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Journal of Materials Science
Erschienen in: Journal of Materials Science 23/2017

20.08.2017 | Metals

Metastable quasicrystals in Al–Mn alloys containing copper, magnesium and silicon

verfasst von: Iztok Naglič, Zoran Samardžija, Kemal Delijić, Spomenka Kobe, Jean-Marie Dubois, Blaž Leskovar, Boštjan Markoli

Erschienen in: Journal of Materials Science | Ausgabe 23/2017

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Abstract

We prepared three Al–Mn-based alloys with different copper, magnesium and silicon contents by casting into cylindrical copper molds. All the alloys exhibited primary metastable quasicrystals (QCs). In order to confirm the presence of either primary decagonal QCs (dQCs) or icosahedral QCs (iQCs) and to determine their compositions, the castings were characterized by means of light microscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy (EDS), electron-backscatter diffraction and X-ray diffraction. The dQCs are present in the Al–Mn-based alloys containing copper. In the case of the combined presence of copper and magnesium, iQCs are present in the edge region and dQCs are present in the central region. In the alloy containing copper, magnesium and silicon, iQCs are present in the casting. The average metallic radius (AMR) and electron-to-atom ratio of these primary phases were calculated by taking into account the composition of these primary phases, as determined by EDS. The AMR shows different values in the cases of dQCs and iQCs. Equal mean values of the AMR were found in iQCs with markedly different compositions. Furthermore, all the metastable QCs in this work show electron concentrations close to 2.6.
Vorheriger Artikel Gold thickness impact on the enhancement of SERS detection in low-cost Au/Si nanosensors
Nächster Artikel Unidirectional freezing as a tool for tailoring air permeability in macroporous poly(ethylene glycol)-based cross-linked networks

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Metadaten
Titel
Metastable quasicrystals in Al–Mn alloys containing copper, magnesium and silicon
verfasst von
Iztok Naglič
Zoran Samardžija
Kemal Delijić
Spomenka Kobe
Jean-Marie Dubois
Blaž Leskovar
Boštjan Markoli
Publikationsdatum
20.08.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 23/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1477-8

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