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Journal of Sol-Gel Science and Technology

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24.10.2019 | Original Paper: Sol-gel and hybrid materials with surface modification for applications

Magnetite particles covered by amino-functionalized poly(dimethylsiloxane) network for copper(II) adsorption from aqueous solution

verfasst von: Mariana de Rezende Bonesio, Fábio Luiz Pissetti

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2020

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Abstract

An amino-functionalized poly(dimethylsiloxane) (PDMS) were obtained over magnetite particles. The materials obtained were characterized by Fourier transform infrared spectroscopy (ATR-FTIR), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and thermogravimetric analysis (TGA). ATR-FTIR spectra showed adsorption bands attributed to the amino-functionalized polymeric network and the Fe–O bonds of magnetite, while XRD patterns indicated that magnetite was covered with an amorphous material, the PDMS polymeric network. Thermal analysis showed that the obtained materials were thermally stable up to 300 °C. SEM micrographs revealed that the polymer network coated the magnetite particles, since the surface roughness decrease. Adsorption of Cu(II) was conducted in aqueous medium at different pH values, contact times, and metal ion concentrations. The adsorption capacities obtained were of 0.56, 0.44, and 0.41 mmol L⁻¹ for the materials with a decreasing content of amino group, respectively. Nonlinear kinetic model equations were applied, showing that the materials with lower and higher content of APTMS was described by chemisorption model, while that the intermediary content by a pseudo-second-order fit. The experimental data of adsorption isotherm were studied by various models and Sips model exhibited the best fit for all materials.

Vorheriger Artikel Nano gold coated hierarchically porous zinc titanium oxide sol–gel based thin film: fabrication and photoelectrochemical activity

Nächster Artikel The dispersion and tribological performances of magnesium silicate hydroxide nanoparticles enhanced by Span60 oleogel

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Titel: Magnetite particles covered by amino-functionalized poly(dimethylsiloxane) network for copper(II) adsorption from aqueous solution
verfasst von: Mariana de Rezende Bonesio
Fábio Luiz Pissetti
Publikationsdatum: 24.10.2019
Verlag: Springer US
Erschienen in: Journal of Sol-Gel Science and Technology / Ausgabe 1/2020
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-019-05154-5

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