Electrochemistry
Online ISSN : 2186-2451
Print ISSN : 1344-3542
ISSN-L : 1344-3542
Articles
Supercapacitor Using an Electrolyte Charge Storage System
Masamitsu TACHIBANATakahiro OHISHIYasuhiro TSUKADAAki KITAJIMAHideo YAMAGISHIMutsuaki MURAKAMI
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2011 Volume 79 Issue 11 Pages 882-886

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Abstract

The combination of an electric double-layer capacitor (EDLC) and an “electrolyte charge storage system”, which is a completely novel charge storage method, was investigated. We screened p-type and n-type active materials and selected acetylferrocene for the former and 1, 1’-diheptyl-bipyridinium bis (tetrafluoroborate) for the latter. As a result, our capacitor effectively used the redox reactions of active materials dissolved in the electrolyte to increase its charge capacity. Self-discharge caused by the shuttle effect of active materials was almost suppressed using an anion-exchange membrane separator.

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© 2011 The Electrochemical Society of Japan
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