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Journal of Materials Science

Erschienen in:

17.07.2018 | Chemical routes to materials

Microstructures and mechanical properties of aligned electrospun carbon nanofibers from binary composites of polyacrylonitrile and polyamic acid

verfasst von: Gaigai Duan, Hong Fang, Chaobo Huang, Shaohua Jiang, Haoqing Hou

Erschienen in: Journal of Materials Science | Ausgabe 21/2018

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Abstract

High mechanical performance carbon nanofibers are highly required for the carbon nanofiber-reinforced composites, and it is necessary to develop novel precursors for the preparation of carbon nanofibers. In this work, blends of poly(acrylonitrile-butyl acrylate mono-butyl itaconate) (co-PAN) and polyamic acid (PAA) were electrospun into aligned nanofibers and the nanofibers were converted to carbon nanofibers by thermal imidization, pre-oxidation and high-temperature carbonization. FT-IR spectroscopy was applied to monitor the chemical structures of the nanofibers before and after pre-oxidation. Tensile tests were used to characterize the mechanical properties of electrospun carbon nanofibers (ECNFs). The microstructures of ECNFs were investigated by high-resolution TEM and Raman spectroscopy. The results indicated that the ECNFs derived from blend of co-PAN/PAA with molar ratio of 6/4 and with carbonization temperature of 1400 °C possessed the highest tensile strength of 1212 MPa, which could be attributed to the ordered graphitic structures in ECNFs.

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Titel: Microstructures and mechanical properties of aligned electrospun carbon nanofibers from binary composites of polyacrylonitrile and polyamic acid
verfasst von: Gaigai Duan
Hong Fang
Chaobo Huang
Shaohua Jiang
Haoqing Hou
Publikationsdatum: 17.07.2018
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 21/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-018-2700-y

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