik. Polym Int. Vol . 49 (2000), p.1095

DOI: 10.1002/1097-0126(200010)49:10<1095::aid-pi405>3.0.co;2-b

Google Scholar

[8] S. Chen, Q.K. Zheng, G.D. Ye, G.K. J Appl Polym Sci. Vol. 102(2006), p.698

Google Scholar

[9] Y. Wu, J. Zhu, L. Zhao, Y. Liu.Chemical Research. Vol. 22 (2011), p.31(In Chinese)

Google Scholar

[10] R. Liu, X.D. Wang. P.G. Polym Degrad Stab. Vol. 94 (2009), p.617

Google Scholar

[11] S. W. Zhu, W. F.Shi. Polym Degrad Stab. Vol. 2 (2003), p.217

Google Scholar

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