Skip to main content
Erschienen in: Journal of Materials Science: Materials in Electronics 10/2019

03.04.2019

Luminescence and energy transfer mechanism of KZnPO4: Dy3+, Eu3+

verfasst von: Ailing Zou, Shixue Sun, Jingjie Yu, Nianyu Zou, Zeqing Hu, Yanjie Zhang

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 10/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Dy3+ -doped and Dy3+/Eu3+ co-doped KZnPO4 phosphors have been successfully synthesized by solid-state method. X-ray diffraction (XRD), photoluminescence spectra and fluorescence lifetime are employed to characterize these samples. It can be indicated from XRD results that KZnPO4 phosphors exhibit pure phase with high crystallinity. Under excitation of 391 nm, Dy3+-doped KZnPO4 phosphors showed two typical emission bands at 485 nm (blue) and 577 nm (yellow). In the case of Dy3+ and Eu3+ co-doped KZnPO4 phosphors, it can be found that color coordinates are sensitive to the Eu3+ concentration due to the red emission from Eu3+ ions. The emission color changes from blue to warm white by increasing the Eu3+ contents. The color coordinates and color temperature were also adjusted by changing the contents of Eu3+ ions. Furthermore, the mechanism of energy transfer from Dy3+ to Eu3+ ions is demonstrated to be quadrupole–quadrupole interaction for the co-doped samples.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat T. Wang, Y.H. Hun, L. Chen, X.J. Wang, M. He, A white-light emitting phosphor LuNbO4: Dy3+ with tunable emission color manipulated by energy transfer from NbO4 3− groups to Dy3+. J. Lumin. 181, 189 (2017)CrossRef T. Wang, Y.H. Hun, L. Chen, X.J. Wang, M. He, A white-light emitting phosphor LuNbO4: Dy3+ with tunable emission color manipulated by energy transfer from NbO4 3− groups to Dy3+. J. Lumin. 181, 189 (2017)CrossRef
2.
Zurück zum Zitat G. Wallez, F. Lucas, J.P. Souron, M. Quarton, Potassium-zinc monophosphate: an original polymorphic, tridymite derivate. Mater. Res. Bull. 34, 1251 (1999)CrossRef G. Wallez, F. Lucas, J.P. Souron, M. Quarton, Potassium-zinc monophosphate: an original polymorphic, tridymite derivate. Mater. Res. Bull. 34, 1251 (1999)CrossRef
3.
Zurück zum Zitat Z.P. Ci, R.N. Guan, L.J. Jin, L.L. Han, J.C. Zhang, J. Ma, Y.H. Wang, Host-sensitized white light-emitting phosphor MgY4Si3O13:Dy3+ with satisfactory thermal properties for UV-LEDs. CrystEngComm 17, 4982 (2015)CrossRef Z.P. Ci, R.N. Guan, L.J. Jin, L.L. Han, J.C. Zhang, J. Ma, Y.H. Wang, Host-sensitized white light-emitting phosphor MgY4Si3O13:Dy3+ with satisfactory thermal properties for UV-LEDs. CrystEngComm 17, 4982 (2015)CrossRef
4.
Zurück zum Zitat Z.C. Wu, J. Liu, W.G. Hou, J. Xu, M.L. Gong, A new single-host white-light emitting BaSrMg(PO4)2:Eu2+ phosphor for white-light-emitting diodes. J. Alloys Compds. 498, 139 (2010)CrossRef Z.C. Wu, J. Liu, W.G. Hou, J. Xu, M.L. Gong, A new single-host white-light emitting BaSrMg(PO4)2:Eu2+ phosphor for white-light-emitting diodes. J. Alloys Compds. 498, 139 (2010)CrossRef
5.
Zurück zum Zitat C.C. Lin, Z.R. Xiao, G.Y. Guo, T.S. Chan, R.S. Liu, Versatile phosphate phosphors ABPO4 in white light-emitting diodes: collocated characteristic analysis and theoretical calculations. J. Am. Chem. Soc. 132, 3020 (2010)CrossRef C.C. Lin, Z.R. Xiao, G.Y. Guo, T.S. Chan, R.S. Liu, Versatile phosphate phosphors ABPO4 in white light-emitting diodes: collocated characteristic analysis and theoretical calculations. J. Am. Chem. Soc. 132, 3020 (2010)CrossRef
6.
Zurück zum Zitat M. Gaft, R. Reisfeld, G. Panczer, S. Shoval, B. Champagnon, G. Boulon, Eu3+ luminescence in high-symmetry sites of natural apatite. J. Lumin. 96, 572 (1997)CrossRef M. Gaft, R. Reisfeld, G. Panczer, S. Shoval, B. Champagnon, G. Boulon, Eu3+ luminescence in high-symmetry sites of natural apatite. J. Lumin. 96, 572 (1997)CrossRef
7.
Zurück zum Zitat H. Zeqing, Y. Guo, J. Zhang, Y. Zhang, Tunable luminescence properties and energy transfer of single-phase Ca4(PO4)2O: Dy3+, Eu2+ multi-color phosphors for warm white light. J. Mater. Sci. 53, 6414 (2018)CrossRef H. Zeqing, Y. Guo, J. Zhang, Y. Zhang, Tunable luminescence properties and energy transfer of single-phase Ca4(PO4)2O: Dy3+, Eu2+ multi-color phosphors for warm white light. J. Mater. Sci. 53, 6414 (2018)CrossRef
8.
Zurück zum Zitat D. Deng, H. Yu, Y. Li, Y. Hua, G. Jia, S. Zhao, H. Wang, L. Huang, Y. Li, C. Li, S. Xu, Ca4(PO4)2O: Eu2+ red-emitting phosphor for solid-state lighting: structure, luminescent properties and white light emitting diode application. J. Mater. Chem. C 1, 3194 (2013)CrossRef D. Deng, H. Yu, Y. Li, Y. Hua, G. Jia, S. Zhao, H. Wang, L. Huang, Y. Li, C. Li, S. Xu, Ca4(PO4)2O: Eu2+ red-emitting phosphor for solid-state lighting: structure, luminescent properties and white light emitting diode application. J. Mater. Chem. C 1, 3194 (2013)CrossRef
9.
Zurück zum Zitat C. Xu, Y. Song, H. Guan, Y. Sheng, P. Ma, X. Zhou, Z. Shi, H. Zou, The photoluminescence, thermal properties and tunable color of Na1-xAl1+2xSi12xO4: xCe3+/Tb3+/Dy3+ via energy transfer: a single-component multicolor-emitting phosphor. Phys. Chem. Chem. Phys. 19, 22197 (2017)CrossRef C. Xu, Y. Song, H. Guan, Y. Sheng, P. Ma, X. Zhou, Z. Shi, H. Zou, The photoluminescence, thermal properties and tunable color of Na1-xAl1+2xSi12xO4: xCe3+/Tb3+/Dy3+ via energy transfer: a single-component multicolor-emitting phosphor. Phys. Chem. Chem. Phys. 19, 22197 (2017)CrossRef
10.
Zurück zum Zitat Y. Wang, J. Ding, Y. Li, L. Yang, X. Ding, Y. Wang, A novel single-phase warm white emission phosphor Sr3YAl2O7.5: Bi3+, Eu3+ with energy transfer for UV white LEDs. RSC Adv. 6, 42618 (2016)CrossRef Y. Wang, J. Ding, Y. Li, L. Yang, X. Ding, Y. Wang, A novel single-phase warm white emission phosphor Sr3YAl2O7.5: Bi3+, Eu3+ with energy transfer for UV white LEDs. RSC Adv. 6, 42618 (2016)CrossRef
11.
Zurück zum Zitat H. Zhu, C.C. Lin, W. Luo, S. Shu, Z. Liu, Y. Liu, J. Kong, E. Ma, Y. Cao, R.S. Liu, X. Chen, Highly efficient non-rare earth red emitting phosphor for warm white light-emitting diodes. Nat. Commun. 5, 4312 (2014)CrossRef H. Zhu, C.C. Lin, W. Luo, S. Shu, Z. Liu, Y. Liu, J. Kong, E. Ma, Y. Cao, R.S. Liu, X. Chen, Highly efficient non-rare earth red emitting phosphor for warm white light-emitting diodes. Nat. Commun. 5, 4312 (2014)CrossRef
12.
Zurück zum Zitat X. Fei Li, T.H. Liu, Solid state synthesis of CaTiO3:Dy3+/Eu3+ phosphors towards white light emission. Chem. Phys. Lett. 686, 78 (2017)CrossRef X. Fei Li, T.H. Liu, Solid state synthesis of CaTiO3:Dy3+/Eu3+ phosphors towards white light emission. Chem. Phys. Lett. 686, 78 (2017)CrossRef
13.
Zurück zum Zitat X. Liu, Y. Liu, D. Yan, H. Zhu, C. Liu, C. Xu, Y. Liu, X. Wang, Single-phased white-emitting 12CaO·7Al2O3:Ce3+, Dy3+ phosphors with suitable electrical conductivity for field emission displays. J. Mater. Chem. 22, 16839 (2012)CrossRef X. Liu, Y. Liu, D. Yan, H. Zhu, C. Liu, C. Xu, Y. Liu, X. Wang, Single-phased white-emitting 12CaO·7Al2O3:Ce3+, Dy3+ phosphors with suitable electrical conductivity for field emission displays. J. Mater. Chem. 22, 16839 (2012)CrossRef
14.
Zurück zum Zitat Y. Zhang, W. Gong, J. Yu, H. Pang, Q. Song, G. Ning, A new single-phase white-light-emitting CaWO4: Dy3+ phosphor: synthesis, luminescence and energy transfer. RSC Adv. 5, 62527 (2015)CrossRef Y. Zhang, W. Gong, J. Yu, H. Pang, Q. Song, G. Ning, A new single-phase white-light-emitting CaWO4: Dy3+ phosphor: synthesis, luminescence and energy transfer. RSC Adv. 5, 62527 (2015)CrossRef
15.
Zurück zum Zitat F. Chen, X. Yuan, F. Zhang, S. Wang, Photoluminescence properties of Sr3(PO4)2: Eu2+, Dy3+ double-emitting blue phosphor for white LEDs. Opt. Mater. 37, 65 (2014)CrossRef F. Chen, X. Yuan, F. Zhang, S. Wang, Photoluminescence properties of Sr3(PO4)2: Eu2+, Dy3+ double-emitting blue phosphor for white LEDs. Opt. Mater. 37, 65 (2014)CrossRef
16.
Zurück zum Zitat K.E. Foka, B.F. Dejene, H.C. Swart, The effect of urea: nitrate ratio on the structure and luminescence properties of YVO4: Dy3+ phosphors. Phys. Lett. B 480, 95 (2016) K.E. Foka, B.F. Dejene, H.C. Swart, The effect of urea: nitrate ratio on the structure and luminescence properties of YVO4: Dy3+ phosphors. Phys. Lett. B 480, 95 (2016)
17.
Zurück zum Zitat S. Dutta, S.K. Sharma, Energy transfer between Dy3+ and Eu3+ in Dy3+/Eu3+-codoped Gd2MoO6. J. Mater. Sci. 51, 6750 (2016)CrossRef S. Dutta, S.K. Sharma, Energy transfer between Dy3+ and Eu3+ in Dy3+/Eu3+-codoped Gd2MoO6. J. Mater. Sci. 51, 6750 (2016)CrossRef
18.
Zurück zum Zitat G. Jyothia, L.S. Kumari, K.G. Gopchandran, White emitting Dy3+ activated perovskite titanates and energy transfer by Eu3+ codoping. Ceram. Int. 43, 12044 (2017)CrossRef G. Jyothia, L.S. Kumari, K.G. Gopchandran, White emitting Dy3+ activated perovskite titanates and energy transfer by Eu3+ codoping. Ceram. Int. 43, 12044 (2017)CrossRef
19.
Zurück zum Zitat M. Fang, P. Liu, M. Liu, F. Li, G.L. Shang, X.X. Gong, G.T. Fei, SrS: Eu2+, Dy3+ nanostructures: morphologies evolution and properties of afterglow. J. Alloys Compds. 639, 149 (2015)CrossRef M. Fang, P. Liu, M. Liu, F. Li, G.L. Shang, X.X. Gong, G.T. Fei, SrS: Eu2+, Dy3+ nanostructures: morphologies evolution and properties of afterglow. J. Alloys Compds. 639, 149 (2015)CrossRef
20.
Zurück zum Zitat S. Das, C.Y. Yang, C.H. Lu, Structural and optical properties of tunable warm-white light-emitting ZrO2:Dy3+-Eu3+ nanocrystals. J. Am. Ceram. Soc. 96, 1602 (2013)CrossRef S. Das, C.Y. Yang, C.H. Lu, Structural and optical properties of tunable warm-white light-emitting ZrO2:Dy3+-Eu3+ nanocrystals. J. Am. Ceram. Soc. 96, 1602 (2013)CrossRef
21.
Zurück zum Zitat J. Gou, J. Wang, S.F. Ye, B.X. Yu, Luminescence and microstructural features of Dy3+-activated KZnPO4 phosphors. Mater. Res. Bull. 70, 827 (2015)CrossRef J. Gou, J. Wang, S.F. Ye, B.X. Yu, Luminescence and microstructural features of Dy3+-activated KZnPO4 phosphors. Mater. Res. Bull. 70, 827 (2015)CrossRef
22.
Zurück zum Zitat S.Y. Zhang, Y.L. Huang, H.J. Seo, The spectroscopy and structural sites of Eu2+ ions doped KCaPO4 phosphor. J. Electrochem. Soc. 157, 261 (2010)CrossRef S.Y. Zhang, Y.L. Huang, H.J. Seo, The spectroscopy and structural sites of Eu2+ ions doped KCaPO4 phosphor. J. Electrochem. Soc. 157, 261 (2010)CrossRef
23.
Zurück zum Zitat B. Elouadi, L. Elammart, Crystal structures and ferroelectric properties of AIBIIPO4 (AI = monovalent cation and BII = divalent cation). Ferroelectrics 107, 253 (1900)CrossRef B. Elouadi, L. Elammart, Crystal structures and ferroelectric properties of AIBIIPO4 (AI = monovalent cation and BII = divalent cation). Ferroelectrics 107, 253 (1900)CrossRef
24.
Zurück zum Zitat S.H.M. Poort, W.P. Blokpoel, G. Blasse, Luminescence of Eu2+ in barium and strontium aluminate and gallate. Chem. Mater. 7, 1547 (1995)CrossRef S.H.M. Poort, W.P. Blokpoel, G. Blasse, Luminescence of Eu2+ in barium and strontium aluminate and gallate. Chem. Mater. 7, 1547 (1995)CrossRef
25.
Zurück zum Zitat T.S. Chan, R.S. Liu, I. Baginskiy, Synthesis, crystal structure, and luminescence properties of a novel green-yellow emitting phosphor LiZn1−xPO4: Mnx for light emitting diodes. Chem. Mater. 20, 1215 (2008)CrossRef T.S. Chan, R.S. Liu, I. Baginskiy, Synthesis, crystal structure, and luminescence properties of a novel green-yellow emitting phosphor LiZn1−xPO4: Mnx for light emitting diodes. Chem. Mater. 20, 1215 (2008)CrossRef
26.
Zurück zum Zitat S. Zhang, Y. Nakai, T. Tsuboi, Y. Huang, Luminescence and microstructural features of Eu-activated LiBaPO4 phosphor. Chem. Mater. 23, 1216 (2011)CrossRef S. Zhang, Y. Nakai, T. Tsuboi, Y. Huang, Luminescence and microstructural features of Eu-activated LiBaPO4 phosphor. Chem. Mater. 23, 1216 (2011)CrossRef
27.
Zurück zum Zitat Y.S. Tang, S.F. Hu, C.C. Lin, N.C. Bagkar, R.S. Liu, Thermally stable luminescence of KSrPO4: Eu2+ phosphor for white light UV light-emitting diodes. Appl. Phys. Lett. 90, 151108 (2007)CrossRef Y.S. Tang, S.F. Hu, C.C. Lin, N.C. Bagkar, R.S. Liu, Thermally stable luminescence of KSrPO4: Eu2+ phosphor for white light UV light-emitting diodes. Appl. Phys. Lett. 90, 151108 (2007)CrossRef
28.
Zurück zum Zitat Z.W. Zhang, A.J. Song, S.T. Song, J.P. Zhang, W.G. Zhang, D.J. Wang, Synthesis and luminescence properties of novel KSrPO4:Dy3+ phosphor. J. Alloys Compds. 629, 32 (2015)CrossRef Z.W. Zhang, A.J. Song, S.T. Song, J.P. Zhang, W.G. Zhang, D.J. Wang, Synthesis and luminescence properties of novel KSrPO4:Dy3+ phosphor. J. Alloys Compds. 629, 32 (2015)CrossRef
29.
Zurück zum Zitat M.P. Hehlen, M.G. Brik, K.W. Krämer, 50th anniversary of the Judd-Ofelt theory: an experimentalist’s view of the formalism and its application. J. Lumin. 136, 221 (2013)CrossRef M.P. Hehlen, M.G. Brik, K.W. Krämer, 50th anniversary of the Judd-Ofelt theory: an experimentalist’s view of the formalism and its application. J. Lumin. 136, 221 (2013)CrossRef
30.
Zurück zum Zitat G. Li, Solid state synthesis and luminescence of NaLa(WO4)2:Dy3+ phosphors. J. Mater. Sci. 27, 11012 (2016) G. Li, Solid state synthesis and luminescence of NaLa(WO4)2:Dy3+ phosphors. J. Mater. Sci. 27, 11012 (2016)
31.
Zurück zum Zitat Q. Mao, Q. Yuan, Z. Ji, J. Xi, Z. Kong, J. Zhang, Effects of boric acid on structural and luminescent properties of BaAl2O4:(Eu2+, Dy3+) phosphors. Res. Chem. Intermediates 42, 6557 (2016)CrossRef Q. Mao, Q. Yuan, Z. Ji, J. Xi, Z. Kong, J. Zhang, Effects of boric acid on structural and luminescent properties of BaAl2O4:(Eu2+, Dy3+) phosphors. Res. Chem. Intermediates 42, 6557 (2016)CrossRef
32.
Zurück zum Zitat B.M. Mothudi, O.M. Ntwaeaborwa, S. S. Pitale, H.C. Swart, Luminescent properties of Ca0.97Al2O4:Eu0.01 Dy 0.02 3+ phosphors prepared by combustion method at different initiating temperatures. J. Alloys Compds. 508, 262 (2010)CrossRef B.M. Mothudi, O.M. Ntwaeaborwa, S. S. Pitale, H.C. Swart, Luminescent properties of Ca0.97Al2O4:Eu0.01 Dy 0.02 3+ phosphors prepared by combustion method at different initiating temperatures. J. Alloys Compds. 508, 262 (2010)CrossRef
33.
Zurück zum Zitat D.L. Dexter, J.H. Schulman, Theory of concentration quenching in inorganic phosphors. J. Chem. Phys. 22, 1063 (1954)CrossRef D.L. Dexter, J.H. Schulman, Theory of concentration quenching in inorganic phosphors. J. Chem. Phys. 22, 1063 (1954)CrossRef
34.
Zurück zum Zitat R. Reisfeld, E. Greenberg, R. Velapoldi, B. Barnett, Luminescence quantum efficiency of Gd and Tb in borate glasses and the mechanism of energy transfer between them. J. Chem. Phys. 56, 1698 (1972)CrossRef R. Reisfeld, E. Greenberg, R. Velapoldi, B. Barnett, Luminescence quantum efficiency of Gd and Tb in borate glasses and the mechanism of energy transfer between them. J. Chem. Phys. 56, 1698 (1972)CrossRef
35.
Zurück zum Zitat Z.Y. Cheng, J.J. Yu, Y.J. Zhang, N.Y. Zou, Luminescence and energy transfer mechanism of α-Ba3Y(BO3)3:Ce3+, Tb3+. J. Lumin. 192, 1004 (2017)CrossRef Z.Y. Cheng, J.J. Yu, Y.J. Zhang, N.Y. Zou, Luminescence and energy transfer mechanism of α-Ba3Y(BO3)3:Ce3+, Tb3+. J. Lumin. 192, 1004 (2017)CrossRef
36.
Zurück zum Zitat P.I. Paulose, G. Jose, V. Thomas, N.V. Unnikrishnan, M.K.R. Warrier, Sensitized fluorescence of Ce3+/Mn2+ system in phosphate glass. J. Phys. Chem. Solids 64, 841 (2003)CrossRef P.I. Paulose, G. Jose, V. Thomas, N.V. Unnikrishnan, M.K.R. Warrier, Sensitized fluorescence of Ce3+/Mn2+ system in phosphate glass. J. Phys. Chem. Solids 64, 841 (2003)CrossRef
Metadaten
Titel
Luminescence and energy transfer mechanism of KZnPO4: Dy3+, Eu3+
verfasst von
Ailing Zou
Shixue Sun
Jingjie Yu
Nianyu Zou
Zeqing Hu
Yanjie Zhang
Publikationsdatum
03.04.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 10/2019
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-01244-w

Weitere Artikel der Ausgabe 10/2019

Journal of Materials Science: Materials in Electronics 10/2019 Zur Ausgabe

Neuer Inhalt