CuZr Based Shape Memory Alloys: Effect of Cr and Co on the Martensitic Transformation

Article Preview

Abstract:

In the present work an investigation on CuZr based shape memory alloys was proposed. In particular, this study has been addressed the effect of the addition of Cr and Co on the martensitic transformation behaviour. The characterization was performed using DSC in terms of evolution of characteristic temperatures. The analysis of the proposed alloys was completed with the evaluation of the microhardness and the microstructure, observed by means of a scanning electron. Moreover, X-rays diffraction analysis was also carried out to check the crystal structures in the different alloys. It was shown how the addition of Co can improve thermal stability and the thermal hysteresis of the martensitic transformation by the first thermal cycles, even if the characteristic temperatures were significantly decreased.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 738-739)

Pages:

167-171

Citation:

Online since:

January 2013

Export:

Price:

[1] J. Ma, I. Karaman, R.D. Noebe, High temperature shape memory alloys, International Materials Reviews 55 (2010) 257-315.

DOI: 10.1179/095066010x12646898728363

Google Scholar

[2] G.S. Firstov, J. Van Humbeeck, Yu.N. Koval, High-temperature shape memory alloys: some recent developments, Materials Science and Engineering A378 (2004) 2-10.

DOI: 10.1016/j.msea.2003.10.324

Google Scholar

[3] J. Saida, M. Matsushita, A. Inoue, Nano icosahedral quasicrystals in Zr-based glassy alloys, Intermetallics 10 (2002) 1089-1098.

DOI: 10.1016/s0966-9795(02)00142-5

Google Scholar

[4] Y. Wu, h. Wang, H.H. Wu, Z.Y. Zhang, X.D. Hui, G.L. Chen, d. Ma, X.L. Wang, Z.P. Lu, Formation of Cu-Zr-Al bulk metallic glass composites with improved tensile properties, Acta Materialia 59 (2011) 2928-2936.

DOI: 10.1016/j.actamat.2011.01.029

Google Scholar

[5] D. Xu, B. Lohwongwatana, G. Duan, W.L. Johnson, C. Garland, Bulk metallic glass formation in binary Cu-rich alloy series-Cu100-xZrx (x=34, 36, 38. 2, 40 at. %) and mechanical properties of bulk Cu64Zr36 glass, Acta Materialia 52 (2004) 2621-2624.

DOI: 10.1016/j.actamat.2004.02.009

Google Scholar

[6] G.S. Firstov, J. Van Humbeeck, Yu.N. Koval, Pecularities of the martensitic transformation in ZrCu intermetallic compound-potential high temperature SMA, Journal De Physique IV France 11 (2001) 481-486.

DOI: 10.1051/jp4:2001880

Google Scholar

[7] G.S. Firstov, A.N. Timoshevskii, Yu.N. Koval, S. Kalkuta and J. Van Humbeeck, Phase stability during martensitic transformation in ZrCu intermetallics: crystal and electronic structure aspects, Proc. Of ESOMAT (2009).

DOI: 10.1051/esomat/200902008

Google Scholar

[8] F. Qiu, H. Wang, T. Liu, Q. Jiang, Influence of Al content on the microstructure and mechanical property of the (Zr2Cu)100-xAlx alloys, Journal of Alloys and Compounds 468 (2009) 195-199.

DOI: 10.1016/j.jallcom.2008.01.081

Google Scholar

[9] F. Qiu, P. Shen, T. Liu, Q. Li, Q. Jiang, Electronic structure and phase stability during martensitic transformation in Al-doped ZrCu intermetallics, Journal of Alloys and Compounds 491 (2010) 354-358.

DOI: 10.1016/j.jallcom.2009.10.182

Google Scholar

[10] G.S. Firstov, Y.N. Koval, J. Van humbeeck, R. Portier, P. Vermaut, P. Ochin, Phase transformations in Zr-29. 56 at. % Cu-19. 85 at. % Ni melt-spun high-temperature shape memory alloy, Materials Science and Engineering A 438-440 (2006) 816-820.

DOI: 10.1016/j.msea.2006.02.203

Google Scholar

[11] F.Q. Meng, K. Tsuchiya, F.X. Yin, S. Ii , Y. Yokoyama, Influence of Al content on martensitic transformation behavior in Zr50Cu50−xAlx, Journal of Alloys and Compounds 522 (2012) 136– 140.

DOI: 10.1016/j.jallcom.2012.01.125

Google Scholar

[12] F. Meng, K. Tsuchiya, S. Ii, Y. Yokoyama, Influence of Ni on stability of martensitic transformation in Zr50Cu50−xNix, Journal of Alloys and Compounds (2012) IN-PRESS.

DOI: 10.1016/j.jallcom.2012.01.089

Google Scholar

[13] Thaddeus B. Massalski, Binary alloy phase diagram, Second Edition, Vol. 2 (1990).

Google Scholar

[14] Z.Y. Liu, M Aindow, J.A. Hriljac, I.P. Jones, I.R. Harris, Microstructural characteristics of the eutectoid mixture Zr2Cu and Zr7Cu10, Journal of Materials Science Letters 20 (2001) 543-545.

DOI: 10.1023/a:1010932601393

Google Scholar