Paper Titles

The Effect of Different Pretreatment Methods on the Membrane Fouling in the Process of Reverse Osmosis Seawater Desalination
p.1102

Incineration Experiment to Dispose as Hyperaccumulator Pteris vittata L
p.1110

Effect of Acidolysis Process on Viscosity of Cassava Starch
p.1118

Study on One-Step Process of the Size Mixture Blending and Acidolysis Modification of Starch
p.1122

Depolymerization of Lignin with Supercritical Fluids: A Review
p.1126

Key Parameter Function of Wine Cushioning Package of Honeycomb Paper Core
p.1135

Mechanical Properties of Polyvinyl Chloride Composites Reinforced with Magnesium Borate Whiskers
p.1143

Study on the Wear Resistance of Al₂O₃ Particles Reinforced Epoxy Resin Composite Coating
p.1148

The Effect of Spacer Yarn Arrangement on Compression Behaviors of Novel Flexible Foam-Core Sandwich Composites
p.1152

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 821-822Depolymerization of Lignin with Supercritical...

Depolymerization of Lignin with Supercritical Fluids: A Review

Article Preview

Abstract:

Biomass has attracted keen interest as a renewable resource and an environmental friendly material that is essential to realize a sustainable world. Lignin as biomass has been long labeled with waste material. But now the innate chemistry of lignin and a phenolic heteropolymer, has allowed it to make inroads into the high value polymer and natural biomass material industries. Supercritical fluids (SCF) have been shown to be a promising technique for future large-scale biofuel and base-chemicals production, especially for depolymerization production from lignin. This paper reviews the research progress of lignin-depolymerization processes, including effects of process parameters, such as reaction time, temperature, pressure and catalyst, product analysis, and reaction mechanism with different supercritical fluids. The problems of depolymerization with supercritical fluid technology and its development direction are also briefly discussed. Compared with conventional lignin production methods, the SCF technology processes of lignin can produce smaller fragments through breakage of the ether linkages and produce larger fragments through cross linking between the reactive fragments, and the depolymerization lignin processes are typically conducted at mild operating conditions, and the monomeric products have a high economic value because the aromatic products can be readily blended into current transportation fuels or used in chemical industry.

You might also be interested in these eBooks

Advances in Textile Engineering and Materials III

Info:

Periodical:

Advanced Materials Research (Volumes 821-822)

Pages:

1126-1134

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.821-822.1126

Citation:

Cite this paper

Online since:

September 2013

Authors:

Xing Wang, Jing Hui Zhou, Hai Ming Li, Guang Wei Sun

Keywords:

Biofuel, Depolymerization, Lignin, Liquefaction, Supercritical Fluids

Export:

RIS, BibTeX

Price:

Permissions:

Request Permissions

[1] R.E. Smalley: MRS Bull. Vol. 30 (2005), p.412.

[2] W.S.L. Mok, M.J. Antal Jr.: Ind. Eng. Chem. Res. Vol. 31 (1992), p.1157.

[3] H. Ando, T. Sakaki and T. Kokusho: Ind. Eng. Chem. Res. Vol. 39 (2000), p.3688.

[4] T. Sakaki, M. Shibata, T. Miki and H. Hirosue: Energy Fuels. Vol. 10 (1996), p.684.

[5] M.J. Antal Jr., S.G. Allen and D. Schulman: Ind. Eng. Chem. Res. Vol. 39 (2000), p.4040.

[6] M. Sasaki, B.M. Kabyemela and R.M. Malaluan: Supercrit. Fluids. Vol. 13 (1998) , p.280.

[7] Y.Q. Jin, X.M. Ruan and X.S. Cheng: Bioresour. Technol. Vol. 102 (2011) , p.3581.

[8] M. Sasaki, Z. Fang and Y. Fukushima: Ind. Eng. Chem. Res. Vol. 39 (2000), p.2883.

[9] E. Dorrestijn, L.J.J. Laarhoven, I.W.C.E. Arends and P. Mulder: J. Anal. Appl. Pyrolysis. Vol. 54 (2000), p.153.

[10] U. Kües: Wood Production, Wood Technology and Biotechnological Impacts (Micología Aplicada International, Germany 2007).

[11] D. Stewart: Ind. Crops and Prod. Vol. 27 (2008), p.202.

[12] W. Gang, W. Li, B.Q. Li and H.K. Chen: Fuel. Vol. 87 (2008), p.552.

[13] D.S. Wen, H. Jiang, K. Zhang: Sci. Direct. Vol. 19 (2009), p.273.

[14] X.J. Ping, F.C. zheng: Prog. Chem. Vol. (13) 2001, p.94.

[15] J. Tao , H.B. Xing: Prog. Chem. Vol. (18) 2006, p.657.

[16] Z.Z. Qiang: Supercritical Fluid Technology: Principle and Application (Chemical Industry Press, China 2006).

[17] L. Székely: Supercritical Fluid Extraction (Budapest University of Technology and Economics, Magyarul 2007).

[18] L.T. Taylor: Supercritical Fluid Extraction (John Wiley & Sons, USA 1996).

[19] R. Marr, T. Gamse : Chem. Eng. Process. Vol. (39) 2000, p.19.

[20] C. Aymonier, A.L. Serani, H. Reveron, Y. Garrabos and F. Cansell: J. Supercrit. Fluids. Vol. (38) 2006, p.242.

[21] P. Azadia, R. O. Inderwildi, R. Farnood: Renew. Sustain. Energy Rev. Vol. 21 (2013), p.506.

[22] D. K Johnson, H. L Chum, R. Anzick, R. Anzick and M. Baldwin: Thermochem. Biomass Convers. 1988, p.485.

DOI: 10.1007/978-94-009-2737-7_37

[23] T. Funazukuri, N. Wakao and J.M. Smith: Fuel. Vol. 69 (1990), p.349.

[24] T. Yokoyama, H. Kazuhiko and A. Nakajima: Sekiyu Gakkaishi. Vol. 41 (1998), p.243.

[25] K. Barta, T. Matson, M. Fettig and S. Scott: Green Chem. Vol. 12 (2010), p.1640.

[26] H. Pińkowska, P. Wolak and A. ZÍocińska: Chem. Eng. J. Vol. 187 (2012), p.410.

[27] E. Minami, H. Kawamoto and S. Saka: Jpn. Wood Res. Soc. Vol. 49 (2003), p.158.

[28] J. Tsujino, H. Kawamoto and S. Saka: Wood Sci. Technol. Vol. 37 (2003), p.299.

[29] J. Miller, L. Evans, A. Littlewolf, and D. Trudell: Fuel. Vol. 78(1999), p.1363.

[30] S. Cheng, l. D'cruz , M. Wang, M. Leitch and C.B. Xu: Energe Fuel. Vol. 24 (2010), p.4659.

[31] S. Cheng, C. Wilks, Z. Yuan, M. Leitch and C. Xu: Polym. Degrad. Stab. Vol. 97 (2012), p.839.

[32] Z. Yuan, S. Cheng and M. Leitch: Bioresour. Technol. Vol. 101(2010), p.9308.

[33] M. Saisu, T. Sato, M. Watanabe, T. Adschiri and K. Arai: Energy Fuel. Vol. 17 (2003), p.922.

[34] Z. Fang, T. Sato and L. Richard : Bioresour. Technol. Vol. 99 (2008), p.3424.

[35] O. Kazuhide, U. Mitsuo, T. Seiichi and A. Tadafumi: Fuel Process. Technol. Vol. 85 (2004), p.803.

[36] O. Kazuhide, S. Ohara, M. Umetsu, S. Takami and T. Adschiri, Disassembly of Waste Lignin in Supercritical Water and p-Cresol Mixtures, in 14th International Conference on the Properties of Water and Steam, Kyoto, Japan, pp.341-344, (2004).

DOI: 10.1016/j.biortech.2007.03.062

[37] J.A. Gosselink, W. Teunissena, E.G. Dam, E.D. Jong, G. Gellerstedt, E.L. Scott and J.P.M. Sanders: Bioresour. Technol. Vol. 106 (2012), p.173.

[38] E. Adler: Wood Sci. Technol. Vol. 11(1977), p.169.

[39] Z. Tang, Y. Zhang and Q. Guo: Ind. Eng. Chem. Res. Vol. 49(2010), p. (2040).

[40] M. Kleinert, T. Barth: Energy Fuels. Vol. 22(2008), p.1371.

[41] W. Xu, S. Miller and P. Agrawal: Chem. Sus. Chem. Vol. 5(2012), p.667.

[42] K. Barta, T. Matson and M. Fettig: Green Chem. Vol. 12(2010), p.1640.

[43] T. Kleinm, P.S. Virk: Ind. Eng. Chem. Fundam. Vol. 22(1983), p.35.

[44] B.M. John, T.K. Michaelel: Ind. Eng. Chem. Process Des. Dev. Vol. 25(1986), p.885.

[45] F.B. Phillip , K.K. Michelle and A.C. Buchananiii: Energy Fuels. Vol. 21(2007), p.3102.