Electrical Properties of Fresnoite Ba2TiSi2O8 Using Impedance Spectroscopy

Rozana A.M. Osman; Mohd Sobri Idris

doi:10.4028/www.scientific.net/AMR.795.640

Paper Titles

Potential of Upgrading Domestic Biomass into a Higher Energy Density via Torrefaction Process
p.620

Simulated Body Fluid Sorption and Solubility of Silica Reinforced Dental Resin Composites
p.626

The Effect of Different Alkaline Treatment Condition on Flexural Properties of Kenaf Bast-Unsaturated Polyester Composite
p.631

Production of Wollastonite from Local Resources
p.635

Electrical Properties of Fresnoite Ba₂TiSi₂O₈ Using Impedance Spectroscopy
p.640

Characterizations on the Effect of Processing of Polymers Blend with Petroleum Coke (Part I)
p.644

Organic Dye Degradation with TiO₂ Catalyst/AAO Template in the Presence of H₂O₂
p.649

Electrochemical Measurement of PBS Using Cyclic Voltammetry and AAO Fabricated at Ambient Temperature and Low Potential
p.654

Ferroelectric and Relaxor Ferroelectric to Paralectric Transition Based on Lead Magnesium Niobate (PMN) Materials
p.658

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 795Electrical Properties of Fresnoite Ba2TiSi2O8...

Electrical Properties of Fresnoite Ba₂TiSi₂O₈ Using Impedance Spectroscopy

Abstract:

Fresnoite with composition Ba₂TiSi₂O₈(B₂TS₂) was first found in 1965, adopting a non-centrosymmetric structure. It also reported to crystallize in a tetragonal unit cell with a=8.52Å and c=5.210Å leading to some possible application as hydrophone, transducer and second harmonic generation and low temperature co-fired ceramics (LTCC). B₂TS₂ were synthesized by conventional solid state reaction. Phase pure B₂TS₂ was obtained after heating the pellets at a final sintering temperature of 1230 °C in air at 92 h. Study found that Fresnoite B₂TS₂ is a type of materials which are not ferroelectric and instead show perfect dielectric insulator behaviour with resistance >10⁶Ωcm at temperatures below 750°C and also shows nonideal debye respone. The activation energy for conduction of B₂TS₂ samples is very high, indicating that these materials are highly insulating.

You might also be interested in these eBooks

2nd International Conference on Sustainable Materials (ICoSM 2013)

View Preview

Info:

Periodical:

Advanced Materials Research (Volume 795)

Pages:

640-643

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.795.640

Citation:

Cite this paper

Online since:

September 2013

Authors:

Rozana A.M. Osman, Mohd Sobri Idris

Keywords:

Debye Response, Ferroelectric, Fresnoite, Impedance Spectroscopy

Export:

RIS, BibTeX

Price:

Permissions:

Request Permissions

References

[1] P. K. Allen and S. Schmid, in 34th Annual Condensed Matter and Materials Meeting (Australian Institute of Physics, Waiheke Island, Auckland, New Zealand, 2010).

Google Scholar

[2] P. B. Moore and S. J. Louisnathan, The Crystal Structure of fresnoite, Ba2(TiO)Si2O7., Zeitschrift fur Kristallographie,Bd 130, 438-448 (1969).

DOI: 10.1524/zkri.1969.130.1-6.438

Google Scholar

[3] M. Gabelica-Robert and P. Tarte, Vibrational spectrum of fresnoite (Ba2TiOSi2O7) and isostructural compounds., Physics and Chemistry of Minerals 7 (1), 26-30 (1981).

DOI: 10.1007/bf00308197

Google Scholar

[4] S. Haussühl, J. Eckstein, K. Recker and F. Wallrafen, Growth and physical properties of fresnoite Ba2TiSi2O8., Journal of Crystal Growth 40 (2), 200-204 (1977).

DOI: 10.1016/0022-0248(77)90006-9

Google Scholar

[5] S. A. Markgraf, S. K. Sharma and A. S. Bhalla, Raman Study of fresnoite-type materials: Polarized single crystal, crystalline powders, and glasses, Journal Materials Research 8 (3), 635-648 (1993).

DOI: 10.1557/jmr.1993.0635

Google Scholar

[6] M. C. Foster, D. J. Arbogast, R. M. Nielson, P. Photinos and S. C. Abrahams, Fresnoite: A new ferroelectric mineral, Journal of Applied Physics 85 (4), 2299-2303 (1999).

DOI: 10.1063/1.369541

Google Scholar