Abstract
In this study, we report some improvements in a hydrothermal method for lead-free piezoelectric powders and the performance of the sintered (K0.48Na0.52)NbO3 ceramics. To increase the obtained powder weight per source solution volume, the hydrothermal reaction conditions were modified. This improvement is important for mass production; however, it resulted in a larger particle size dispersion. Therefore, we examined to introduced the ball milling process that is useful for dense (K0.48Na0.52)NbO3 ceramics. When a large amount of powder was obtained, it took a long time to eliminate the residual alkaline ions in the hydrothermal powders by a washing process. Therefore, a neutralization was conducted in the powder washing process. Using this powder, a solid solution of (K,Na)NbO3 ceramics was synthesized. The relative density was successfully increased. Concerning the electrical properties, the relative permittivity was improved, and the piezoelectric constant d33 was also increased from 114 to 130 pC/N.