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Journal of Materials Science
Erschienen in: Journal of Materials Science 10/2017

24.01.2017 | Original Paper

Microstructures and properties of equiatomic CuZr and CuZrAlTiNi bulk alloys fabricated by mechanical alloying and spark plasma sintering

verfasst von: Wenjuan Ge, Yingzi Wang, Caiyun Shang, Zitang Zhang, Yan Wang

Erschienen in: Journal of Materials Science | Ausgabe 10/2017

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Abstract

Equiatomic CuZr and CuZrAlTiNi bulk alloys were designed and fabricated by mechanical (MA) alloying and spark plasma sintering (SPS). The results show that during the MA process, the phases of as-milled samples transform from solid solutions to amorphous phases with increasing milling time. Moreover, the as-milled CuZrAlTiNi amorphous high entropy powders possess higher thermal stability and smaller particle sizes than the as-obtained CuZr powders. After SPS, the bulk CuZrAlTiNi samples are comprised of three solid solutions and a AlNi2Zr phase, and have good phase stability. The CuZrAlTiNi sample sintered at 950 °C shows the higher microhardness value of 1007 HV0.2 due to the fine precipitates, the existence of AlNi2Zr phase and solid solution strengthening. In addition, the chemical corrosion behavior of the as-sintered samples has been investigated in the seawater solution. The 950 °C-sintered CuZrAlTiNi sample exhibits excellent passivity and higher pitting resistance as compared to other sintered samples. All the CuZr and CuZrAlTiNi bulk samples show better corrosion resistance than 304 stainless steel revealed by the reduced corrosion rate.
Vorheriger Artikel Asymmetric membranes based on poly(vinyl chloride): effect of molecular weight of additive and solvent power on the morphology and performance
Nächster Artikel Microwave-assisted one-step synthesis of acetate-capped NaYF4:Yb/Er upconversion nanocrystals and their application in bioimaging

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Literatur
1.
Guo S, Ng C, Wang ZJ, Liu CT (2014) Solid solutioning in equiatomic alloys: limit set by topological instability. J Alloys Compd 583:410–413CrossRef
2.
Yeh JW, Chen SK, Lin SJ, Gan JY, Chin TS, Shun TT et al (2004) Nanostructured high entropy alloys with multiple principal elements: novel alloy design concepts and outcomes. Adv Eng Mater 6:299–303CrossRef
3.
Chuang MH, Tsai MH, Wang WR, Lin SJ, Yeh JW (2011) Microstructure and wear behavior of Al x Co1.5CrFeNi1.5Ti y high-entropy alloys. Acta Mater 59:6308–6317CrossRef
4.
He JY, Liu WH, Wang H, Wu Y, Liu XJ, Nieh TG, Lu ZP (2014) Effects of Al addition on structural evolution and tensile properties of the FeCoNiCrMn high-entropy alloy system. Acta Mater 62:105–113CrossRef
5.
Zhang ZT, Axinte E, Ge WJ, Shang CY, Wang Y (2016) Microstructure, mechanical properties and corrosion resistance of CuZrY/Al, Ti, Hf series high-entropy alloys. Mater Des 108:106–113
6.
Gao XQ, Zhao K, Ke HB, Ding DW, Wang WH, Bai HY (2011) High mixing entropy bulk metallic glasses. J Non-Cryst Solids 357:557–560
7.
Fu ZQ, Chen WP, Xiao HQ, Zhou LW, Zhu DZ, Yang SF (2013) Fabrication and properties of nanocrystalline Co0.5FeNiCrTi0.5 high entropy alloy by MA-SPS technique. Mater Des 44:535–539CrossRef
8.
Zhang Y, Zuo TT, Tang Z, Gao MC, Dahmen KA, Liaw PK, Lu ZP (2014) Microstructures and properties of high-entropy alloys. Prog Mater Sci 61:1–93CrossRef
9.
Fu ZQ, Chen WP, Wen HM, Chen Z, Lavernia EJ (2015) Effects of Co and sintering method on microstructure and mechanical behavior of a high-entropy Al0.6NiFeCrCo alloy prepared by powder metallurgy. J Alloys Compd 646:175–182CrossRef
10.
Varalakshmi S, Kamaraj M, Murty BS (2010) Processing and properties of nanocrystalline CuNiCoZnAlTi high entropy alloys by mechanical alloying. Mater Sci Eng, A 527:1027–1030CrossRef
11.
Tong CJ, Chen MR, Chen SK, Yeh JW, Shun TT, Lin SJ et al (2005) Mechanical performance of the Al x CoCrCuFeNi high-entropy alloy system with multiprincipal elements. Metall Mater Trans A 36:1263–1271CrossRef
12.
Huang PK, Yeh JW, Shun TT, Chen SK (2004) Multi-principal-element alloys with improved oxidation and wear resistance for thermal spray coating. Adv Eng Mater 6:74–78CrossRef
13.
Zhang KB, Fu ZY, Zhang JY, Wang WM, Lee SW, Niihara K (2010) Characterization of nanocrystalline CoCrFeNiTiAl high-entropy solid solution processed by mechanical alloying. J Alloys Compd 495:33–38CrossRef
14.
Ji W, Wang WM, Wang H, Zhang JY, Wang YC, Zhang F, Fu ZY (2015) Alloying behavior and novel properties of CoCrFeNiMn high-entropy alloy fabricated by mechanical alloying and spark plasma sintering. Intermetallics 56:24–27CrossRef
15.
Fu ZQ, Chen WP, Wen HM, Morgan S, Chen F, Zheng BL, Zhou YZ, Zhang LM, Lavernia EJ (2015) Microstructure and mechanical behavior of a novel Co20Ni20Fe20Al20Ti20 alloy fabricated by mechanical alloying and spark plasma sintering. Mater Sci Eng, A 644:10–16CrossRef
16.
Fu ZQ, Chen WP, Wen HM, Zhang DL, Chen Z, Zheng BL et al (2016) Microstructure and strengthening mechanisms in an FCC structured single-phase nanocrystalline Co25Ni25Fe25Al7.5Cu17.5 high-entropy alloy. Acta Mater 107:59–71CrossRef
17.
Zhang KB, Fu ZY, Zhang JY, Wang WM, Wang H, Wang YC, Zhang QJ, Shi J (2009) Nanocrystalline CoCrFeNiCuAl high-entropy solid solution synthesized by mechanical alloying. J Alloys Compd 485:L31–L34CrossRef
18.
Chen YL, Hu YH, Tsai CW, Hsieh CA, Kao SW, Yeh JW et al (2009) Alloying behavior of binary to octonary alloys based on Cu–Ni–Al–Co–Cr–Fe–Ti–Mo during mechanical alloying. J Alloys Compd 477:696–705CrossRef
19.
Munir ZA, Anselmi-Tamburini U, Ohyanagi M (2006) The effect of electric field and pressure on the synthesis and consolidation of materials: a review of the spark plasma sintering method. J Mater Sci 41:763–777. doi:10.​1007/​s10853-006-6555-2 CrossRef
20.
Ding HY (2013) Hong entropy Ti20Zr20Cu20Ni20Be20 bulk metallic glass. J Non-Cryst Solids 364:9–12CrossRef
21.
Li HF, Xie XH, Zhao K, Wang YB, Zheng YF, Wang WH et al (2013) In vitro and in vivo studies on biodegradable CaMgZnSrYb high-entropy bulk metallic glass. Acta Biomater 9:8561–8573CrossRef
22.
Qi TL, Li YH, Takeuchi A, Xie GQ, Miao HT, Zhang W (2015) Soft magnetic Fe25Co25Ni25(B, Si)25 high entropy bulk metallic glasses. Intermetallics 66:8–12CrossRef
23.
Huo JT, Huo LS, Li JW, Men H, Wang XM, Inoue A, Chang CT, Wang JQ, Li RW (2015) High-entropy bulk metallic glasses as promising magnetic refrigerants. J Appl Phys 117:073902CrossRef
24.
Takeuchi A, Chen N, Wada T, Yokoyama Y, Kato H, Inoue A et al (2011) Pd20Pt20Cu20Ni20P20 high-entropy alloy as a bulk metallic glass in the centimeter. Intermetallics 19:1546–1554CrossRef
25.
Kang DH, Zhang H, Yoo HB, Lee HH, Lee S, Lee GW et al (2014) Interfacial free energy controlling glass-forming ability of Cu–Zr alloys. Sci Rep 4:5167
26.
Pauly S, Gorantla S, Wang G, Kühn U, Eckert J (2010) Transformation-mediated ductility in CuZr-based bulk metallic glasses. Nat Mater 9:473–477CrossRef
27.
Tomolya K, Janovszky D, Sycheva A, Sveda M, Ferenczi T, Roósz A (2015) Peculiarities of ball-milling induced crystalline-amorphous transformation in Cu–Zr–Al–Ni–Ti alloys. Intermetallics 65:117–121CrossRef
28.
Yan HH, Hu Y, Yan ZJ, Zheng XH, Li YT (2012) Microstructure evolution of Zr50Cu18Ni17Al10Ti5 bulk metallic glass during cold-rolling. J Mater Sci Technol 28:756–760CrossRef
29.
Chieh TC, Chu J, Liu CT, Wu JK (2003) Corrosion of Zr52.5Cu17.9Ni14.6Al10Ti5 bulk metallic glasses in aqueous solutions. Mater Lett 57:3022–3025CrossRef
30.
Baldenebro-Lopez FJ, Herrera-Ramírez JM, Arredondo-Rea SP, Gómez-Esparza CD, Martínez-Sánchez R (2015) Simultaneous effect of mechanical alloying and arc-melting processes in the microstructure and hardness of an AlCoFeMoNiTi high-entropy alloy. J Alloys Compd 643:S250–S255CrossRef
31.
Guinier A (1963) X-ray diffraction in crystals, imperfect crystals and amorphous bodies. WH Freeman, San Francisco, pp 72–81
32.
Sharma S, Suryanarayana C (2008) Effect of Nb on the glass-forming ability of mechanically alloyed Fe–Ni–Zr–B alloys. Scr Mater 58:508–511CrossRef
33.
Yu P, Bai HY, Tang MB, Wang WL (2005) Excellent glass-forming ability in simple Cu50Zr50-based alloys. J Non-Cryst Solids 351:1328–1332CrossRef
34.
Cui X, Zhang QD, Li XY, Zu FQ (2016) Dependence of GFA and thermal stability of the Cu50Zr50 alloy on temperature-functioned different liquid states. Intermetallics 73:79–85CrossRef
35.
Zhang PN, Li JF, Hu Y, Zhou YH (2008) Effect of rolling on the microstructure and mechanical property of Zr52.5Cu17.9Ni14.6Al10Ti5 bulk metallic glass. J Alloys Compd 462:88–93CrossRef
36.
Pekarskaya E, Löffler JF, Johnson WL (2003) Microstructural studies of crystallization of a Zr-based bulk metallic glass. Acta Mater 51:4045–4057CrossRef
37.
Takeuchi A, Inoue A (2005) Classification of bulk metallic glasses by atomic size dierence, heat of mixing and period of constituent elements and its application to characterization of the main alloying element. Mater Trans 462:2817–2829CrossRef
38.
Tomolya K, Janovszky D, Janvari T, Sycheva A, Tranta F, Solyom J, Ferenczi T, Roosz A (2012) Consolidation of Cu58Zr42 amorphous/nanocrystalline powders by PM. J Alloys Compd 536S:S154–S158CrossRef
39.
Li C, Li JC, Zhao M, Jiang Q (2009) Effect of alloying elements on microstructure and properties of multiprincipal elements high-entropy alloys. J Alloys Compd 475:752–757CrossRef
40.
Ke GY, Chen SK, Hsu T, Yeh JW (2006) FCC and BCC equivalents in as-cast solid solutions of AlxCoyCrzCu0.5FevNiw high-entropy alloys. Ann Chim Sci Mater 31:669–683CrossRef
41.
Senkov ON, Miracle DB (2001) Effect of the atomic size distribution on glass forming ability of amorphous metallic alloys. Mater Res Bull 36:2183–2198CrossRef
42.
Zhou YJ, Zhang Y, Wang FJ, Wang YL, Chen GL (2008) Effect of Cu addition on the microstructure and mechanical properties of AlCoCrFeNiTi0.5 solid-solution alloy. J Alloys Compd 466:201–204CrossRef
43.
Cheng JB, Liang XB, Xu BS (2014) Effect of Nb addition on the structure and mechanical behaviors of CoCrCuFeNi high-entropy alloy coatings. Surf Coat Technol 240:184–190CrossRef
44.
Standard practice for calculation of corrosion rates and related information from electrochemical measurements. Designation: G 102–189 (Reapproved 1999)
45.
Tam MK, Pang SJ, Shek CH (2007) Corrosion behavior and glass-forming ability of Cu–Zr–Al–Nb alloys. J Non-Cryst Solids 353:3596–3599CrossRef
Metadaten
Titel
Microstructures and properties of equiatomic CuZr and CuZrAlTiNi bulk alloys fabricated by mechanical alloying and spark plasma sintering
verfasst von
Wenjuan Ge
Yingzi Wang
Caiyun Shang
Zitang Zhang
Yan Wang
Publikationsdatum
24.01.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 10/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-0808-0

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