Physical and Structural Properties of Dysprosium Doped Barium Borate Glass

Article Preview

Abstract:

Five distinguish glass samples were prepared by melt quenching technique of the composition (81-x)H3BO3-19BaCO3-xDy2O3 with x = 0, 0.2, 0.4, 0.6 and 0.8 mol%. The effect of Dy3+ to the barium borate glass can be investigated in terms of their physical properties such as density, molar volume and oxygen packing density. The structural properties were analyzed by X-Ray Diffraction (XRD) technique and Fourier Transform Infrared Spectroscopy (FTIR). The result revealed that the increment of mol% of Dy3+ in the compound generally will increases the density and molar volume of the glass samples. The amorphous nature of the glass system was verified from the XRD spectra pattern. Meanwhile, the FTIR spectra shown the presence of Ba2+, BO3, BO4, B-O-B linkage, H-O-H and isolated borate in the glass network.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volume 290)

Pages:

46-52

Citation:

Online since:

April 2019

Export:

Price:

* - Corresponding Author

[1] M. Veeramohan Rao, B. Shanmugavelu and V.V Ravi Kanth Kumar, (2017). Optical absorption and photoluminescence studies of Dy3+ doped alkaline earth bismuth borate glasses. Journal of Luminescence, 181, 291-298.

DOI: 10.1016/j.jlumin.2016.09.012

Google Scholar

[2] Kirti Nanda, Neelam Berwal, R.S. Kundu, R. Punia and N. Kishore, (2015). Effect of doping of Nd3+ ions in BaO-TeO2-B2O3 glasses: A vibrational and optical study. Journal of Molecular Structure, 1088, 147-154.

DOI: 10.1016/j.molstruc.2015.02.021

Google Scholar

[3] S.N.C. Santos, J.M.P. Almeida, K.T. Paula, N.B. Tomazio, V.R. Mastelaro and C.R. Mendonça, (2017). Characterization of the third-order optical nonlinearity spectrum of barium borate glasses. Optical Materials, 73, 16-19.

DOI: 10.1016/j.optmat.2017.06.060

Google Scholar

[4] P.P Pawar, S.R. Munishwar, S. Gautam and R.S. Gedam, (2017). Physical, thermal, structural and optical properties of Dy3+ doped lithium alumino-borate glasses for bright W-LED. Journal of Luminescence, 183, 79-88.

DOI: 10.1016/j.jlumin.2016.11.027

Google Scholar

[5] M.A. Marzouk, F.H. ElBatal and H.A. ElBatal, (2016). Effect of TiO2 on the optical, structural and crystallization behavior of barium borate glasses. Optical Materials, 57, 14-22.

DOI: 10.1016/j.optmat.2016.04.002

Google Scholar

[6] P. Karthikeyan, R. Vijayakumar and K. Marimuthu, (2017). Luminescence studies on Dy3+ doped calcium boro-tellurite glasses for White light applications. Physica B, 521, 347-354.

DOI: 10.1016/j.physb.2017.07.018

Google Scholar

[7] P.P. Pawar, S.R. Munishwar and R.S. Gedam, (2016). Physical and optical properties of Dy3+/Pr3+ Co-doped lithium borate glasses for W-LED. Journal of Alloys and Compounds, 660, 347-355.

DOI: 10.1016/j.jallcom.2015.11.087

Google Scholar

[8] Lokesh Mishra, Anchal Sharma, Amit K. Vishwakarma, Kaushal Jha, M. Jayasimhadri, B.V. Ratnam, Kiwan Jang, A.S. Rao and R.K. Sinha, (2016). White light emission and color tunability of dysprosium doped barium silicate glasses. Journal of Luminescence, 169,121-127.

DOI: 10.1016/j.jlumin.2015.08.063

Google Scholar

[9] Lakhwant, S., Vanitha, T., Punia, R., Kundu, R.S. and Anupinder, S., (2014). Structural and optical properties of barium titanate modified bismuth borate glasses. Journal of Solid State Sciences, 37, 64-71.

DOI: 10.1016/j.solidstatesciences.2014.08.010

Google Scholar

[10] Farag, M.A., Abd-Allah, K., Turky, G. and Alokr, M.M., (2015). Optical and Upconversion properties of Nd3+ doped lead borate barium glass system. Nature and Science, 13(5),123 129.

Google Scholar

[11] Meena, S.L., (2017). Polarizability and Optical Basicity of Dy3+ Ions Doped Yttrium Zinc Lithium Bismuth Borate Glasses. Journal of Pure Applied and Industrial Physics, 7(8),310-318.

DOI: 10.29055/jpaip/285

Google Scholar

[12] Gautam, C.R. and Avadhesh, K.Y., (2013). Synthesis and optical investigations on (Ba,Sr)TiO3 borosilicate glasses doped with La2O3. Journal of Optics and Photonics, 3, 1-7.

Google Scholar

[13] Karunakaran, R.T., Marimuthu, K., Surendra Babu, S. and Arumugam, S., (2009). Sturctural, optical and thermal studies of Eu3+ ions in lithium fluoroborate glasses. Journal of Solid State Sciences, 11, 1882-1889.

DOI: 10.1016/j.solidstatesciences.2009.08.001

Google Scholar

[14] Abdelghany, A.M. and Ahmed H.H., (2015). Impact of vanadium ions in barium borate glass. Journal of Spectrochimia Acta Part A: Molecular and Biomolecular Spectroscopy, 137, 39-44.

DOI: 10.1016/j.saa.2014.08.012

Google Scholar

[15] P. Kaur, S. Kaur, G.P. Singh, D.P. Singh.,(2014). Cerium and samarium codoped lithium aluminoborate glasses for white light emitting devices. J. Alloy. Compd, 588,394–398.

DOI: 10.1016/j.jallcom.2013.10.181

Google Scholar

[16] Vijayakumar, R., Nagaraj, R., Suthanthirakumar, P., Karthikeyan, P., and Marimuthu, K. (2018). Silver (Ag) nanoparticles enhanced luminescence properties of Dy3+ ions in borotellurite glasses for white light applications. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 204, 537-547.

DOI: 10.1016/j.saa.2018.06.092

Google Scholar

[17] Sindhu, S., Sanghi, S., Agarwal, A., Seth, V. P., and Kishore, N. (2005). The role of V2O5 in the modification of structural, optical and electrical properties of vanadium barium borate glasses. Physica B: Condensed Matter, 365(1-4), 65-75.

DOI: 10.1016/j.physb.2005.04.037

Google Scholar