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2013 | OriginalPaper | Buchkapitel

12. Measurement of Gas Hydrate by Laser Raman Spectrometry

verfasst von : Changling Liu, Qingguo Meng, Yuguang Ye

Erschienen in: Natural Gas Hydrates

Verlag: Springer Berlin Heidelberg

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Abstract

Raman spectrometry is a powerful tool for gas hydrate researches to provide vital information regarding the structure of the hydrate, hydrate composition, and cage occupancy. This chapter begins with discussing the basic knowledge and application of laser Raman spectrometry and then, giving the techniques and methods which have been developed in our laboratory for different experiments of gas hydrate with Raman. The techniques and methods are used for measuring hydration number of methane hydrate prepared under different conditions; investigating the Raman spectra characteristics of air, nitrogen, and oxygen hydrates; and observing methane hydrate dissociation in sediments with different particle sizes. Observation of the microprocesses of hydrate formation and dissociation is also carried out based on a low-temperature high-pressure device for in situ Raman detection. The methods are also successfully used to determinate the natural gas hydrate samples collected from Shenhu area of the South China Sea and from Qilian Mountain permafrost area, respectively, providing microscopic evidences for gas hydrate existence in the sediments.

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Metadaten
Titel
Measurement of Gas Hydrate by Laser Raman Spectrometry
verfasst von
Changling Liu
Qingguo Meng
Yuguang Ye
Copyright-Jahr
2013
Verlag
Springer Berlin Heidelberg
DOI
https://doi.org/10.1007/978-3-642-31101-7_12