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Journal of Materials Science

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29.03.2021 | Metals & corrosion

Metastable phase diagram on heating in quenched Ti-Nb high-temperature shape memory alloys

verfasst von: Jian Zhang, Yanjie Li, Wei Li

Erschienen in: Journal of Materials Science | Ausgabe 19/2021

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Abstract

Metastable phase diagrams of β (BCC)-Ti high-temperature shape memory alloys (HTSMAs) have been investigated extensively, where however β→isothermal ω (iso-ω, hexagonal) transition upon heating has not been accessed. Following α” (orthorhombic)→β reverse martensitic transformation on heating, iso-ω precipitation is commonly encountered. These two transitions may overlap within certain composition range, but have not been clearly differentiated. It is of vital importance for the understanding of the subsequent transition behaviors. In this paper, phase transformations upon heating at various heating rates were characterized in quenched Ti-(16–25 at.%)Nb HTSMAs. In contrast to the linear increase in A_s (the starting temperature of α”→β transition) with decreasing Nb-content, ω_s (the starting temperature of β→iso-ω transition) exhibits normal decrease firstly and shows abnormal increase below 20Nb. It is because iso-ω precipitates only in the reversed β phase but not in α” martensite proved by transmission electron microscopy observations. Namely, β→iso-ω transition is postponed to higher temperature due to the suppression of α” martensite below 20Nb. On this basis, the characteristics of both transformations can be determined for Ti-Nb below 20Nb by proper peak deconvolution. New metastable phase diagrams of Ti-Nb are formulated, including both α”→β and β→iso-ω transitions upon heating. Moreover, effective activation energies for β→iso-ω transition during isochronal annealing are determined by the Kissinger method.

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Vorheriger Artikel Influence of mutual substitution between Cu and Ti on phase components, microstructures, and compressive properties of AlFeNiV–Cu/Ti alloys

Nächster Artikel Effect of aging temperature on the heterogeneous microstructure and mechanical properties of a 12Cr–10Ni–Mo–Ti maraging steel for cryogenic applications

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Titel: Metastable phase diagram on heating in quenched Ti-Nb high-temperature shape memory alloys
verfasst von: Jian Zhang
Yanjie Li
Wei Li
Publikationsdatum: 29.03.2021
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 19/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-021-05814-4

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