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Erschienen in: Tribology Letters 2/2019

01.06.2019 | Original Paper

Lubricity and Adsorption of Castor Oil Sulfated Sodium Salt Emulsion Solution on Titanium Alloy

verfasst von: Ye Yang, Chenhui Zhang, Yuanjing Dai, Jianbin Luo

Erschienen in: Tribology Letters | Ausgabe 2/2019

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Abstract

Effective water-based lubricants for titanium alloys have been investigated. The results reveal that castor oil sulfated sodium salt (CSS) solution can decrease the friction coefficient and adhesive wear compared with water, polyalkylene glycol (PAG) aqueous solution, or castor oil. The surface morphology of the tested discs and balls were measured, and the mechanism investigated. The rubbing surface was analyzed by using time-of-flight secondary-ion mass spectrometry (ToF–SIMS), indicating that a layer of physically adsorbed film remained on the surface, the main ingredient of which was CSS molecules. The mass and morphology of the adsorbed film were explored by quartz crystal microbalance measurements with dissipation monitoring and atom force microscopy, respectively. An electrical voltage, which could change the electrostatic force of the lubricants with the metal surface, was then applied to the frictional pair to explore the mechanism driving the adsorption. The physically adsorbed film played an important role in lubrication. The results of this study indicate that CSS could represent a good water-based lubricant base stock for the design of cutting fluids for titanium alloys.

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Literatur
1.
Zurück zum Zitat Leyens, C., Peters, M.: Titanium and Titanium Alloys. Wiley Online Library. Wiley-VCH Verlag, Weinheim (2003)CrossRef Leyens, C., Peters, M.: Titanium and Titanium Alloys. Wiley Online Library. Wiley-VCH Verlag, Weinheim (2003)CrossRef
2.
Zurück zum Zitat Ezugwu, E.O., Wang, Z.M.: Titanium alloys and their machinability—a review. J. Mater. Process. Technol. 68(3), 262–274 (1997)CrossRef Ezugwu, E.O., Wang, Z.M.: Titanium alloys and their machinability—a review. J. Mater. Process. Technol. 68(3), 262–274 (1997)CrossRef
3.
Zurück zum Zitat Veiga, C., Devim, J.P., Loureiro, A.J.R.: Properties and applications of titanium alloys: a brief review. Rev. Adv. Mater. Sci. 32(2), 133–148 (2012) Veiga, C., Devim, J.P., Loureiro, A.J.R.: Properties and applications of titanium alloys: a brief review. Rev. Adv. Mater. Sci. 32(2), 133–148 (2012)
4.
Zurück zum Zitat Ezugwu, E.O.: Key improvements in the machining of difficult-to-cut aerospace superalloys. Int. J. Mach. Tools Manuf. 45(12), 1353–1367 (2005)CrossRef Ezugwu, E.O.: Key improvements in the machining of difficult-to-cut aerospace superalloys. Int. J. Mach. Tools Manuf. 45(12), 1353–1367 (2005)CrossRef
5.
Zurück zum Zitat Pramanik, A.: Problems and solutions in machining of titanium alloys. Int. J. Adv. Manuf. Technol. 70, 919–928 (2014)CrossRef Pramanik, A.: Problems and solutions in machining of titanium alloys. Int. J. Adv. Manuf. Technol. 70, 919–928 (2014)CrossRef
6.
Zurück zum Zitat Brinksmeier, E., Meyer, D., Huesmann-Cordes, A.G., Herrmann, C.: Metalworking fluids-mechanisms and performance. CIRP Ann. Manuf. Technol. 64(2), 605–628 (2015)CrossRef Brinksmeier, E., Meyer, D., Huesmann-Cordes, A.G., Herrmann, C.: Metalworking fluids-mechanisms and performance. CIRP Ann. Manuf. Technol. 64(2), 605–628 (2015)CrossRef
7.
Zurück zum Zitat Debnath, S., Reddy, M.M., Yi, Q.S.: Environmental friendly cutting fluids and cooling techniques in machining: a review. J. Clean. Prod. 83, 33–47 (2014)CrossRef Debnath, S., Reddy, M.M., Yi, Q.S.: Environmental friendly cutting fluids and cooling techniques in machining: a review. J. Clean. Prod. 83, 33–47 (2014)CrossRef
8.
Zurück zum Zitat Xavior, M.A., Adithan, M.: Determining the influence of cutting fluids on tool wear and surface roughness during turning of AISI 304 austenitic stainless steel. J. Mater. Process. Technol. 209(2), 900–909 (2009)CrossRef Xavior, M.A., Adithan, M.: Determining the influence of cutting fluids on tool wear and surface roughness during turning of AISI 304 austenitic stainless steel. J. Mater. Process. Technol. 209(2), 900–909 (2009)CrossRef
9.
Zurück zum Zitat Molinari, A., Straffelini, G., Tesi, B., Bacci, T.: Dry sliding wear mechanisms of the Ti6Al4V alloy. Wear 208(1), 105–112 (1997)CrossRef Molinari, A., Straffelini, G., Tesi, B., Bacci, T.: Dry sliding wear mechanisms of the Ti6Al4V alloy. Wear 208(1), 105–112 (1997)CrossRef
10.
Zurück zum Zitat Niu, Q.L., Zheng, X.H., Ming, W.W., Chen, M.: Friction and wear performance of titanium alloys against tungsten carbide under dry sliding and water lubrication. Tribol. Trans. 56(1), 101–108 (2013)CrossRef Niu, Q.L., Zheng, X.H., Ming, W.W., Chen, M.: Friction and wear performance of titanium alloys against tungsten carbide under dry sliding and water lubrication. Tribol. Trans. 56(1), 101–108 (2013)CrossRef
11.
Zurück zum Zitat Straffelini, G., Molinari, A.: Dry sliding wear of Ti-6Al-4V alloy as influenced by the counterface and sliding conditions. Wear 236, 328–338 (1999)CrossRef Straffelini, G., Molinari, A.: Dry sliding wear of Ti-6Al-4V alloy as influenced by the counterface and sliding conditions. Wear 236, 328–338 (1999)CrossRef
12.
Zurück zum Zitat Li, C.X., Xia, J., Dong, H.: Sliding wear of TiAl intermetallics against steel and ceramics of Al2O3, Si3N4 and WC/Co. Wear 261(5–6), 693–701 (2006)CrossRef Li, C.X., Xia, J., Dong, H.: Sliding wear of TiAl intermetallics against steel and ceramics of Al2O3, Si3N4 and WC/Co. Wear 261(5–6), 693–701 (2006)CrossRef
13.
Zurück zum Zitat Qu, J., Blau, P.J., Watkins, T.R., Cavin, O.B., Kulkarni, N.S.: Friction and wear of titanium alloys sliding against metal, polymer, and ceramic counterfaces. Wear 258(9), 1348–1356 (2004)CrossRef Qu, J., Blau, P.J., Watkins, T.R., Cavin, O.B., Kulkarni, N.S.: Friction and wear of titanium alloys sliding against metal, polymer, and ceramic counterfaces. Wear 258(9), 1348–1356 (2004)CrossRef
14.
Zurück zum Zitat Amanov, A., Sasaki, S.: A study on the tribological characteristics of duplex-treated Ti–6Al–4V alloy under oil-lubricated sliding conditions. Tribol. Int. 64, 155–163 (2013)CrossRef Amanov, A., Sasaki, S.: A study on the tribological characteristics of duplex-treated Ti–6Al–4V alloy under oil-lubricated sliding conditions. Tribol. Int. 64, 155–163 (2013)CrossRef
15.
Zurück zum Zitat Dutt Sharma, M., Sehgal, R.: Experimental study of friction and wear characteristics of titanium alloy (Ti–6Al–4V) under lubricated sliding condition. Ind. Lubr. Tribol. 66(2), 174–183 (2014)CrossRef Dutt Sharma, M., Sehgal, R.: Experimental study of friction and wear characteristics of titanium alloy (Ti–6Al–4V) under lubricated sliding condition. Ind. Lubr. Tribol. 66(2), 174–183 (2014)CrossRef
16.
Zurück zum Zitat Cheng, J., Yang, J., Ma, J., Bi, Q., Zhang, X., Fu, L., Li, F., Zhu, S., Liu, W.: The tribological behavior of a Ti-46Al-2Cr-2Nb alloy under liquid paraffine lubrication. Tribol. Lett. 46(3), 233–241 (2012)CrossRef Cheng, J., Yang, J., Ma, J., Bi, Q., Zhang, X., Fu, L., Li, F., Zhu, S., Liu, W.: The tribological behavior of a Ti-46Al-2Cr-2Nb alloy under liquid paraffine lubrication. Tribol. Lett. 46(3), 233–241 (2012)CrossRef
17.
Zurück zum Zitat Yang, Y., Zhang, C., Dai, Y., Luo, J.: Tribological properties of titanium alloys under lubrication of SEE oil and aqueous solutions. Tribol. Int. 109, 40–47 (2017)CrossRef Yang, Y., Zhang, C., Dai, Y., Luo, J.: Tribological properties of titanium alloys under lubrication of SEE oil and aqueous solutions. Tribol. Int. 109, 40–47 (2017)CrossRef
18.
Zurück zum Zitat Jiménez, A.E., Bermúdez, M.: Ionic liquids as lubricants of titanium–steel contact. Tribol. Lett. 33(2), 111–126 (2009)CrossRef Jiménez, A.E., Bermúdez, M.: Ionic liquids as lubricants of titanium–steel contact. Tribol. Lett. 33(2), 111–126 (2009)CrossRef
19.
Zurück zum Zitat Jiménez, A.E., Bermúdez, M.D.: Ionic liquids as lubricants of titanium–steel contact. Part 3. Ti6Al4V lubricated with imidazolium ionic liquids with different alkyl chain lengths. Tribol. Lett. 40(2), 237–246 (2010)CrossRef Jiménez, A.E., Bermúdez, M.D.: Ionic liquids as lubricants of titanium–steel contact. Part 3. Ti6Al4V lubricated with imidazolium ionic liquids with different alkyl chain lengths. Tribol. Lett. 40(2), 237–246 (2010)CrossRef
20.
Zurück zum Zitat Jiménez, A.E., Bermúdez, M.D.: Ionic liquids as lubricants of titanium-steel contact. Part 2: friction, wear and surface interactions at high temperature. Tribol. Lett. 37(2), 431–443 (2010)CrossRef Jiménez, A.E., Bermúdez, M.D.: Ionic liquids as lubricants of titanium-steel contact. Part 2: friction, wear and surface interactions at high temperature. Tribol. Lett. 37(2), 431–443 (2010)CrossRef
21.
Zurück zum Zitat Yang, Y., Zhang, C., Wang, Y., Dai, Y., Luo, J.: Friction and wear performance of titanium alloy against tungsten carbide lubricated with phosphate ester. Tribol. Int. 95, 27–34 (2016)CrossRef Yang, Y., Zhang, C., Wang, Y., Dai, Y., Luo, J.: Friction and wear performance of titanium alloy against tungsten carbide lubricated with phosphate ester. Tribol. Int. 95, 27–34 (2016)CrossRef
22.
Zurück zum Zitat Fox, N.J., Stachowiak, G.W.: Vegetable oil-based lubricants—a review of oxidation. Tribol. Int. 40(7), 1035–1046 (2007)CrossRef Fox, N.J., Stachowiak, G.W.: Vegetable oil-based lubricants—a review of oxidation. Tribol. Int. 40(7), 1035–1046 (2007)CrossRef
23.
Zurück zum Zitat Matthew, T., Siniawski, M.T.: Influence of fatty acid composition on the tribological performance of two vegetable-based lubricants. J. Synth. Lubr. 24(2), 101–110 (2007)CrossRef Matthew, T., Siniawski, M.T.: Influence of fatty acid composition on the tribological performance of two vegetable-based lubricants. J. Synth. Lubr. 24(2), 101–110 (2007)CrossRef
24.
Zurück zum Zitat Wagner, H., Luther, R., Mang, T.: Lubricant base fluids based on renewable raw materials: their catalytic manufacture and modification. Appl. Catal. A 221(1), 429–442 (2001)CrossRef Wagner, H., Luther, R., Mang, T.: Lubricant base fluids based on renewable raw materials: their catalytic manufacture and modification. Appl. Catal. A 221(1), 429–442 (2001)CrossRef
25.
Zurück zum Zitat Maleque, M.A., Masjuki, H.H., Sapuan, S.M.: Vegetable-based biodegradable lubricating oil additives. Ind. Lubr. Tribol. 3(55), 137–143 (2003)CrossRef Maleque, M.A., Masjuki, H.H., Sapuan, S.M.: Vegetable-based biodegradable lubricating oil additives. Ind. Lubr. Tribol. 3(55), 137–143 (2003)CrossRef
26.
Zurück zum Zitat Shashidhara, Y.M., Jayaram, S.R.: Vegetable oils as a potential cutting fluid—an evolution. Tribol. Int. 43(5–6), 1073–1081 (2010)CrossRef Shashidhara, Y.M., Jayaram, S.R.: Vegetable oils as a potential cutting fluid—an evolution. Tribol. Int. 43(5–6), 1073–1081 (2010)CrossRef
27.
Zurück zum Zitat Ogunniyi, D.S.: Castor oil: a vital industrial raw material. Bioresour. Technol. 97(9), 1086–1091 (2006)CrossRef Ogunniyi, D.S.: Castor oil: a vital industrial raw material. Bioresour. Technol. 97(9), 1086–1091 (2006)CrossRef
28.
Zurück zum Zitat Mohammed, A.D., Jimoh, A., Akpan, U.G.: Extraction, characterization and modification of castor seed oil. Leonardo J. Sci. 5(8), 43–52 (2006) Mohammed, A.D., Jimoh, A., Akpan, U.G.: Extraction, characterization and modification of castor seed oil. Leonardo J. Sci. 5(8), 43–52 (2006)
29.
Zurück zum Zitat Zhu, L.Z., Zhao, B.W., Li, Z.L.: Water solubility enhancement of PAHs by sodium castor oil sulfonate microemulsions. J. Environ. Sci. 5(15), 583–589 (2003) Zhu, L.Z., Zhao, B.W., Li, Z.L.: Water solubility enhancement of PAHs by sodium castor oil sulfonate microemulsions. J. Environ. Sci. 5(15), 583–589 (2003)
30.
Zurück zum Zitat Escobar, W.: Understanding polyalkylene glycols and where to apply them. Tribol. Lubr. Technol. 64(5), 34–39 (2008) Escobar, W.: Understanding polyalkylene glycols and where to apply them. Tribol. Lubr. Technol. 64(5), 34–39 (2008)
31.
Zurück zum Zitat Zhang, C.H., Zhao, Y.C., Björling, M., Wang, Y., Luo, J.B., Prakash, B.: EHL properties of polyalkylene glycols and their aqueous solutions. Tribol. Lett. 45(3), 379–385 (2012)CrossRef Zhang, C.H., Zhao, Y.C., Björling, M., Wang, Y., Luo, J.B., Prakash, B.: EHL properties of polyalkylene glycols and their aqueous solutions. Tribol. Lett. 45(3), 379–385 (2012)CrossRef
32.
Zurück zum Zitat Zhang, C., Zheng, M., Dai, Y.: Lubricating properties of polyalkylene glycol and organic phosphate ester mixed aqueous solutions. Sci. China Technol. Sci. 56(12), 2988–2993 (2013)CrossRef Zhang, C., Zheng, M., Dai, Y.: Lubricating properties of polyalkylene glycol and organic phosphate ester mixed aqueous solutions. Sci. China Technol. Sci. 56(12), 2988–2993 (2013)CrossRef
33.
Zurück zum Zitat Yan, P., Rong, Y., Wang, G.: The effect of cutting fluids applied in metal cutting process. Proc. Inst. Mech. Eng. Part B J. Eng. Manuf. 230(1), 19–37 (2016)CrossRef Yan, P., Rong, Y., Wang, G.: The effect of cutting fluids applied in metal cutting process. Proc. Inst. Mech. Eng. Part B J. Eng. Manuf. 230(1), 19–37 (2016)CrossRef
34.
Zurück zum Zitat Pettersson, A., Kassfeldt, E., Minami, I.: Additives for environmentally adapted lubricants-friction and wear protection. Tribol. Online 3(3), 163–167 (2008)CrossRef Pettersson, A., Kassfeldt, E., Minami, I.: Additives for environmentally adapted lubricants-friction and wear protection. Tribol. Online 3(3), 163–167 (2008)CrossRef
35.
Zurück zum Zitat Jayal, A.D., Balaji, A.K.: Effects of cutting fluid application on tool wear in machining: interactions with tool-coatings and tool surface features. Wear 267(9–10), 1723–1730 (2009)CrossRef Jayal, A.D., Balaji, A.K.: Effects of cutting fluid application on tool wear in machining: interactions with tool-coatings and tool surface features. Wear 267(9–10), 1723–1730 (2009)CrossRef
36.
Zurück zum Zitat Murase, A., Ohmori, T.: ToF-SIMS analysis of phosphate-type lubricant additives adsorbed on friction surfaces of ferrous materials. Surf. Interface Anal. 31(2), 93–98 (2001)CrossRef Murase, A., Ohmori, T.: ToF-SIMS analysis of phosphate-type lubricant additives adsorbed on friction surfaces of ferrous materials. Surf. Interface Anal. 31(2), 93–98 (2001)CrossRef
37.
Zurück zum Zitat Dauchot, G., De Castro, E., Repoux, M., Combarieu, R., Montmitonnet, P., Delamare, F.: Application of ToF-SIMS surface analysis to tribochemistry in metal forming processes. Wear 260(3), 296–304 (2006)CrossRef Dauchot, G., De Castro, E., Repoux, M., Combarieu, R., Montmitonnet, P., Delamare, F.: Application of ToF-SIMS surface analysis to tribochemistry in metal forming processes. Wear 260(3), 296–304 (2006)CrossRef
38.
Zurück zum Zitat Ma, L., Luo, J., Zhang, C.: Effect of solid surface on the formation of thin confined lubricating film of water with micro-content of oil. Appl. Surf. Sci. 256(22), 6574–6579 (2010)CrossRef Ma, L., Luo, J., Zhang, C.: Effect of solid surface on the formation of thin confined lubricating film of water with micro-content of oil. Appl. Surf. Sci. 256(22), 6574–6579 (2010)CrossRef
39.
Zurück zum Zitat Ma, L., Luo, J., Zhang, C., Liu, S., Zhu, T.: Effect of microcontent of oil in water under confined condition. Appl. Phys. Lett. 95(9), 91908 (2009)CrossRef Ma, L., Luo, J., Zhang, C., Liu, S., Zhu, T.: Effect of microcontent of oil in water under confined condition. Appl. Phys. Lett. 95(9), 91908 (2009)CrossRef
40.
Zurück zum Zitat Ma, L., Zhang, C., Luo, J.: Investigation of the film formation mechanism of oil-in-water (O/W) emulsions. Soft Matter 7(9), 4207–4213 (2011)CrossRef Ma, L., Zhang, C., Luo, J.: Investigation of the film formation mechanism of oil-in-water (O/W) emulsions. Soft Matter 7(9), 4207–4213 (2011)CrossRef
41.
Zurück zum Zitat Zhang, J., Meng, Y.: Stick–slip friction of stainless steel in sodium dodecyl sulfate aqueous solution in the boundary lubrication regime. Tribol. Lett. 56(3), 543–552 (2014)CrossRef Zhang, J., Meng, Y.: Stick–slip friction of stainless steel in sodium dodecyl sulfate aqueous solution in the boundary lubrication regime. Tribol. Lett. 56(3), 543–552 (2014)CrossRef
42.
Zurück zum Zitat Zhang, J., Meng, Y.: Boundary lubrication by adsorption film. Friction 3(2), 115–147 (2015)CrossRef Zhang, J., Meng, Y.: Boundary lubrication by adsorption film. Friction 3(2), 115–147 (2015)CrossRef
43.
Zurück zum Zitat Sauerbrey, G.: Verwendung von Schwingquarzen zur Wägung dünner Schichten und zur Mikrowägung. Zeitschrift für Physik 155(2), 206–222 (1959)CrossRef Sauerbrey, G.: Verwendung von Schwingquarzen zur Wägung dünner Schichten und zur Mikrowägung. Zeitschrift für Physik 155(2), 206–222 (1959)CrossRef
44.
Zurück zum Zitat Malmsten, M., Lindström, A.L., Wärnheim, T.R.: Electrostatic effects on interfacial film formation in emulsion systems. J. Colloid Interface Sci. 179(2), 537–543 (1996)CrossRef Malmsten, M., Lindström, A.L., Wärnheim, T.R.: Electrostatic effects on interfacial film formation in emulsion systems. J. Colloid Interface Sci. 179(2), 537–543 (1996)CrossRef
45.
Zurück zum Zitat Connell, S.D.A., Allen, S., Roberts, C.J., Davies, J., Davies, M.C., Tendler, S.J.B., Williams, P.M.: Investigating the interfacial properties of single-liquid nanodroplets by atomic force microscopy. Langmuir 18(5), 1719–1728 (2002)CrossRef Connell, S.D.A., Allen, S., Roberts, C.J., Davies, J., Davies, M.C., Tendler, S.J.B., Williams, P.M.: Investigating the interfacial properties of single-liquid nanodroplets by atomic force microscopy. Langmuir 18(5), 1719–1728 (2002)CrossRef
46.
Zurück zum Zitat Zhou, X., Wang, F., Lin, H., Ye, Q., Wu, K.: Study on characteristics of micellar-enhanced ultrafiltration using Turkey red oil as an anionic surfactant. Chin. J. Environ. Eng. 05(9), 2070–2074 (2011) Zhou, X., Wang, F., Lin, H., Ye, Q., Wu, K.: Study on characteristics of micellar-enhanced ultrafiltration using Turkey red oil as an anionic surfactant. Chin. J. Environ. Eng. 05(9), 2070–2074 (2011)
Metadaten
Titel
Lubricity and Adsorption of Castor Oil Sulfated Sodium Salt Emulsion Solution on Titanium Alloy
verfasst von
Ye Yang
Chenhui Zhang
Yuanjing Dai
Jianbin Luo
Publikationsdatum
01.06.2019
Verlag
Springer US
Erschienen in
Tribology Letters / Ausgabe 2/2019
Print ISSN: 1023-8883
Elektronische ISSN: 1573-2711
DOI
https://doi.org/10.1007/s11249-019-1173-8

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