Synthesis and Characterization of Nanocrystalline M-Mg-O and Carbon-Coated MgO Systems

Timofey Karnaukhov; Aleksey A. Vedyagin; Ilya V. Mishakov; Alexander Bedilo; Alexander M. Volodin

doi:10.4028/www.scientific.net/MSF.917.157

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HomeMaterials Science ForumMaterials Science Forum Vol. 917Synthesis and Characterization of Nanocrystalline...

Synthesis and Characterization of Nanocrystalline M-Mg-O and Carbon-Coated MgO Systems

Abstract:

Two different approaches to modify the structure and reaction ability of nanocrystalline MgO have been discussed. In the first case, a series of two-component x%MO_x–MgO systems (M = Fe, Co and Ni, x = 1–45 wt.%) was synthesized via sol–gel technique. Aqueous solution of inorganic salt precursor was used as a hydrolyzing agent. Samples obtained were characterized by number of physicochemical methods (differential thermal analysis, X-ray diffraction analysis, low-temperature adsorption, etc.). It was shown that presence of inorganic salt in magnesium hydroxide matrix shifts the temperature of decomposition of latter towards lower values. Structural and textural characteristics of MgO-based oxide systems were found to be strongly affected by the presence of additive and their concentration. Formation of joint phase was observed in the case of cobalt oxide only. Second way of MgO modification was represented by creating a controlled carbon coating over its surface via decomposition of C₄H₁₀ at 400 °C. The obtained x%C/MgO (x = 1–10 wt.%) samples were shown to possess the improved reaction ability in destruction sorption of CF₂Cl₂ as well as in catalytic dehydrochlorination of 1-chlorobutane in presence of water vapors.

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Materials Science Forum (Volume 917)

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157-161

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.917.157

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Online since:

March 2018

Authors:

Timofey Karnaukhov, Aleksey A. Vedyagin*, Ilya V. Mishakov, Alexander Bedilo, Alexander M. Volodin

Keywords:

Carbon Coating, Destructive Sorption, Halogenated Hydrocarbons, Nanocrystalline Magnesium Oxide, Sol-Gel Technique, Two-Component Oxides

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References

[1] K.J. Klabunde, J.V. Stark, O. B. Koper, C. Mohs, D.G. Park, S. Decker, Y. Jiang, I. Lagadic and D. Zhang: J. Phys. Chem. Vol. 100 (1996), p.12142.

DOI: 10.1021/jp960224x

Google Scholar

[2] I.V. Mishakov, A.F. Bedilo, R.M. Richards, V.V. Chesnokov, A.M. Volodin, V.I. Zaikovskii, R.A. Buyanov and K.J. Klabunde: J. Catal. Vol. 206 (2002), p.40.

DOI: 10.1006/jcat.2001.3474

Google Scholar

[3] Y. Jiang, S. Decker, C. Mohs and K.J. Klabunde: J. Catal. Vol. 180 (1998), p.24.

Google Scholar

[4] P.P. Gupta, K.L. Hohn, L.E. Erickson, K.J. Klabunde, and A.F. Bedilo: AlChE J., Vol. 50 (2004), p.3195.

Google Scholar

[5] I.V. Mishakov, V.I. Zaikovskii, D.S. Heroux, A.F. Bedilo, V.V. Chesnokov, A.M. Volodin, I.N. Martyanov, S.V. Filimonova, V.N. Parmon and K.J. Klabunde: J. Phys. Chem. B Vol. 109 (2005), p.6982.

DOI: 10.1021/jp047847s

Google Scholar

[6] I.V. Mishakov, A.A. Vedyagin, A.F. Bedilo, V. I Zaikovskii and K.J. Klabunde: Catal. Today Vol. 144 (2009), p.278.

DOI: 10.1016/j.cattod.2009.01.018

Google Scholar

[7] E.V. Ilyina, I.V. Mishakov, A.A. Vedyagin, A.F. Bedilo and K.J. Klabunde: Micropor. Mesopor. Mater. Vol. 175 (2013), p.76.

Google Scholar

[8] A.A. Vedyagin, A.F. Bedilo, I.V. Mishakov, E.I. Shuvarakova: J. Serbian Chem. Soc. Vol. 82 (2017), p.523.

DOI: 10.2298/jsc161020037v

Google Scholar

[9] A.F. Bedilo, E.I. Shuvarakova, A.M. Volodin, E.V. Ilyina, I.V. Mishakov, A.A. Vedyagin, V.V. Chesnokov, D.S. Heroux, K.J. Klabunde: J. Phys. Chem. C Vol. 118 (2014), p.13715.

DOI: 10.1021/jp503916e

Google Scholar

[10] A.A. Vedyagin, I.V. Mishakov, T.M. Karnaukhov, E.F. Krivoshapkina, E.V. Ilyina, T.A. Maksimova, S.V. Cherepanova, P.V. Krivoshapkin: J. Sol-Gel Sci. Technol. Vol. 82. (2017) p.611.

DOI: 10.1007/s10971-017-4321-3

Google Scholar