Synthesis of Nanocrystalline LaFeO3 by Precipitation and its Visible-Light Photocatalytic Activity

Article Preview

Abstract:

The LaFeO3 nanoparticle was synthesized using Fe(NO3)3 and La(NO3)3 as starting materials by homogeneous precipitation method. The as-prepared LaFeO3 product was characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM) and UV-visible diffuse reflectance spectroscopy (DRS). XRD and SEM demonstrate the successful synthesis of single phase perovskite LaFeO3 and with 60-80 nm particle size. It was found that the as-prepared LaFeO3 shows strong visible-light absorption with absorption onset of 532 nm, indicating a narrow optical band gap of 2.33 eV. Furthermore, the as-prepared LaFeO3 shows high visible-light photocatalytic activity for decomposition of methylene blue in comparison with the commercial Degussa P25.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

150-154

Citation:

Online since:

July 2011

Export:

Price:

[1] X. Chen, S. Shen and L. Guo et al: Chem. Rev. Vol. 110 (2010), pp.6503-6570.

Google Scholar

[2] M.R. Hoffmann, S.T. Martin and W. Choi et al: Chem. Rev. Vol. 95 (1995), pp.69-96.

Google Scholar

[3] C. Hu, X. Hu, J. Guo and J. Qu: Environ. Sci. Technol. Vol. 40 (2006), pp.5508-5513.

Google Scholar

[4] Y. H. Ng, I. V. Lightcap and K. Goodwin et al: J. Phys. Chem. Lett. Vol. 1(2010), pp.2222-2227.

Google Scholar

[5] S. Sakthivel and H. Kisch: Angew. Chem. Int. Ed. Vol. 42(2003), pp.4908-4911.

Google Scholar

[6] R. Asahi, T. Morikawa and T. Ohwaki et al: Science Vol. 293 (2001), pp.269-275.

Google Scholar

[7] E. Reisner, D. J. Powell and C. Cavazza et al: J. Am. Chem. Soc. Vol. 131 (2009), pp.18457-18466.

Google Scholar

[8] S.U.M. Khan, M. Al-Shahry and W. B: Science Vol. 297 (2002), pp.2243-2245.

Google Scholar

[9] X. Yang, C. Cao and K. Hohn et al: J. Catal. Vol. 252(2007), pp.296-302.

Google Scholar

[10] J. Gole, J. Stout and C. Burda et al: J. Phys. Chem. B Vol. 108(2004), pp.1230-1240.

Google Scholar

[11] J. Tang, Z. Zou and M. Katagiri et al: Catal. Today Vol. 93-95(2004), pp.885-889.

Google Scholar

[12] J. Yu, Y. Zhang and A. Kudo et al: J. Solid State Chem. Vol. 182 (2009), pp.223-228.

Google Scholar

[13] P. Tang, H. Chen and F. Cao et al: Mater. Lett. Vol. 65(2011), pp.450-452.

Google Scholar

[14] H. J. Su, L. Q. Jing and K. Y. Shi: J. Nanopart. Res. Vol. 12(2010), pp.967-974.

Google Scholar

[15] P. V. Gosavi and R. B. Biniwale: Mater. Chem. Phys. Vol. 119 (2010), pp.324-329.

Google Scholar