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Journal of Materials Science
Erschienen in: Journal of Materials Science 15/2018

30.04.2018 | Energy materials

Mangosteen peel-derived porous carbon: synthesis and its application in the sulfur cathode for lithium sulfur battery

verfasst von: Mingzhe Xue, Chen Chen, Yan Tan, Zhiwei Ren, Bing Li, Cunman Zhang

Erschienen in: Journal of Materials Science | Ausgabe 15/2018

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Abstract

Porous carbon with various structures from micropores (< 2 nm) to hierarchical pores (0–4 nm) was synthesized from biomass waste mangosteen peels via KOH activation process. Microporous carbon was obtained mainly at a low activation temperature of 700 °C or a low alkali/carbon of 3. Hierarchical porous carbon with ultrahigh surface area (> 3000 m2 g−1) and pore volume (> 1.4 cm3 g−1) was obtained at alkali/carbon ratio higher than 3.5 and activation temperature of 800 °C. Sulfur with a high content of 65 wt% was able to be fully accommodated into the pores of hierarchical porous carbon to form C/S composite cathode for lithium sulfur battery while in the case of microporous carbon, residual sulfur on carbon surface was detected. High specific discharge capacities of more than 800 mAh g−1 were achieved from hierarchical porous carbon/S composites at 0.5 C, and the sample synthesized at alkali/carbon of 4 and activation of 800 °C exhibits the best cycling performance. After 500 cycles at 0.5 C, a high discharge capacity of 509 mAh g−1 was maintained, indicating an excellent capacity retention. Relationship between pore characteristics of porous carbon and the electrochemical performance of its sulfur composite was discussed.
Vorheriger Artikel Microwave-assisted exfoliation strategy to boost the energy storage capability of carbon fibers for supercapacitors
Nächster Artikel Enhanced lithium and electron diffusion of LiFePO4 cathode with two-dimensional Ti3C2 MXene nanosheets

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Metadaten
Titel
Mangosteen peel-derived porous carbon: synthesis and its application in the sulfur cathode for lithium sulfur battery
verfasst von
Mingzhe Xue
Chen Chen
Yan Tan
Zhiwei Ren
Bing Li
Cunman Zhang
Publikationsdatum
30.04.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 15/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2370-9

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