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Topics in Catalysis
Erschienen in: Topics in Catalysis 18-19/2018

25.08.2018 | Original Paper

Metal-Free Catalytic Wet Oxidation: From Powder to Structured Catalyst Using N-Doped Carbon Nanotubes

verfasst von: Raquel P. Rocha, Diogo F. M. Santos, Olívia Salomé M. P. Soares, Adrián M. T. Silva, Manuel Fernando R. Pereira, José L. Figueiredo

Erschienen in: Topics in Catalysis | Ausgabe 18-19/2018

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Abstract

This work shows a promising N-doped carbon catalyst for the oxidation of oxalic acid by catalytic wet oxidation, which is able to compete with the traditional noble metal and metal oxide catalysts used in the process. After preliminary studies conducted in batch mode, the catalytic performance of the metal-free carbon nanotubes, both in powder form and supported on a macrostructured carrier (a cordierite monolith), was evaluated under continuous operating conditions. The ability of the N-functionalities to promote activation and chemisorption of oxygen led not only to fast oxalic acid mineralization under batch mode (5 min of reaction to reach full mineralization), but also to good performance under continuous operation (more than 90% conversion of oxalic acid in the steady state, using the powder and around 55% using the catalyst immobilized on a honeycomb cordierite monolith).
Vorheriger Artikel Cobalt-Catalyzed Green Cross-Dehydrogenative C(sp2)-H/P-H Coupling Reactions
Nächster Artikel Mechanistic Study of the NO + NH4NO3 Reaction on H- and Fe/H-BEA Zeolites Using 15N and 18O Labeled Species

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Metadaten
Titel
Metal-Free Catalytic Wet Oxidation: From Powder to Structured Catalyst Using N-Doped Carbon Nanotubes
verfasst von
Raquel P. Rocha
Diogo F. M. Santos
Olívia Salomé M. P. Soares
Adrián M. T. Silva
Manuel Fernando R. Pereira
José L. Figueiredo
Publikationsdatum
25.08.2018
Verlag
Springer US
Erschienen in
Topics in Catalysis / Ausgabe 18-19/2018
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-018-1029-8

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