Skip to main content
Log in

The relaxation of a double-well energy

  • Published:
Continuum Mechanics and Thermodynamics Aims and scope Submit manuscript

Abstract

This paper studies coherent, energy-minimizing mixtures of two linearly elastic phases with identical elastic moduli. We derive a formula for the “relaxed” or “macroscopic” energy of the system, by identifying microstructures that minimize the total energy when the volume fractions and the average strain are fixed. If the stress-free strains of the two phases are incompatible then the relaxed energy is nonconvex, with “double-well structure”. An optimal microstructure always exists within the class of layered mixtures. The optimal microstructure is generally not unique, however; we show how to construct a large family of optimal, sequentially laminated microstructures in many circumstances. Our analysis provides a link between the work of Khachaturyan and Roitburd in the metallurgical literature and that of Ball, James, Pipkin, Lurie, and Cherkaev in the recent mathematical literature. We close by explaining why the corresponding problem for three or more phases is fundamentally more difficult.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Acerbi, E.; Fusco, N.: Semicontinuity problems in the calculus of variations. Arch. Rat. Mech. Anal. 86 (1984) 125–145

    Google Scholar 

  2. Allaire, G.; Kohn, R.: Optimal bounds on the effective behavior of a mixture of two well-ordered elastic materials, preprint.

  3. Avellaneda, M.: Iterated homogenization, differential effective medium theory, and applications. Comm. Pure Appl. Math. 40 (1987) 527–554

    Google Scholar 

  4. Avellaneda, M.: Optimal bounds and microgeometries for elastic two-phase composites. SIAM Journal Appl. Math. 47 (1987) 1216–1228

    Google Scholar 

  5. Avellaneda, M.; Cherkaev, A. V.; Lurie, K. A.; Milton, G. W.: On the effective conductivity of polycrystals and a three-dimensional phase-interchange inequality. J. Appl. Phys. 63 (1988) 4989–5003

    Google Scholar 

  6. Avellaneda, M.; Milton, G. W.: Bounds on the effective elasticity tensor of composites based on two-point correlations, in Proc. ASME Energy-Technology Conference and Exposition, D. Hui and T. Koszic, ed., ASME (1989)

  7. Ball, J. M.; Murat, F.:W 1,p-quasiconvexity and variational problems for multiple integrals. Journal Funct. Anal. 58 (1984) 225–253

    Google Scholar 

  8. Ball, J. M.; James, R. D.: Fine phase mixtures as minimizers of energy. Arch. Rat. Mech. Anal. 100 (1987) 13–52

    Google Scholar 

  9. Ball, J. M.; James, R. D.: Proposed experimental tests of a theory of fine microstructure and the two well problem, to appear

  10. Bhattacharya, K.; Firoozye, N; James, R.; Kohn, R.: in preparation

  11. Cahn, J. W.; Larche, F.: A simple model for coherent equilibrium. Acta Metall. 32 (1984) 1915–1923

    Google Scholar 

  12. Chipot, M.; Kinderlehrer, D.: Equilibrium configurations of crystals. Arch. Rat. Mech. Anal. 103 (1988) 237–277

    Google Scholar 

  13. Collins, C.; Luskin, M.: The computation of the austenitic-martensitic phase transition. in Lecture Notes in Physics 344, M. Rascle et al. eds., Berlin: Springer-Verlag 1989, 34–50

    Google Scholar 

  14. Collins, C.; Luskin, M.: Optimal order error estimates for the finite element approximation of the solution of a nonconvex variational problem, preprint

  15. Dacorogna, B.: Quasiconvexity and relaxation of nonconvex variational problems. Journal Funct. Anal. 46 (1982) 102–118

    Google Scholar 

  16. Dacorogna, B.: Remarques sur les notions de polyconvexite, quasiconvexite, et convexite de rang 1. J. Math. Pures Appl. 64 (1985) 403–438

    Google Scholar 

  17. Dacorogna, B.: Direct Methods in the Calculus of Variations. Berlin: Springer-Verlag, 1989

    Google Scholar 

  18. Ericksen, J. L.: The Cauchy and Born hypotheses for crystals, in Phase Transformations and Material Instabilities in Solids, M. Gurtin, ed., Academic Press (1984) 61–78

  19. Ericksen, J. L.: Constitutive theory for some constrained elastic crystals. Int. Journal Solids Structures 22 (1986) 951–964

    Google Scholar 

  20. J. L. Ericksen,: Stable equilibrium configurations of elastic crystals. Arch. Rat. Mech. Anal. 94 (1986) 1–14

    Google Scholar 

  21. Ericksen, J. L.: Twinning of crystals I, in Metastability and Incompletely Posed Problems. S. Antman et al., eds., Berlin: Springer-Verlag (1987) 77–94

    Google Scholar 

  22. Firoozye, N.: Optimal Translations and Relaxations of Some Multiwell Energies, Ph. D. thesis, New York University, 1990

  23. Firoozye, N.: Optimal use of the translation method and relaxations of variational problems. Comm. Pure Appl. Math., to appear.

  24. Fonseca, I.: Variational methods for elastic crystals. Arch. Rat. Mech. Anal. 97 (1987) 189–220

    Google Scholar 

  25. Fonseca, I.: Stability of elastic crystals, in Non-Classical Continuum Mechanics, R. Knops and A. Lacey eds., Cambridge: University Press (1987) 187–196

    Google Scholar 

  26. Fonseca, I.: The lower quasiconvex envelope of the stored energy function for an elastic crystal. Journal Math. Pures et Appl. 67 (1988) 175–195

    Google Scholar 

  27. Fonseca, I.; Tartar, L.: The displacement problem for elastic crystals. Proc. Roy. Soc. Edinburgh 113 AA (1989) 159–180

    Google Scholar 

  28. Francfort, G. A.; Murat, F.: Homogenization and optimal bounds in linear elasticity. Arch. Rat. Mech. Anal. 94 (1986) 307–334

    Google Scholar 

  29. Gerard, P.: Moyennisation et regularite 2-microlocale, Annales Scientifiques de l'Ecole Normale Superieure to appear

  30. Gerard, P.: Microlocal defect measures, preprint

  31. Grinfel'd, M. A.: Conditions for thermodynamic phase equilibrium in a nonlinear elastic material. Doklady Akad. Nauk SSSR Geophysics 251 (1980) 824–828

    Google Scholar 

  32. Grinfel'd, M. A.: Stability of interphase boundaries in solid elastic media. Prikl. Matem. Mekhan. 51 (1987) 489–496

    Google Scholar 

  33. Grinfel'd, M.: Continuum methods in the theory of phase transitions in solids. Phys. Earth and Planetary Interiors 50 (1988) 99–109

    Google Scholar 

  34. Grindfel'd, M. A.; Langman, S. L.: Average thermoelastic moduli of two-phase media. Izvestia Earth Physics 21 (1985) 594–602

    Google Scholar 

  35. Hong, M.; Wedge, D. E.; Morris, J. W.: The state and habit of the Fe16N2 precipitate in b.c.c. iron: elastic theory. Acta Metallurgica 32 (1984) 279–288

    Google Scholar 

  36. James, R. D.: The arrangement of coherent phases in a loaded body, in Phase Transformations and Material Instabilities in Solids, M. Gurtin, ed., Academic Press (1984) 79–98

  37. James, R. D.: Displacive phase transformations in solids. Journal Mech. Phys. Solids 34 (1986) 359–394

    Google Scholar 

  38. James, R. D.: The stability and metastability of quartz, in Metastability and Incompletely Posed Problems, S. Antman et al. eds., Berlin: Springer-Verlag (1987) 147–176

    Google Scholar 

  39. James, R. D.; Kinderlehrer, D.: Theory of diffusionless phase transitions, in Lecture Notes in Physics 344, M. Rascle et al., eds., Berlin: Springer-Verlag (1989) 51–84

    Google Scholar 

  40. Johnson, W. C.; Voorhees, P. W.: Phase equilibrium in two-phase coherent solids. Metall. Trans. 18 A (1987) 1213–1228

    Google Scholar 

  41. Kaganova, I. M.; Roitburd, A. L.: An anisotropic crystalline inclusion in an anisotropic matrix. Sov. Phys. Crystallogr. 34 (1989) 650–653

    Google Scholar 

  42. Kaganova, I. M.; Roitburd, A. L.: Equilibrium between elasticially-interacting phases. Sov. Phys. JETP 67 (1988) 1173–1183

    Google Scholar 

  43. Khachaturyan, A. G.: Some questions concerning the theory of phase transformations in solids. Soviet Physics-Solid State 8 (1967) 2163–2168

    Google Scholar 

  44. Khachaturyan, A. G.: Theory of Structural Transformations in Solids. John Wiley and Sons (1983)

  45. Khachaturyan, A. G.; Shatalov, G. A.: Theory of macroscopic periodicity for a phase transition in the solid state. Soviet Physics JETP 29 (1969) 557–561

    Google Scholar 

  46. Kinderlehrer, D.: Twinning of crystals II, in Metastability and Incompletely Posed Problems, S. Antman et al., eds., Berlin: Springer-Verlag (1987) 135–146

    Google Scholar 

  47. Kohn, R. V.: The relationship between linear and nonlinear variational models of coherent phase transitions, in Trans. 7th Army Conf. on Appl. Math. and Computing, ARO Report No. 90-1 (1990)

  48. Kohn, R. V.: Relaxation of the elastic energy for a system of two coherent phases with well-ordered elastic moduli, in preparation

  49. Kohn, R. V.; Lipton, R.: Optimal bounds for the effective energy of a mixture of isotropic, incompressible, elastic materials. Arch. Rat. Mech. Anal. 102 (1988) 331–350

    Google Scholar 

  50. Kohn, R. V.; Milton, G. W.: On bounding the effective conductivity of anisotropic composites, in Homogenization and Effective Moduli of Materials and Media. J. Erickensen et al., eds., Berlin: Springer-Verlag (1986) 97–125

    Google Scholar 

  51. Kohn, R. V.; Muller, S.: in preparation

  52. Kohn, R. V.; Sternberg, P.: Local minimisers and singular perturbations. Proc. Roy. Soc. Edinburgh 111 A (1989) 69–84

    Google Scholar 

  53. Kohn, R. V.; Strang, F.: Optimal design and relaxation of variational problems, I–III. Comm. Pure Appl. Math. 34 (1987) 113–137, 139–182 and 353–377

    Google Scholar 

  54. Kohn, R. V.; Vogelius, M.: Relaxation of a variational method for impedance computed tomography. Comm. Pure Appl. Math. 40 (1987) 745–777

    Google Scholar 

  55. Kostlan, E.; Morris, J. W.: The preferred habit of a coherent thin-plate inclusion in an anisotropic elastic solid. Acta Metallurgica 35 (1987) 2167–2175

    Google Scholar 

  56. Larche, F.; Cahn, J. W.: A linear theory of thermochemical equilibrium of solids under stress. Acta Metallurgica 21 (1973) 1051–1063

    Google Scholar 

  57. Larche, F.; Cahn, J. W.: A nonlinear theory of thermochemical equilibrium of solids under stress. Acta Metallurgica 26 (1978) 53–60

    Google Scholar 

  58. Larche, F. C.; J. Cahn, W.: Thermomechanical equilibrium of multiphase solids under stress. Acta Metallurgica 26 (1978) 1579–1589

    Google Scholar 

  59. Lee, J. K.; Barnett, D. M.; Aaronson, H. I.: The elastic strain energy of coherent ellipsoidal precipitates in anisotropic crystalline solids. Metallurgical Trans. 8 A (1977) 963–970

    Google Scholar 

  60. Lurie, K. A.; Cherkaev, A. V.: Exact estimates of the conductivity of a binary mixture of isotropic components. Proc. Roy. Soc. Edinburgh 104 A (1986) 21–38

    Google Scholar 

  61. Lurie, K. A.; Cherkaev, A. V.: On a certain variational problem of phase equilibrium. in Material Instabilities in Continuum Mechanics, J. M. Ball, ed., Oxford: University Press (1988) 257–268

    Google Scholar 

  62. Mayo, W. E.; Tsakalakos, T.: The influence of elastic strain energy on the formation of coherent hexagonal phases. Metallurgical Trans. 11 A (1980) 1637–1644

    Google Scholar 

  63. Milton, G.: Modelling the properties of composites by laminates, in Homogenization and Effective Moduli of Materials and Media, J. Ericksen etal., eds., Berlin: Springer-Verlag (1986) 150–175

    Google Scholar 

  64. Milton, G. W.: On characterizing the set of possible effective tensors of composites: the variational method and the translation method. Comm. Pure Appl. Math. 43 (1990) 63–125

    Google Scholar 

  65. Milton, G. W.; Kohn, R. V.: Variational bounds on the effective moduli of anisotropic composites. Journal Mech. Phys. Solids 36 (1988) 597–629

    Google Scholar 

  66. Murat, F.: Tartar, L.; personal communication (1989) see also ref. 80.)

  67. Pipkin, A. C.: Elastic materials with two preferred states. Quart. J. Mech. Appl. Math. 44 (1991) 1–15

    Google Scholar 

  68. Roitburd, A. L.: Kristallografiya 12 (1967) 567ff. (In Russian)

    Google Scholar 

  69. Roitburd, A. L.: The domain structure of crystals formed in the solid phase. Sov. Phys. Solid State 10 (1969) 2870–2876

    Google Scholar 

  70. Roitburd, A. L.: Domain structure caused by internal stresses in heterophase solids. Phys. Stat. Sol. (a) 16 (1973) 329–339

    Google Scholar 

  71. Roitburd, A. L.: Martensitic transformation as a typical phase transformation in solids, in Solids State Physics 33 Academic Press (1978) 317–390

  72. Roitburd, A. L.: Equilibrium and phase diagrams of coherent phases in solids. Sov. Phys. Solid State 26 (1984) 1229–1233

    Google Scholar 

  73. Roitburd, A. L.: Thermodynamics of solid solution precipitation. Sov. Phys. Solid State 27 (1985) 598–603

    Google Scholar 

  74. Roitburd, A. L.: Phase equilibrium in solids. Sov. Phys. Solid State 28 (1986) 1716–1718

    Google Scholar 

  75. Roitburd, A. L.; Kosenko, N. S.: Orientational dependence of the elastic energy of a plane interlayer in a system of coherent phases. Phys. Stat. Sol. (a) 35 (1976) 735–746

    Google Scholar 

  76. Rosakis, P.: Compact zones of shear transformation in an anisotropic solid, preprint

  77. Rybka, P.: Dynamical Modelling of Phase Transitions in Solids by Means of Viscoelasticity in Many Dimensions. Ph. D. Thesis NYU 1990

  78. Schneck, R.; Rokhlin, S. I.; Dariel, M. P.: Criterion for predicting the morphology of crystalline cubic precipitates in a cubic matrix. Metallurgical Trans. 16 A (1985) 197–202

    Google Scholar 

  79. Tartar, L.: Estimations fines de coefficients homogeneises, in Ennio de Giorgi's Colloquium, P. Kree, ed., Pitman (1985) 168–187

  80. Tartar, L.: H-measures: a new approach for studying homogenization, oscillations, and concentration effects in partial differential equations. Proc. Roy. Soc. Edinburgh 115A (1990) 193–230

  81. Tartar, L.: H-measures and small amplitude homogenization, in Random Media and Composites, R. Kohn and G. Milton, eds., SIAM (1989) 89–99

  82. Tsakalakos, T.: On the strain energy of transformation inhomogeneities in solids, in Micromechanics and Inhomogeneity — The Toshio Mura 65th Anniversary Volume. G. Weng et al., eds., Berlin: Springer-Verlag (1990) 469–496

    Google Scholar 

  83. Wayman, C. M.: Introduction to the Crystallography of Martensitic Transformations, MacMillan (1964)

  84. Wen, S. H.; Khatchaturyan, A. G.; Morris, J. W.: Computer simulation of a “tweedtransformation” in an idealized elastic crystal. Metall. Trans. 12 A (1981) 581–587

    Google Scholar 

  85. Wen, S. H.; Kostlan, E.; Hong, M.; Khachaturyan, A. G.; Morris, Jr., J. W.: The preferred habit of a tetragonal inclusion in a cubic matrix. Acta Metallurgica 29 (1981) 1247–1254

    Google Scholar 

  86. Wert, J. A.: The strain energy of a disc-shaped GP zone. Acta Metallurgica 24 (1976) 65–71

    Google Scholar 

  87. Williams, R. O.: Long-period superlattices in the copper-gold system as two-phase mixtures. Metall. Trans. 11 A (1980) 247–253

    Google Scholar 

  88. Williams, R. O.: The calculation of coherent phase equilibria. CALPHAD 8 (1984) 1–14

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Supported in part by ARO contract DAAL03-89-K-0039, DARPA contract F49620-87-C-0065, ONR grant N00014-88-K-0279, NSF grant DMS-8701895 and AFOSR grant 90-0090

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kohn, R.V. The relaxation of a double-well energy. Continuum Mech. Thermodyn 3, 193–236 (1991). https://doi.org/10.1007/BF01135336

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01135336

Keywords

Navigation