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29.11.2021 | Original Research

Low-temperature deposition and crystallization of RuO₂/TiO₂ on cotton fabric for efficient solar photocatalytic degradation of o-toluidine

verfasst von: Mouheb Sboui, Hinda Lachheb, Meenakshisundaram Swaminathan, Jia Hong Pan

Erschienen in: Cellulose | Ausgabe 2/2022

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Abstract

A green low-temperature deposition and crystallization method was developed to uniformly coat RuO₂/TiO₂ nanocomposite onto cotton fabrics for efficient solar photocatalysis. The sequential growth of anatase TiO₂ and rutile RuO₂ on the surface of the cotton was confirmed by XRD, Raman and XPS characterizations. After the deposition of RuO₂, the optical properties of RuO₂/TiO₂/Cotton revealed better visible light absorption and higher charge mobility, and XPS spectra showed that the peaks of Ti 2p_3/2 and O 1 s shifted towards the lower binding energies due to the interfacial charge transfer at the robust RuO₂/TiO₂ mediated with Ti–O–Ru bonding. The photocatalytic performances of the RuO₂/TiO₂/Cotton were evaluated towards the photodegradation of o-toluidine (o-TD), an aromatic amine widely used in the chemical industry. Compared with TiO₂/Cotton, RuO₂/TiO₂/Cotton exhibited a remarkable improvement in the photocatalytic activity. The presence of RuO₂ on the surface of TiO₂/Cotton narrowed the band gap and improved the absorption of visible light. Moreover, the successful formation of a robust heterogeneous interface between TiO₂ and RuO₂ suppressed the charge carrier (e^–/h⁺) recombination effectively. With the RuO₂/TiO₂ coating chemically bound to the cotton fibers, RuO₂/TiO₂/Cotton delivered long-term stability in photocatalytic activity and high mechanical durability even after 20 washing times. Our facile and scalable synthesis strategy paved a universal route to efficient immobilization of visible-light-responsible TiO₂-based photocatalysts on the low-heat-resistant substrates for various applications.

Graphical abstract

Vorheriger Artikel Durable hydrophobic and antibacterial textile coating via PDA/AgNPs/ODA in situ assembly

Nächster Artikel Construction of biological flame retardant layer on cotton fabric via photografting of nucleotide/amino acid monomers

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Titel: Low-temperature deposition and crystallization of RuO2/TiO2 on cotton fabric for efficient solar photocatalytic degradation of o-toluidine
verfasst von: Mouheb Sboui
Hinda Lachheb
Meenakshisundaram Swaminathan
Jia Hong Pan
Publikationsdatum: 29.11.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 2/2022
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-04308-5

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