nach oben

Cellulose

Erschienen in:

06.01.2021 | Original Research

Low permeable hydrophobic nanofibrilated cellulose films modified by dipping and heating processing technique

verfasst von: Gustavo de Souza, Mohamed Naceur Belgacem, Alessandro Gandini, Antonio José Felix Carvalho

Erschienen in: Cellulose | Ausgabe 3/2021

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Nanofibrilated cellulose (NFC) films have potential to replace synthetic polymers as flexible films for packaging. However, NFC is hydrophilic and water acts as plasticizer decreasing the stiffness of the films and reducing its barrier effectiveness against water vapor and oxygen. Here we describe the surface modification of cellulose films with blocked diisocyanates through a dipping and heating process not requiring the previous drying of the materials. The reactions were conducted at 170 °C for a few minutes during which deblocking led to a new urethane bond formation with NFC surface hydroxyl groups, thus hydrophobizing the films. A remarkable enhancement in water repellent properties was confirmed by water contact angles higher than 110° and water vapor transmission rate (WVTR) of 40 g/m² day, which is very low when compared to similar materials, representing a reduction of 74% with respect to the non- modified films.

Graphic abstract

Vorheriger Artikel Chitosan-Mg(OH)2 based composite membrane containing nitrogen doped GO for direct ethanol fuel cell

Nächster Artikel Hydrophobic development and mechanical properties of cellulose substrates supercritically impregnated with food-grade waxes

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Arbatan T, Zhang L, Fang X-Y, Shen W (2012) Cellulose nanofibers as binder for fabrication of superhydrophobic paper. Chem Eng J 210:74–79. https://doi.org/10.1016/j.cej.2012.08.074CrossRef

Carvalho AJF, Curvelo AAS, Gandini A (2005) Surface chemical modification of thermoplastic starch: Reactions with isocyanates, epoxy functions and stearoyl chloride. Ind Crops Prod 21:331–336. https://doi.org/10.1016/j.indcrop.2004.04.027CrossRef

Chen Y, Geng B, Ru J et al (2017) Comparative characteristics of TEMPO-oxidized cellulose nanofibers and resulting nanopapers from bamboo, softwood, and hardwood pulps. Cellulose 24:4831–4844. https://doi.org/10.1007/s10570-017-1478-4CrossRef

Delebecq E, Pascault JP, Boutevin B, Ganachaud F (2013) On the versatility of urethane/urea bonds: Reversibility, blocked isocyanate, and non-isocyanate polyurethane. Chem Rev 113:80–118. https://doi.org/10.1021/cr300195nCrossRefPubMed

Djafari Petroudy SR, Rahmani N, Rasooly Garmaroody E et al (2019) Comparative study of cellulose and lignocellulose nanopapers prepared from hard wood pulps: Morphological, structural and barrier properties. Int J Biol Macromol 135:512–520. https://doi.org/10.1016/j.ijbiomac.2019.05.212CrossRefPubMed

Dufresne A (2017) Handbook of Nanocellulose and Cellulose Nanocomposites. Wiley-VCH Verlag GmbH & Co, KGaA, Weinheim, Germany

Dufresne A, Dupeyre D, Vignon MR (2000) Cellulose microfibrils from potato tuber cells: Processing and characterization of starch-cellulose microfibril composites. J Appl Polym Sci 76:2080–2092. https://doi.org/10.1002/(SICI)1097-4628(20000628)76:14%3c2080::AID-APP12%3e3.0.CO;2-UCrossRef

Ferrer A, Pal L, Hubbe M (2017) Nanocellulose in packaging: Advances in barrier layer technologies. Ind Crops Prod 95:574–582. https://doi.org/10.1016/j.indcrop.2016.11.012CrossRef

Ferrer A, Salas C, Rojas OJ (2015) Dewatering of MNFC containing microfibrils and microparticles from soybean hulls: mechanical and transport properties of hybrid films. Cellulose 22:3919–3928. https://doi.org/10.1007/s10570-015-0768-yCrossRef

Garusinghe UM, Varanasi S, Raghuwanshi VS et al (2018) Nanocellulose-montmorillonite composites of low water vapour permeability. Colloids Surfaces A Physicochem Eng Asp 540:233–241. https://doi.org/10.1016/j.colsurfa.2018.01.010CrossRef

Gironès J, Pimenta MTB, Vilaseca F et al (2007) Blocked isocyanates as coupling agents for cellulose-based composites. Carbohydr Polym 68:537–543. https://doi.org/10.1016/j.carbpol.2006.10.020CrossRef

Gironès J, Pimenta MTB, Vilaseca F et al (2008) Blocked diisocyanates as reactive coupling agents: Application to pine fiber-polypropylene composites. Carbohydr Polym 74:106–113. https://doi.org/10.1016/j.carbpol.2008.01.026CrossRef

Heinze T (2016) Cellulose Chemistry and Properties: Fibers, Nanocelluloses and Advanced Materials. In: Rojas OJ (ed) Advances in Polymer Science 271. Springer International Publishing, Cham, p 341

Hu Y, Acharya S, Abidi N (2019) Cellulose porosity improves its dissolution by facilitating solvent diffusion. Int J Biol Macromol 123:1289–1296. https://doi.org/10.1016/j.ijbiomac.2018.10.062CrossRefPubMed

Hubbe MA, Gardner DJ, Shen W (2015) Wettability of cellulosics. BioResources 10:8657–8749

Klemm D, Cranston ED, Fischer D et al (2018) Nanocellulose as a natural source for groundbreaking applications in materials science: Today’s state. Mater Today 21:720–748. https://doi.org/10.1016/j.mattod.2018.02.001CrossRef

Klemm D, Heublein B, Fink HP, Bohn A (2005) Cellulose: Fascinating biopolymer and sustainable raw material. Angew Chemie—Int Ed 44:3358–3393. https://doi.org/10.1002/anie.200460587CrossRef

Li L, Zhou ZH, Yang B et al (2019a) Robust cellulose nanocomposite films based on covalently cross-linked network with effective resistance to water permeability. Carbohydr Polym 211:237–248. https://doi.org/10.1016/j.carbpol.2019.01.084CrossRefPubMed

Li W, Wang S, Wang W et al (2019b) Facile preparation of reactive hydrophobic cellulose nanofibril film for reducing water vapor permeability (WVP) in packaging applications. Cellulose 26:3271–3284. https://doi.org/10.1007/s10570-019-02270-xCrossRef

Liimatainen H, Ezekiel N, Sliz R et al (2013) High-strength nanocellulose-talc hybrid barrier films. ACS Appl Mater Interfaces 5:13412–13418. https://doi.org/10.1021/am4043273CrossRefPubMed

Liu A, Walther A, Ikkala O et al (2011) Clay nanopaper with tough cellulose nanofiber matrix for fire retardancy and gas barrier functions. Biomacromol 12:633–641. https://doi.org/10.1021/bm101296zCrossRef

Meyer-Stork LS, Höcker H, Berndt H (1992) Syntheses and reactions of urethanes of cellobiose and cellulose-containing uretdione groups. J Appl Polym Sci 44:1043–1049. https://doi.org/10.1002/app.1992.070440613CrossRef

Operamolla A (2019) Recent advances on renewable and biodegradable cellulose nanopaper substrates for transparent light-harvesting devices: Interaction with humid environment. Int J Photoenergy. https://doi.org/10.1155/2019/3057929CrossRef

Ouyang X, Huang W, Cabrera E et al (2015) Graphene-graphene oxide-graphene hybrid nanopapers with superior mechanical, gas barrier and electrical properties. AIP Adv. https://doi.org/10.1063/1.4906795CrossRef

Paquet O, Krouit M, Bras J et al (2010) Surface modification of cellulose by PCL grafts. Acta Mater 58:792–801. https://doi.org/10.1016/j.actamat.2009.09.057CrossRef

Quinney RF, Banks WB, Lawther JM (1995) The activation of wood fibre for thermoplastic coupling, the reaction of wood with a potential coupling agent. J Wood Chem Technol 15:529–544. https://doi.org/10.1080/02773819508009524CrossRef

Rahmani Seraji H, Karimi M, Mahmoudi L (2017) In situ monitoring the change of mechanical response induced by the diffusion of saline water in glassy cellulose acetate. Desalination 420:191–207. https://doi.org/10.1016/j.desal.2017.07.013CrossRef

Rodionova G, Lenes M, Eriksen Ø, Gregersen Ø (2011) Surface chemical modification of microfibrillated cellulose: Improvement of barrier properties for packaging applications. Cellulose 18(1):127–134CrossRef

Rojo E, Peresin MS, Sampson WW et al (2015) Comprehensive elucidation of the effect of residual lignin on the physical, barrier, mechanical and surface properties of nanocellulose films. Green Chem 17:1853–1866. https://doi.org/10.1039/c4gc02398fCrossRef

Rueda L, Fernández d’Arlas B, Zhou Q et al (2011) Isocyanate-rich cellulose nanocrystals and their selective insertion in elastomeric polyurethane. Compos Sci Technol 71:1953–1960. https://doi.org/10.1016/j.compscitech.2011.09.014CrossRef

Sehaqui H, Zimmermann T, Tingaut P (2014) Hydrophobic cellulose nanopaper through a mild esterification procedure. Cellulose 21:367–382. https://doi.org/10.1007/s10570-013-0110-5CrossRef

Sethi J, Farooq M, Österberg M et al (2018) Stereoselectively water resistant hybrid nanopapers prepared by cellulose nanofibers and water-based polyurethane. Carbohydr Polym 199:286–293. https://doi.org/10.1016/j.carbpol.2018.07.028CrossRefPubMed

Sethi J, Visanko M, Österberg M, Sirviö JA (2019) A fast method to prepare mechanically strong and water resistant lignocellulosic nanopapers. Carbohydr Polym 203:148–156. https://doi.org/10.1016/j.carbpol.2018.09.037CrossRefPubMed

Sharma S, Zhang X, Nair SS et al (2014) Thermally enhanced high performance cellulose nano fibril barrier membranes. RSC Adv 4:45136–45142. https://doi.org/10.1039/c4ra07469fCrossRef

Solala I, Bordes R, Larsson A (2018) Water vapor mass transport across nanofibrillated cellulose films: effect of surface hydrophobization. Cellulose 25:347–356. https://doi.org/10.1007/s10570-017-1608-zCrossRef

Spence KL, Venditti RA, Rojas OJ et al (2011) Water vapor barrier properties of coated and filled microfibrillated cellulose composite films. BioResources 6:4370–4388CrossRef

Urbina L, Corcuera MÁ, Eceiza A, Retegi A (2019) Stiff all-bacterial cellulose nanopaper with enhanced mechanical and barrier properties. Mater Lett 246:67–70. https://doi.org/10.1016/j.matlet.2019.03.005CrossRef

Wang J, Gardner DJ, Stark NM et al (2018) Moisture and Oxygen Barrier Properties of Cellulose Nanomaterial-Based Films. ACS Sustain Chem Eng 6:49–70. https://doi.org/10.1021/acssuschemeng.7b03523CrossRef

Wicks Da, Wicks ZW (1999) Blocked isocyanates III: Part A. Mechanisms and chemistry. Prog Org Coatings 36:148–172. https://doi.org/10.1016/S0300-9440(99)00042-9CrossRef

Willberg-keyriläinen P, Vartiainen J, Pelto J, Ropponen J (2017) Hydrophobization and smoothing of cellulose nanofibril films by cellulose ester coatings. Carbohydr Polym 170:160–165. https://doi.org/10.1016/j.carbpol.2017.04.082CrossRefPubMed

Xia J, Zhang Z, Liu W et al (2018) Highly transparent 100% cellulose nanofibril films with extremely high oxygen barriers in high relative humidity. Cellulose 25:4057–4066. https://doi.org/10.1007/s10570-018-1843-yCrossRef

Yousefi H, Faezipour M, Hedjazi S et al (2013) Comparative study of paper and nanopaper properties prepared from bacterial cellulose nanofibers and fibers/ground cellulose nanofibers of canola straw. Ind Crops Prod 43:732–737. https://doi.org/10.1016/j.indcrop.2012.08.030CrossRef

Zhang C, Zhang Y, Cha R et al (2019) Manufacture of Hydrophobic Nanocomposite Films with High Printability. ACS Sustain Chem Eng 7:15404–15412. https://doi.org/10.1021/acssuschemeng.9b02856CrossRef

Zheng M, Tajvidi M, Tayeb AH, Stark NM (2019) Effects of bentonite on physical, mechanical and barrier properties of cellulose nanofibril hybrid films for packaging applications. Cellulose 26:5363–5379. https://doi.org/10.1007/s10570-019-02473-2CrossRef

Titel: Low permeable hydrophobic nanofibrilated cellulose films modified by dipping and heating processing technique
verfasst von: Gustavo de Souza
Mohamed Naceur Belgacem
Alessandro Gandini
Antonio José Felix Carvalho
Publikationsdatum: 06.01.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 3/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-020-03619-3

Springer Professional

Abstract

Graphic abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 3/2021

A novel flame retardant based on polyhydric alcohols and P–N synergy for treatment of cotton fabrics

Particle size distributions for cellulose nanocrystals measured by atomic force microscopy: an interlaboratory comparison

Single step PAA delignification of wood chips for high-performance holocellulose fibers

One-pot fabrication of hydrophilic-oleophobic cellulose nanofiber-silane composite aerogels for selectively absorbing water from oil–water mixtures

Strain-stiffening composite hydrogels through UV grafting of cellulose nanofibers

Combination of ultrasonication and deep eutectic solvent in pretreatment of lignocellulosic biomass for enhanced enzymatic saccharification