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Erschienen in:
Resin Systems and Chemistry: Degradation Mechanisms and Durability Kapitel lesen Erstes Kapitel lesen

2012 | OriginalPaper | Buchkapitel

8. Mechanisms and Kinetics of Organic Matrix Thermal Oxidation

verfasst von : Xavier Colin, Jacques Verdu

Erschienen in: Long-Term Durability of Polymeric Matrix Composites

Verlag: Springer US

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Abstract

It is now well recognized that during thermal aging at moderate temperatures, for example, typically below the glass transition temperature, organic matrix composites perish mainly by matrix embrittlement resulting from its thermo-oxidation. The present chapter aims to briefly introduce this domain. The chapter consists of a brief history of polymer oxidation and description of mechanisms and kinetics. The radical character of oxidation processes; the main elementary steps: propagation, termination, initiation processes, and initial steps; structure–property relationships; the nature of oxidation products; and experimental methods for the study of oxidation mechanisms are also discussed. The standard kinetic scheme, case of oxygen excess and general shape of oxidation kinetic curves, the induction period, departure from Arrhenius law, and case of oxygen lack are described. Consequences of oxidation on matrix thermomechanical properties including chain scission and cross-linking physical approaches are presented.

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Vorheriges Kapitel Physical Aging in Glasses and Composites
Nächstes Kapitel Characterization of Thermo-Oxidation in Laminated and Textile Composites
Literatur
1.
Abdeljaoued, K.: Study of matrix thermal oxidation in carbon fibers-PMR-15 composites, PhD Thesis, ENSAM Paris, 1999.
2.
Achimsky, L., Audouin, L., Verdu, J., Rychla, L., Rychly, J.: The effect of oxygen pressure on the rate of polypropylene oxidation determined by chemiluminescence, Europ. Polym. J. 35, 557–563 (1999).CrossRef
3.
Audouin, L., Langlois, V., Verdu, J., De Bruijn, J.C.M.: Role of oxygen diffusion in polymer aging. Kinetic and mechanistic aspects, J. Mater. Sci. 29, 569–583 (1994).CrossRef
4.
Audouin, L., Gueguen, V., Tcharkhtchi, A., Verdu, J.: Close-loop mechanistic schemes for hydrocarbon polymer oxidation, J. Polym. Sci.: Part A: Polym. Chem. 33, 921–927 (1995).CrossRef
5.
Audouin, L., Achimsky, L., Verdu, J.: Kinetic modelling of low temperature oxidation of hydrocarbon polymers, In: Halim Hamid S. (ed) Handbook of polymer degradation, 2nd edition, chap. 16, pp. 727–763, Marcel Dekker, New York (2000).
6.
Bellenger, V., Morel, E., Verdu, J.: Effect of structure on the glass transition temperature of amine crosslinked epoxies, J. Polym. Sci.: Part B: Polym. Phys. 25, 1219–1234 (1987).CrossRef
7.
Bicerano, J.: Prediction of polymer properties, 3rd edition, chap. 6, p. 212, Marcel Dekker, New York (2002).CrossRef
8.
Bolland, J.L., Gee, G.: Kinetic studies in the chemistry of rubber and related materials. Parts II and III, Trans. Faraday Soc. 42, 236–252 (1946).CrossRef
9.
Bowles, K.J., Meyers, A.: Specimen geometry effects on graphite/PMR-15 composites during their thermo-oxidative aging, In: Proc of the 31st International SAMPE Symposium and Exhibition, vol. 3, pp. 1285–1299. Covina, CA, US (1986).
10.
Bowles, K.J., Nowak, G.: Thermo-oxidative stability studies of Celion 6000/PMR-15 unidirectional composites. PMR-15 and Celion 6000 fiber, J. Compos. Mater. 22(6), 966–985 (1988).CrossRef
11.
Colin, X.: Kinetic modelling of high thermomechanical performances polymer and composite materials, PhD Thesis, ENSAM Paris, 2000.
12.
Colin, X., Marais, C., Verdu, J.: Kinetic modelling and simulation of gravimetric curves. Application to the oxidation of bismaleimide and epoxy resins, Polym. Degrad. Stab. 78(3), 545–553 (2002).CrossRef
13.
Colin, X., Verdu, J.: Thermal ageing and lifetime prediction for organic matrix composites, Plastics Rubber Compos.: Macromol. Eng. 32(8/9), 349–356 (2003).
14.
Colin, X., Marais, C., Verdu, J.: Kinetic modelling of the stabilizing effect of carbon fibers on thermal ageing of thermoset matrix composites, Compos. Sci. Technol. 65, 117–127 (2005a).CrossRef
15.
Colin, X., Mavel, A., Marais, C., Verdu, J.: Interaction between cracking and oxidation in organic matrix composites, J. Compos. Mater. 19(15), 1371–1389 (2005b).CrossRef
16.
Colin, X., Fayolle, B., Audouin, L., Verdu J.: The classical model for radical chain oxidation of hydrocarbon substrates initiated by bimolecular hydroperoxide decomposition, Intern. J. Chem. Kin. 38(11), 666–676 (2006).CrossRef
17.
Colin, X., Audouin, L., Verdu, J.: Kinetic modelling of the thermal oxidation of polyisoprene elastomers. Parts I, II and III, Polym. Degrad. Stab. 92(5), 886–914 (2007).CrossRef
18.
Colin, X., Audouin, L., Verdu, J., Rozental-Evesque, M., Rabaud, B., Martin, F., Bourgine, F.: Aging of polyethylene pipes transporting drinking water disinfected by chlorine dioxide. Parts I and II, Polym. Eng. Sci., 49(7), 1429–1437 (2009) and 49(8), 1642–1652 (2009).
19.
Coquillat, M., Verdu, J., Colin, X., Audouin, L., Nevière, R.: Thermal oxidation of polybutadiene. Parts II and III, Polym. Degrad. Stab. 92(7), 1334–1349 (2007).CrossRef
20.
Crews, L.K., McManus, H.L.: Modelling the high temperature degradation of graphite/epoxy, In: Proc. of the American Society for Composites, 12th Technical Conference on Composite Materials, pp. 1123–1132. Detroit, MI, US (1997).
21.
Cunliffe, A.V., Davis, A.: Photo-oxidation of thick polymer samples, Polym. Degrad. Stab. 4(1), 17–37 (1982).CrossRef
22.
Cunningham, R.A., McManus, H.L.: Coupled diffusion-reaction models for predicting the distribution of degradation in polymer matrix composites, In: Proc. of the ASME Aerospace Division, ASME International Mechanical Engineering Congress and Exposition, Symposium on Composite Materials, vol. 52, p. 353. Atlanta, GA, US (1996).
23.
Denisov, E.T., Afanas’ev, I.B.: Oxidation and antioxidants in organic chemistry and biology, CRC Taylor and Francis, Boca Raton (2005).CrossRef
24.
Di Marzio, E.A.: On the second-(order transition of a rubber, J. Res. NBS: Section A: Phys. Chem. 68, 611–617 (1964).
25.
Fayolle, B., Richaud, E., Colin, X., Verdu, J.: Review: Degradation-induced embrittlement in semi-crystalline polymers having their amorphous phase in rubbery state, J. Mater. Sci. 43, 6999–7012 (2008).CrossRef
26.
Fox, T.G., Flory, P.J.: Second-order transition temperatures and related properties of polystyrene. I. Influence of molecular weight, J. Appl. Phys. 21, 581–591 (1950).CrossRef
27.
Furneaux, G.C., Ledbury K.J., Davis, A.: Photo-oxidation of thick polymer samples. Part I: The variation of photo-oxidation with depth in naturally and artificially weathered low density polyethylene, Polym. Degrad. Stab. 3(6), 431–442 (1981).CrossRef
28.
Gilbert, D.G., Ashby, M.F., Beaumont, P.W.R.: Modulus maps for amorphous polymers, J. Mater. Sci. 21, 3194–3210 (1986).CrossRef
29.
Gillen, K.T., Wise, J., Clough, R.L.: General solution for the basic autoxidation scheme, Polym. Degrad. Stab. 47, 149–161 (1995).CrossRef
30.
Golike, R.C., Lasoski, S.W.: Kinetics of hydrolysis of polyethylene terephthalate films, J. Phys. Chem. 64, 895–898 (1960).CrossRef
31.
Korcek, S., Chenier, J.H.B., Howard, J.A., Ingold, K.U.: Absolute rate constants for hydrocarbon autoxidation. XXI: Activation energies for propagation and the correlation of propagation rate constants with carbon-hydrogen bond strengths, Can. J. Chem. 50, 2285–2297 (1972).CrossRef
32.
Le Huy, M., Bellenger, V., Paris, M., Verdu, J.: Thermal oxidation of anhydride cured epoxies. Part I, II and III, Polym. Degrad. Stab. 35, 77–86 (1992), 35, 171–179 (1992) and 41(2), 149–156 (1993).CrossRef
33.
Nam, J.D., Seferis, J.C.: Anisotropic thermo-oxidative stability of carbon fiber reinforced polymeric composites, SAMPE Quart. 24(1), 10–18 (1992).
34.
Nelson, J.B.: Thermal aging of graphite/polyimide composites. In: O’Brien, T.K. (ed) Long term behaviour of composites, ASTM STP 813, pp. 206–221. American Society for Testing and Materials, Philadelphia, (1983).CrossRef
35.
Pascault, J.-P., Sautereau, H., Verdu, J., Williams, R.J.J.: Thermosetting Polymers. Marcel Dekker, New York (2002).CrossRef
36.
Putthanarat, S., Tandon, G.P., Schoeppner, G.A.: Influence of polishing time on thermooxidation characterization of isothermally aged PMR-15 resin, Polym. Degrad. Stab. 92, 2110–2120 (2007).CrossRef
37.
Rasoldier, N., Colin, X., Verdu, J., Bocquet, M., Olivier, L., Chocinski-Arnault, L., Lafarie-Frenot, M.-C.: Model systems for thermo-oxidized composites matrices, Composites: Part A: Applied Science and Manufacturing 39, 1522–1529 (2008).CrossRef
38.
Reich, L., Stivala, S.S.: Autoxidation of hydrocarbons and polyolefins. Kinetics and mechanisms, Marcel Dekker, New York (1969).
39.
Richaud, E., Colin, X., Fayolle, B., Verdu, J.: Induction period in the low temperature thermal oxidation of saturated hydrocarbons. Example of polyethylene, Intern. J. Chem. Kin. 40(12), 769–777 (2008).CrossRef
40.
Rincon-Rubio, L.M., Fayolle, B., Audouin, L., Verdu, J.: A general solution of closed-loop kinetic scheme for the thermal oxidation of polypropylene, Polym. Degrad. Stab. 74(1), 177–188 (2001).CrossRef
41.
Rincon-Rubio, L.M., Colin, X., Audouin, L., Verdu, J.: A theoretical model for the diffusion-limited thermal oxidation of elastomers at medium temperatures, Rubber Chem. Technol. 76(2), 460–482 (2003).CrossRef
42.
Rychly, J., Matisova-Rychla, L., Csomorova, K., Achimsky, L., Audouin, L., Tcharkhtchi, A., Verdu, J.: Kinetics of mass changes in oxidation of polypropylene, Polym. Degrad. Stab. 58, 269–274 (1997).CrossRef
43.
Salin, I.M., Seferis, J.C.: Anisotropic effects in thermogravimetry of polymeric composites, J. Polym. Sci.: Part B: Polym Phys. 31, 1019–1027 (1993).CrossRef
44.
Seferis, J.C.: Aging analyses of polymer composites through time-temperature equivalence. In: Reifsnider, K.L., Dillard, D.A., Cardon, A. (eds) Progress in durability analysis of composite systems, pp. 193–201, Balkema, Rotterdam (1998).
45.
Seguchi, T., Hashimoto, S., Arakawa, K., Hayakawa, N., Kawakami, W., Kuriyama, I.: Radiation induced oxidative degradation of polymers. Part I: Oxidation region in polymeric films irradiated in oxygen under pressure, Radiat. Phys. Chem. 17(4), 195–201 (1981).
46.
Semenov, N.M.: Chemical kinetics and chain reactions, Oxford University Press, London (1935).
47.
Skontorp, A., Wong, M.S., Wang, S.S.: High temperature anisotropic thermal oxidation of carbon fiber reinforced polyimide composites. Theory and experiments, In: Street, K., Poursartip, A. (eds) Proc. of ICCM-10, 10th International Conference on Composite Materials, vol. 4, pp. 375–382. Whistler, BC, Canada (1995).
48.
Smith, Vale: Chimie et Industrie (Paris) 105(18), 1179 (1972).
49.
Sommersall, A.C., Guillet, J.E.: Computer modelling studies of polymer photooxidation and stabilization. In: Klemchuk, P.P. (ed) Polymer stabilization and degradation, chap. 16, pp. 211–234, American Chemical Society, Washington, DC (1985).CrossRef
50.
Swern, D.: Organic peroxides, vols 1 and 2, Wiley-Interscience, New York (1971).
51.
Tobolsky, A.V., Metz, D.J., Mesrobian, R.B.: Low temperature oxidation of hydrocarbons. The phenomenon of maximum rates, J. Amer. Chem. Soc. 72, 1942–1952 (1950).CrossRef
Metadaten
Titel
Mechanisms and Kinetics of Organic Matrix Thermal Oxidation
verfasst von
Xavier Colin
Jacques Verdu
Copyright-Jahr
2012
Verlag
Springer US
Buch
Long-Term Durability of Polymeric Matrix Composites

Print ISBN: 978-1-4419-9307-6

Electronic ISBN: 978-1-4419-9308-3

Copyright-Jahr: 2012

DOI
https://doi.org/10.1007/978-1-4419-9308-3_8

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