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Polymer Bulletin

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04.12.2017 | Original Paper

Microphase separation and thermo-mechanical properties of energetic poly(urethane–urea)

verfasst von: Jie Lv, Jizhen Huo, Ye Yang, Yingfeng Yu, Guozhu Zhan, Huikun Zhang

Erschienen in: Polymer Bulletin | Ausgabe 9/2018

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Abstract

In this paper, the phase segregation and thermo-mechanical properties of energetic poly(urethane–urea) (EPUU) for propellant binder application are analyzed. Series of EPUUs are synthesized from copolymer of 3,3-bis-azido methyl oxetane and tetrahydrofuran, tolylene diisocyanate, and 3,3′-dichloro-4,4′-dianilino methane, with different hard segment contents ranging from 9.7 to 38%. With the enlargement of hard segment content from 9.7 to 28.9% (EPUU1–EPUU3), the percentage of ordered part via hydrogen-bonded C=O in urea increases as investigated by FTIR, further increase of hard segment content to 38% results in less hydrogen-bonded ordered part but more disordered part. The SAXS result also verifies the highest degree of phase segregation of EPUU3. The thermo-mechanical properties of energetic poly(urethane–urea) are related to the degree of microphase separation. With the increase of hard segment content, the tensile strength increases roughly, while the elongation at break drops from EPUU1 to EPUU4. EPUU3 exhibits the highest value of tensile strength and acceptable elongation at break.

Vorheriger Artikel Effect of interface in dielectric relaxation properties of PEMA–BaZrO3 nanocomposites

Nächster Artikel Thermal decomposition kinetics and dielectric properties of polyurethane grafted onto PEMA-co-PHEMA

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Pisharath S, Ang HG (2007) Synthesis and thermal decomposition of GAP-Poly(BAMO) copolymer. Polym Degrad Stabil 92(7):1365–1377. https://doi.org/10.1016/j.polymdegradstab.2007.03.016 CrossRef

Zhang ZJ, Wang G, Wang Z, Zhang YL, Ge Z, Luo YJ (2015) Synthesis and characterization of novel energetic thermoplastic elastomers based on glycidyl azide polymer (GAP) with bonding functions. Polym Bull 72(8):1835–1847. https://doi.org/10.1007/s00289-015-1375-7 CrossRef

Badgujar DM, Talawar MB, Asthana SN, Mahulikar PP (2008) Advances in science and technology of modern energetic materials: an overview. J Hazard Mater 151(2–3):289–305. https://doi.org/10.1016/j.jhazmat.2007.10.039 CrossRefPubMed

Cheradame H, Andreolety JP, Rousset E (1991) Synthesis of polymers containing pseudohalide groups by cationic polymerization. 1. Homopolymerization of 3,3-bis(azidomethyl)oxetane and its copolymerization with 3-chloromethyl-3-(2,5,8-trioxadecyl)oxetane. Makromol Chem 192(4):901–918CrossRef

Zhang C, Li J, Luo YJ, Zhai B (2015) Preparation and property studies of carbon nanotubes covalent modified BAMO-AMMO energetic binders. J Energ Mater 33(4):305–314. https://doi.org/10.1080/07370652.2014.990588 CrossRef

Kubota N, Sonobe T, Yamamoto A, Shimizu H (1990) Burning rate characteristics of GAP propellants. J Propul Power 6(6):686–689CrossRef

Frankel M, Grant L, Flanagan J (1992) Historical development of glycidyl azide polymer. J Propul Power 8(3):560–563CrossRef

Nair JK, Satpute RS, Polke BG, Mukundan T, Asthana SN, Singh H (2002) Synthesis and characterisation of bis-azido methyl oxetane and its polymer and copolymer with tetrahydrofuran. Defence Sci J 52(2):147–156CrossRef

Mohan YM, Mani Y, Raju KM (2006) Synthesis of azido polymers as potential energetic propellant binders. Des Monomers Polym 9(3):201–236. https://doi.org/10.1163/156855506777351045 CrossRef

10.

Luo Y, Chen P, Zhao FQ, Hu RZ, Li SW, Gao Y (2004) Kinetics and mechanism of the thermal decomposition reaction of 3,3-bis(azidomethyl)oxetane/tetrahydrofuran copolymer. Chin J Chem 22(11):1219–1224CrossRef

11.

Miyazaki T, Kubota N (1992) Energetics of BAMO. Propellants Explos Pyrotech 17(1):5–9CrossRef

12.

Zhang C, Luo YJ, Jiao QJ, Zhai B, Guo XY (2014) Application of the BAMO-AMMO alternative block energetic thermoplastic elastomer in composite propellant. Propellants Explos Pyrot 39(5):689–693. https://doi.org/10.1002/prep.201300164 CrossRef

13.

Manser GE, Ross DL (1981) Synthesis of energetic polymers. DTIC Document

14.

Manser G, Guimont J, Ross D (1981) A new polymerization technique for preparing low molecular weight polyether glycols. SR Int, Menlo Park

15.

Zhai JX, Yang RJ, Li JM (2008) Catalytic thermal decomposition and combustion of composite BAMO-THF propellants. Combust Flame 154(3):473–477. https://doi.org/10.1016/j.combustflame.2008.04.016 CrossRef

16.

Cooper SL, Tobolsky AV (1966) Properties of linear elastomeric polyurethanes. J Appl Polym Sci 10(12):1837–1844CrossRef

17.

Janik H, Palys B, Petrovic ZS (2003) Multiphase-separated polyurethanes studied by micro-Raman spectroscopy. Macromol Rapid Comm 24(3):265–268. https://doi.org/10.1002/Marc.200390039 CrossRef

18.

Romanova V, Begishev V, Karmanov V, Kondyurin A, Maitz MF (2002) Fourier transform Raman and Fourier transform infrared spectra of cross-linked polyurethaneurea films synthesized from solutions. J Raman Spectrosc 33(10):769–777CrossRef

19.

Ryan AJ, Willkomm WR, Bergstrom TB, Macosko CW, Koberstein JT, Yu CC, Russell TP (1991) Dynamics of (micro) phase separation during fast, bulk copolymerization: some synchrotron SAXS experiments. Macromolecules 24(10):2883–2889CrossRef

20.

Leung LM, Koberstein JT (1985) Small-angle scattering analysis of hard-microdomain structure and microphase mixing in polyurethane elastomers. J Polym Sci B 23(9):1883–1913

21.

Garrett J, Runt J, Lin J (2000) Microphase separation of segmented poly (urethane urea) block copolymers. Macromolecules 33(17):6353–6359CrossRef

22.

Zia KM, Bhatti IA, Barikani M, Zuber M, Bhatti HN (2009) XRD studies of polyurethane elastomers based on chitin/1,4-butane diol blends. Carbohyd Polym 76(2):183–187. https://doi.org/10.1016/j.carbpol.2008.10.005 CrossRef

23.

Trovati G, Sanches EA, Neto SC, Mascarenhas YP, Chierice GO (2010) Characterization of polyurethane resins by FTIR, TGA, and XRD. J Appl Polym Sci 115(1):263–268CrossRef

24.

Eceiza A, Martin M, De La Caba K, Kortaberria G, Gabilondo N, Corcuera M, Mondragon I (2008) Thermoplastic polyurethane elastomers based on polycarbonate diols with different soft segment molecular weight and chemical structure: mechanical and thermal properties. Polym Eng Sci 48(2):297–306CrossRef

25.

Camberlin Y, Pascault JP (1984) Phase segregation kinetics in segmented linear polyurethanes: relations between equilibrium time and chain mobility and between equilibrium degree of segregation and interaction parameter. J Polym Sci Polym Phys Ed 22(10):1835–1844CrossRef

26.

Mattia J, Painter P (2007) A comparison of hydrogen bonding and order in a polyurethane and poly (urethane-urea) and their blends with poly (ethylene glycol). Macromolecules 40(5):1546–1554CrossRef

27.

Yilgor I, Yilgor E, Guler IG, Ward TC, Wilkes GL (2006) FTIR investigation of the influence of diisocyanate symmetry on the morphology development in model segmented polyurethanes. Polymer 47(11):4105–4114CrossRef

28.

Ferry A, Jacobsson P, Van Heumen J, Stevens J (1996) Raman, infra-red and dsc studies of lithium coordination in a thermoplastic polyurethane. Polymer 37(5):737–744CrossRef

29.

Lee HS, Wang YK, Hsu SL (1987) Spectroscopic analysis of phase separation behavior of model polyurethanes. Macromolecules 20(9):2089–2095CrossRef

30.

Bonart R, Müller E (1974) Phase separation in urethane elastomers as judged by low-angle X-ray scattering. I. Fundamentals. J Macromol Sci B 10(1):177–189CrossRef

31.

Keicher T, Kuglstatter W, Eisele S, Wetzel T, Krause H (2009) Isocyanate-free curing of glycidyl azide polymer (GAP) with bis-propargyl-succinate (II). Propell Explos Pyrot 34(3):210–217. https://doi.org/10.1002/prep.200900001 CrossRef

32.

Diaz E, Brousseau P, Ampleman G, Prud’homme RE (2003) Heats of combustion and formation of new energetic thermoplastic elastomers based on GAP, PolyNIMMO and PolyGLYN. Propell Explos Pyrot 28(3):101–106. https://doi.org/10.1002/Prep.200390015 CrossRef

33.

Mathew S, Manu SK, Varghese TL (2008) Thermomechanical and morphological characteristics of cross-linked GAP and GAP-HTPB networks with different diisocyanates. Propell Explos Pyrot 33(2):146–152. https://doi.org/10.1002/prep.200800213 CrossRef

34.

Yilgör I, Yilgör E, Wilkes GL (2015) Critical parameters in designing segmented polyurethanes and their effect on morphology and properties: a comprehensive review. Polymer 58:A1–A36CrossRef

35.

Tereshatov V, Makarova M, Senichev VY, Volkova E, Vnutskikh ZA, Slobodinyuk A (2015) The role of the soft phase in the hardening effect and the rate dependence of the ultimate physico-mechanical properties of urethane-containing segmented elastomers. Colloid Polym Sci 293(1):153–164CrossRef

36.

Tereshatov V, Makarova M, Tereshatova E (2004) Abnormal thermal and mechanical behavior of plasticized polyurethaneureas. Polymer science Series A, Chemistry, physics 46(12):1232–1238

37.

Tereshatov V, Tereshatova E, Makarova M, Tereshatov S (2002) Influence of chemical structure and composition of mixed soft segments on the properties of elastomers with urethane-urea hard blocks. Polym Sci Ser A 44(3):275–281

38.

Tereshatov V, Vnutskikh Z, Slobodinyuk A, Makarova M, Senichev V (2016) New multi-block isophorone diisocyanate-based copolymers with urethane urea hard segments. J Elastomers Plast 48(4):289–304CrossRef

39.

Lee HS, Hsu SL (1989) An analysis of phase separation kinetics of model polyurethanes. Macromolecules 22(3):1100–1105CrossRef

40.

Ishihara H, Kimura I, Saito K, Ono H (1974) Infrared studies on segmented polyurethane-urea elastomers. J Macromol Sci B 10(4):591–618CrossRef

41.

Paik Sung C, Smith T, Sung N (1980) Properties of segmented polyether poly (urethaneureas) based of 2, 4-toluene diisocyanate. 2. Infrared and mechanical studies. Macromolecules 13(1):117–121CrossRef

42.

Ning L, De-Ning W, Sheng-Kang Y (1997) Hydrogen-bonding properties of segmented polyether poly (urethane urea) copolymer. Macromolecules 30(15):4405–4409CrossRef

43.

Fedors RF (1974) A method for estimating both the solubility parameters and molar volumes of liquids. Polym Eng Sci 14(2):147–154CrossRef

44.

Koberstein JT, Stein RS (1983) Small-angle X-ray scattering studies of microdomain structure in segmented polyurethane elastomers. J Polym Sci Polym Phys Ed 21(8):1439–1472CrossRef

45.

Paik Sung C, Hu C, Wu C (1980) Properties of segmented poly (urethaneureas) based on 2, 4-toluene diisocyanate. 1. Thermal transitions, X-ray studies, and comparison with segmented poly (urethanes). Macromolecules 13(1):111–116CrossRef

46.

Yilgör I, Riffle J, Wilkes G, McGrath J (1982) Siloxane-urea segmented copolymers. Polym Bull 8(11–12):535–542

47.

Stanford JL, Still RH, Wilkinson AN (2003) Effects of soft-segment prepolymer functionality on structure—property relations in RIM copolyurethanes. Polymer 44(14):3985–3994. https://doi.org/10.1016/S0032-3861(03)000357-4 CrossRef

48.

Ertem SP, Yilgor E, Kosak C, Wilkes GL, Zhang M, Yilgor I (2012) Effect of soft segment molecular weight on tensile properties of poly (propylene oxide) based polyurethaneureas. Polymer 53(21):4614–4622CrossRef

49.

Sheth JP, Unal S, Yilgor E, Yilgor I, Beyer FL, Long TE, Wilkes GL (2005) A comparative study of the structure-property behavior of highly branched segmented poly(urethane urea) copolymers and their linear analogs. Polymer 46(23):10180–10190. https://doi.org/10.1016/j.polymer.2005.07.068 CrossRef

Titel: Microphase separation and thermo-mechanical properties of energetic poly(urethane–urea)
verfasst von: Jie Lv
Jizhen Huo
Ye Yang
Yingfeng Yu
Guozhu Zhan
Huikun Zhang
Publikationsdatum: 04.12.2017
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 9/2018
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-017-2251-4

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