Properties of Polyurethanes Based on Tall Oil Fatty Acids Ester with Different Types of Flame Retardants

Vladimir Yakushin; Uldis Stirna; Irina Sevastyanova; Dzintra Vilsone; Viesturs Zeltins; Mikelis Kirpluks

doi:10.4028/www.scientific.net/KEM.559.115

Paper Titles

Improvement of Thermal Polyurethane Adhesive Compositions Parameters by Modification with Zeolite
p.81

Compact Representation and Statistical Significance of Measurement Data Reflecting Electric Properties of Polymer Nanocomposites
p.87

Thermal and Mechanical Properties of Unvulcanized Polypropylene Blends with Different Elastomers: Ethylene-Propylene-Diene Terpolymer, Nitrile-Butadiene Copolymer and Chlorinated Polyethylene
p.93

Influence of Сellulose Stearate (CS) Content on Thermal and Rheological Properties of Poly(lactic acid)/CS Composites
p.99

Preparation of Cellulose Stearate and Cellulose Acetate Stearate in 1-Butyl-3-Methylimidazolium Chloride
p.105

Improvement of Paper Hydrophobic Properties by Using Biodegradable Natural Polymer – Chitosan
p.111

Properties of Polyurethanes Based on Tall Oil Fatty Acids Ester with Different Types of Flame Retardants
p.115

Electrochemistry and In Situ EPR Spectroelectrochemistry of Poly(3,4-ethylenedithiothiophene)
p.121

Liquid Crystalline Copolyester Made from Recycled Polyethylene Terephthalate and p-Acetoxybenzoic Acid: Synthesis, Characterization and Blending with Recycled Polyethylene Terephthalate
p.127

HomeKey Engineering MaterialsKey Engineering Materials Vol. 559Properties of Polyurethanes Based on Tall Oil...

Properties of Polyurethanes Based on Tall Oil Fatty Acids Ester with Different Types of Flame Retardants

Abstract:

To decrease the combustibility of polyurethanes based on tall oil fatty acids ester, additives of five different halogen- and phosphorus-containing flame retardants were used. The efficiency of the flame retardants was evaluated from the change in the thermal, mechanical and combustibility characteristics of the obtained polyurethanes. It has been found that the phosphorus-containing flame retardant Levagard 4090 N decreases the combustibility of polyurethane to the greatest extent.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Key Engineering Materials (Volume 559)

Pages:

115-120

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.559.115

Citation:

Cite this paper

Online since:

June 2013

Authors:

Vladimir Yakushin, Uldis Stirna, Irina Sevastyanova, Dzintra Vilsone, Viesturs Zeltins, Mikelis Kirpluks

Keywords:

Fatty Acid, Polyurethane (PU), Property, Reactive Flame Retardants, Tall Oil

Export:

RIS, BibTeX

Price:

Permissions:

Request Permissions

References

[1] F.S. Güner, Y. Yağci, A.T. Erciyes, Polymers from triglyceride oils, Prog. Polym. Sci. 31 (2006) 633-670.

Google Scholar

[2] Z.S. Petrovic, Polyurethanes from vegetable oils, Polym. Rev. 48 (2008) 109-155.

Google Scholar

[3] S.V. Levchik, E.D. Weil, Thermal decomposition, combustion and fire retardancy of polyurethanes – a review on the recent literature, Polym. Int. 53 (2004) 1585-1610.

DOI: 10.1002/pi.1314

Google Scholar

[4] G.E. Zaikov, Flammability of Polymeric Materials, Nova Science Publishers, New York, 1996.

Google Scholar

[5] D.K. Chattopadhyay, K.V.S.N. Raju, Structural engineering of polyurethane coatings for high performance applications, Prog. Polym. Sci. 32 (2007) 352-418.

DOI: 10.1016/j.progpolymsci.2006.05.003

Google Scholar

[6] Ying-Ling Liu, Ging-Ho Hsiue, Chih-Wein Lan et al., Flame-retardant polyurethanes from phosphorus-containing isocyanates, J. Polym. Sci., Part A: Polym. Chem. 35 (1997) 1769-1780.

DOI: 10.1002/(sici)1099-0518(19970715)35:9<1769::aid-pola18>3.0.co;2-3

Google Scholar

[7] Hong-Soo Park, Soon-Yong Kwon, Kum-Jong Seo et al., Preparation and physical properties of polyurethane flame retardant coatings using phosphorus-containing lactone modified polyesters, J. Coat. Technol. 71 No. 899 (1999) 59-65.

DOI: 10.1007/bf02697979

Google Scholar

[8] Seung Jin Kim, Hong Soo Park, Ki Chang Lee et al., Preparation and characterizations of two-component polyurethane flame retardant coatings using bromo modified polyesters, J. Ind. Eng. Chem. 3 (1997) 63-69.

DOI: 10.1007/bf02720169

Google Scholar

[9] K. Pielichowski, D. Slotwinska, Morphological features and flammability of MDI/HMDI-based segmented polyurethanes containing 3-chloro-1,2-propanediol in the main chain, Polym. Degrad. Stab. 80 (2003) 327-331.

DOI: 10.1016/s0141-3910(03)00016-8

Google Scholar

[10] M. Alaee, P. Arias, A. Sjödin, Å. Bergman, An overview of commercially used brominated flame retardants, their applications, their use patterns in different countries/regions and possible modes of release, Environ. Int. 29 (2003) 683-689.

DOI: 10.1016/s0160-4120(03)00121-1

Google Scholar

[11] D.K. Chattopadhyay, D.C. Webster, Thermal stability and flame retardancy of polyurethanes, Prog. Polym. Sci. 34 (2009) 1068-1133.

DOI: 10.1016/j.progpolymsci.2009.06.002

Google Scholar

[12] I. Javni, Z.S. Petrovic, A. Guo, R. Fuller, Thermal stability of polyurethanes based on vegetable oils, J. Appl. Polym. Sci. 77 (2000) 1723-1734.

DOI: 10.1002/1097-4628(20000822)77:8<1723::aid-app9>3.0.co;2-k

Google Scholar