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Journal of Materials Science
Erschienen in: Journal of Materials Science 12/2016

28.03.2016 | Original Paper

Microcrystalline cellulose property–structure effects in high-pressure fluidization: microfibril characteristics

Erschienen in: Journal of Materials Science | Ausgabe 12/2016

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Abstract

The raw material properties and characteristics of four different microfibrillated celluloses (MFCs) produced by microfluidizing were investigated. The cellulose materials were never-dried and dried microcrystalline cellulose (MCC), a commercial MCC, and an enzymatic-mechanically treated softwood sulfite pulp. The study comprises extensive initial and final physical, structural, and molecular-level analyses. The results indicated that raw material properties related to both fibril aggregation, structural compaction levels and geometric heterogeneity and interaction levels essentially affected both the process and the final MFC properties. The increase in specific surface area (SSA) was minor for the enzymatic-mechanically treated raw material, while MCC showed a larger increase of several orders of magnitude in SSA. The drying of particulate MCC was reflected both in improved fibrillation efficiency and in the final MFC properties, primarily observed as enhanced SSA, in fibril dimensions and in gel strength. The feed consistency (7.5 %) applicable with dried, particulate MCC in fluidization was more than any of those hitherto reported. The study indicated that MCC can facilitate energy-efficient MFC production with the application of fluidization technology.
Vorheriger Artikel Strength prediction for bi-axial braided composites by a multi-scale modelling approach
Nächster Artikel Effects of different fatty acid ligands on the synthesis of CdSe nanocrystals

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Literatur
1.
Taniguchi T, Okamura K (1998) New films produced from microfibrillated natural fibres. Polym Int 47:291–294CrossRef
2.
Iwamoto S, Abe K, Yano H (2008) The effect of hemicelluloses on wood pulp nanofibrillation and nanofiber network characteristics. Biomacromolecules 9:1022–1026CrossRef
3.
Qing Y, Sabo R, Zhy JY, Agarwal U, Cai Z, Wu Y (2013) A comparative study of cellulose nanofibrils disintegrated via multiple processing approaches. Carbohydr Polym 97:226–234CrossRef
4.
Zimmermann T, Pöhler E, Geiger T (2004) Cellulose fibrils for polymer reinforcement. Adv Eng Mater 6:754–761CrossRef
5.
Ahola S, Salmi J, Johansson L-S, Laine J, Österberg M (2008) Model films from native cellulose nanofibrils. Preparation, swelling, and surface interactions. Biomacromolecules 9:1273–1282CrossRef
6.
Charani PR, Dehghani Dehghani-Firouzabadi M, Afra E, Blademo Å, Naderi A, Lindström T (2013) Production of microfibrillated cellulose from unbleached kraft pulp of Kenaf and Scotch Pine and its effect on the properties of hardwood kraft: microfibrillated cellulose paper. Cellulose 20:2559–2567CrossRef
7.
Wichmann J-U, Øivind H (2008) Method for producing microfibrillated cellulose. European patent application EP 2196579A1, 9 Dec 2008, 708
8.
Dufresne A, Cavaillé J-Y, Vignon MR (1997) Mechanical behavior of sheets prepared from sugar beet cellulose microfibrils. J Appl Polym Sci 64:1185–1194CrossRef
9.
Andresen M, Johansson L-S, Tanem BS, Stenius P (2006) Properties and characterization of hydrophobized microfibrillated cellulose. Cellulose 13:665–677CrossRef
10.
Herrick FW, Casebier RL, Hamilton JK, Sandberg KR (1983) Microfibrillated cellulose: morphology and accessibility. J Appl Polym Sci 37:797–813
11.
Turbak AF, Snyder FW, Sandberg KR (1983) Microfibrillated cellulose, a new cellulose product: properties uses, and commercial potential. J Appl Polym Sci 37:815–827
12.
Lavoine N, Desloges I, Dufresne A, Bras J (2012) Microfibrillated cellulose—Its barrier properties and applications in cellulosic materials: a review. Carbohydr Polym 90:735–764CrossRef
13.
Gullichsen J (1999) Principles of wood chip delignification. In: Gullichsen J, Fogelholm CJ (eds) Chemical pulping 6a, 1st edn. Fapet, Helsinki, pp 19–104
14.
Ankerfors M (2012) Microfibrillated cellulose: energy-efficient preparation techniques and key properties. Licentiate thesis, KTH Royal Institute of Technology, pp 1–49
15.
Lundin T (2008) Tailoring pulp fiber properties in low consistency refining. DSc dissertation, Åbo Akademi University, pp 1–259
16.
Charani PR, Dehghani-Firouzabadi, Afra E, Shakeri A (2013) Rheological characterization of high concentrated MFC gel from kenaf unbleached pulp. Cellulose 20:727–740CrossRef
17.
Pääkkö M, Ankerfors M, Kosonen H, Nykänen A, Ahola S, Österberg M, Ruokolainen J, Laine J, Larsson PT, Ikkala O, Linström T (2007) Enzymatic hydrolysis combined with mechanical shearing and high-pressure homogenization for nanoscale cellulose fibrils and strong gels. Biomacromolecules 8:1934–1941CrossRef
18.
Saito T, Nishiyama Y, Putaux J-L, Vignon M, Isogai A (2006) Homogeneous suspensions of individualized microfibrils from TEMPO-catalyzed oxidation of native cellulose. Biomacromolecules 7:1687–1691CrossRef
19.
Pääkkönen T, Vuorinen T, Nuopponen M (2011) Method for catalytic oxidation of cellulose and method for making a cellulose product. International patent application WO 2012168562A1, pp 1–55, 9 Jun 2011
20.
Wågberg L, Decher G, Norgren M, Linström T, Ankerfors M, Axnäs K (2008) The build-Up of polyelectrolyte multilayers of microfibrillated cellulose and cationic polyelectrolytes. Langmuir 24:784–795CrossRef
21.
Siro I, Plackett D, Hedenqvist M, Ankerfors M, Lindström T (2011) Highly transparent films from carboxymethylated microfibrillated cellulose: the effect of multiple homogenization steps on key properties. J Appl Polym Sci 119:2652–2660CrossRef
22.
Paltakari J, Laine J, Österberg M, Ramjee S, Teirfolk J-E (2009) A method for producing modified cellulose. International patent application WO 2010092239A1, 1–36, 13 Feb 2009
23.
Ankerfors M, Lindström T (2009) Method for providing a nanocellulose involving modified cellulose fibers. International patent application WO 2009126106A1, pp 1–27, 10 Apr 2008
24.
Beghello L (1998) Some factors that influence fibre flocculation. Nord Pulp Paper Res J 13:274–279CrossRef
25.
Derakhshandeh B, Kerekes RJ, Hatzikiriakos SG, Bennington CPJ (2011) Rheology of pulp fibre suspensions: a critical review. Chem Eng Sci 66:3460–3470CrossRef
26.
Gullichsen J, Harkonen E (1981) Medium consistency technology. Tappi J 64:69–72
27.
Kerekes RJ, Soszynski RM, Doo PAT (1985) The flocculation of pulp fibres. Proceedings of the 8th fundamental research symposium. Mechanical Engineering Publications, Oxford, pp 265–310
28.
Tuason DC, Krawczyk GR, Buliga G (2009) Microcrystalline cellulose. In: Imeson A (ed) Food stabilisers, thickeners and gelling agents, 1st edn. Wiley, Oxford, pp 218–236CrossRef
29.
Battista OA (1975) Colloidal microcrystalline celluloses. In: Turbak AF (ed) Cellulose technology research, vol 10. ACS Symposium Series, Washington, pp 1–8CrossRef
30.
Yokota H, Okumura Y (1984) Homogenization of microcrystalline cellulose suspension. Japan patent JP 59120638, pp 1–5, 12 Jul 1984
31.
Kleinebudde P (2000) Influence of degree of polymerization on behavior of cellulose during homogenization and extrusion/spheronization. AAPS PharmSci 2:1–10CrossRef
32.
Jacquet N, Vanderghem C, Danthine S, Blecker C, Paquet M (2012) Influence of homogenization treatment on physicochemical properties and enzymatic hydrolysis rate of pure cellulose fibers. Appl Biochem Biotech 169:1315–1328CrossRef
33.
Lee S-Y, Chun S-J, Kang I-A, Park J-Y (2009) Preparation of cellulose nanofibrils by high-pressure homogenizer and cellulose-based composite films. J Ind Eng Chem 15:50–55CrossRef
34.
Diniz FJMB, Gil MH, Castro JAAM (2004) Hornification—its origin and interpretation in wood pulps. Wood Sci Technol 37:489–494CrossRef
35.
Newman RH (2004) Carbon-13 NMR evidence for cocrystallization of cellulose as a mechanism for hornification of bleached kraft pulp. Cellulose 11:45–52CrossRef
36.
Dahl O, Vanhatalo K, Parviainen K (2011) A novel method to produce microcellulose. International patent application WO 2011154600, pp 1–27, 7 Jun 2011
37.
Vanhatalo K, Dahl O (2014) Effect of mild acid hydrolysis parameters on properties of microcrystalline cellulose. Bioresources 9:4729–4740
38.
Henriksson M, Henriksson G, Berglund LA, Lindström T (2007) An environmentally friendly method for enzyme-assisted preparation of microfibrillated cellulose (MFC) nanofibers. Eur Polym J 43:3434–3441CrossRef
39.
Marx-Figini M (1978) Significance of the intrinsic viscosity ratio of unsubstituted and nitrated cellulose in different solvents. Angew Makromol Chem 72:161–171CrossRef
40.
Gruber E, Gruber R (1981) Viskosimetrische bestimmung des polymerisationsgrades von cellulose. Das Papier 35:133–141
41.
Segal L, Creely JJ, Martin AE, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29:786–794CrossRef
42.
Krässig HA (1993) Methods of fiber structure characterization chapter 3. In: Huglin MB (ed) Cellulose: structure, accessibility and reactivity, polymer monographs, vol 11. Gordon and Breach Science Publishers, Philadelphia, pp 43–149
43.
Testova L, Borrega M, Tolonen LK, Penttilä PP, Serimaa R, Larsson PT, Sixta H (2014) Dissolving-grade birch pulps produced under various prehydrolysis intensities: quality, structure and applications. Cellulose 21:2007–2021CrossRef
44.
Kangas H, Lahtinen P, Sneck A, Saariaho A-M, Laitinen O, Hellén E (2014) Characterization of fibrillated celluloses. A short review and evaluation of characteristics with a combination of methods. Nord Pulp Pap Res J 29:129–143CrossRef
45.
Park S, Venditti RA, Jameel H, Pawlak JJ (2005) Measurement of fiber hornification using high resolution thermogravimetric analysis. In: Proceedings of the TAPPI engineering pulping and environmental conference, TAPPI Press, Philadelphia, pp 30–35, August 28–31
46.
Sczostak A (2009) Cotton linters: an alternative cellulosic raw material. Macromol Symp 280:45–53CrossRef
47.
Fan LT, Gharpuray MM, Lee YH (1987) Nature of cellulosic material. In: Aiba S, Fan LT, Fiechter A, Klein J, Schügerl K (eds) Cellulose hydrolysis. Springer, Berlin, pp 5–19CrossRef
48.
Sirviö T (2008) Fibres and bonds. In: Niskanen K (ed) Paper physics 16, 2nd edn. Fapet, Helsinki, pp 59–92
49.
Microfluidized Corporation (2015) Microfluidizer® processor used guide—innovation through microfluidizer™ processor technology, pp 1–10
50.
Battista OA, Coppick S, Howsmon JA, Morehead FF, Sisson WA (1956) Level-off degree of polymerization. Ind Eng Chem 48:333–335CrossRef
51.
Salajkova M, Valentini L, Zhou Q, Berglund LA (2013) Tough nanopaper structures based on cellulose nanofibers and carbon nanotubes. Compos Sci Technol 87:103–110CrossRef
52.
Eronen P, Österberg M, Heikkinen S, Tenkanen M, Laine J (2011) Interactions of structurally different hemicelluloses with nanofibrillar cellulose. Carbohydr Polym 86:1281–1290CrossRef
53.
Pöhler T, Lappalainen T, Tammelin T, Eronen P, Hiekkataipale P, Vehniäinen A, Koskinen TM (2010) Influence of fibrillation method on the character of nanofibrillated cellulose (NFC). TAPPI International conference on nanotechnology for the forest product industry. Dipoli Congress Centre, Espoo, pp 27–29
54.
Li Q, Renneckar S (2009) Molecularly thin nanoparticles from cellulose: isolation of sub-microfibrillar structures. Cellulose 16:1025–1032CrossRef
55.
Leppänen K, Andersson S, Torkkeli M, Knaapila M, Kotelnikova N, Serimaa R (2009) Structure of cellulose and microcrystalline cellulose from various wood species, cotton and flax studied by X-ray scattering. Cellulose 16:999–1015CrossRef
56.
Zografi G, Kontny MJ, Yang AYS, Brenner GS (1984) Surf ace area and water vapor sorption of microcrystalline cellulose. Int J Pharm 18:117–125CrossRef
57.
Steele DF, Moreton RC, Staniforth JN, Young PM, Tobyn MJ, Edge S (2008) Surface energy of microcrystalline cellulose determined by capillary intrusion and inverse gas chromatography. AAPS J 10:494–503CrossRef
58.
Luukkonen P, Schaefer T, Hellen L, Juppo AM, Ylikruusi J (1999) Rheological characterization of microcrystalline cellulose and silicified microcrystalline cellulose wet masses using a mixer torque rheometer. Int J Phar 188:181–192CrossRef
59.
Page DH, Barbe MC, Seth RS, Jordan BD (1983) Mechanism of curl creation, removal and retention in pulp fibers. In: Proceedings of the TAPPl international mechanical pulping conference, Washington DC, pp 271–275
60.
Hartler N (1995) Aspects on curled and microcompressed fibers. Nord Pulp Paper Res J 10:4–7CrossRef
61.
Barnes HA, Hutton JF, Walters K (1989) An introduction to rheology. Elsevier Science Publishers, Amsterdam
62.
Vable M (2002) Mechanical Properties of Materials. In: Vable M (ed) Mechanics of materials. Oxford University Press, Oxford
63.
Karato SI (2009) Theory of lattice strain in a material undergoing plastic deformation: basic formulation and applications to a cubic crystal. Phys Rev B 79:214106CrossRef
64.
Spence KL, Venditti RA, Rojas OJ, Habibi Y, Pawlak JJ (2011) A comparative study of energy consumption and physical properties of microfibrillated cellulose produced by different processing methods. Cellulose 18:1097–1111CrossRef
65.
Kontturi E, Vuorinen T (2009) Indirect evidence of supramolecular changes within cellulose microfibrils of chemical pulp fibers upon drying. Cellulose 16:65–74CrossRef
66.
Iwamoto S, Nakagaito AN, Yano H (2007) Nano-fibrillation of pulp fibers for the processing of transparent nanocomposites. Appl Phys A 89:461–466CrossRef
67.
Alila S, Besbes I, Vilar MR, Mutje P, Boufi S (2013) Non-woody plants as raw materials for production of microfibrillated cellulose (MFC): a comparative study. Ind Crop Prod 41:250–259CrossRef
68.
Liimatainen H, Sirviö J, Haapala A, Hormi O, Niinimäki J (2011) Characterization of highly accessible cellulose microfibers generated by wet stirred media milling. Carbohydr Polym 83:2005–2010CrossRef
69.
Uetani K, Yano H (2011) Nanofibrillation of wood pulp using a high-speed blender. Biomacromolecules 12:348–353CrossRef
70.
Csiszár E, Fekete E, Tóth A, Bandi E, Koczkac B, Sajó I (2013) Effect of particle size on the surface properties and morphology of ground flax. Carbohydr Polym 94:927–933CrossRef
71.
Zhang L, Tsuzuki T, Wanf X (2015) Preparation of cellulose nanofiber from softwood pulp by ball milling. Cellulose 22:1729–1741CrossRef
72.
Wang QQ, Zhy JY, Gleisner R, Kuster TA, Baxa U, McNeil SE (2012) Morphological development of cellulose fibrils of a bleached eucalyptus pulp by mechanical fibrillation. Cellulose 19:1631–1643CrossRef
73.
Battista AO (1950) Hydrolysis and crystallization of cellulose. Ind Eng Chem 42:502–507CrossRef
74.
Sen SK, Baheti VK, Venditti RA, Pawlak JJ, Park S, Bansal MC (2012) Cellulose microfibril–water interaction as characterized by isothermal thermogravimetric analysis and scanning electron microscopy. Bioresources 7:4683–4703
75.
Spence KL, Venditti RA, Rojas OJ, Habibi Y, Pawlak JJ (2010) The effect of chemical composition on microfibrillar cellulose films from wood pulps: water interactions and physical properties for packaging applications. Cellulose 17:835–848CrossRef
76.
Deinert MR, Dathe A, Parlange J-Y, Cady KB (2008) Capillary pressure in a porous medium with distinct pore surface and pore volume fractal dimensions. Phys Rev B 77:021203CrossRef
77.
Yano H, Nakahara S (2004) Bio-composites produced from plant microfiber bundles with a nanometer unit web-like network. J Mater Sci 39:1635–1638CrossRef
78.
Nair SS, Zhou JY, Deng Y, Ragauskas AJ (2014) Characterization of cellulose nanofibrillation by micro grinding. J Nanopart Res 16:2348–2349CrossRef
79.
Thanomchat S, Srikulkit K, Suksut B, Schlarb AK (2014) Morphology and crystallization of polypropylene/microfibrillated cellulose composites. Int J Appl Sci Technol 7:23–34
Metadaten
Titel
Microcrystalline cellulose property–structure effects in high-pressure fluidization: microfibril characteristics
Publikationsdatum
28.03.2016
Erschienen in
Journal of Materials Science / Ausgabe 12/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-9907-6

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