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Journal of Nanoparticle Research

Erschienen in:

01.10.2011 | Research Paper

Microwave-assisted hydrothermal synthesis of biocompatible silver sulfide nanoworms

verfasst von: Ruimin Xing, Shanhu Liu, Shufang Tian

Erschienen in: Journal of Nanoparticle Research | Ausgabe 10/2011

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Abstract

In this study, silver sulfide nanoworms were prepared via a rapid microwave-assisted hydrothermal method by reacting silver nitrate and thioacetamide in the aqueous solution of the Bovine Serum Albumin (BSA) protein. The morphology, composition, and crystallinity of the nanoworms were characterized by field emission scanning electron microscopy (FESEM), X-ray powder diffraction (XRD), transmission electron microscopy (TEM), selected area electron diffraction (SAED), X-ray energy dispersive spectroscopy (EDS), and Fourier transform infrared (FTIR) spectroscopy. The results show that the nanoworms were assembled by multiple adjacent Ag₂S nanoparticles and stabilized by a layer of BSA attached to their surface. The nanoworms have the sizes of about 50 nm in diameter and hundreds of nanometers in length. The analyses of high-resolution TEM and their correlative Fast Fourier Transform (FFT) indicate that the adjacent Ag₂S nanoparticles grow by misoriented attachment at the connective interfaces to form the nanoworm structure. In vitro assays on the human cervical cancer cell line HeLa show that the nanoworms exhibit good biocompatibility due to the presence of BSA coating. This combination of features makes the nanoworms attractive and promising building blocks for advanced materials and devices.

Vorheriger Artikel Investigation on F–B–S tri-doped nano-TiO2 films for the photocatalytic degradation of organic dyes

Nächster Artikel The effective reinforcement of magnesium alloy ZK60A using Al2O3 nanoparticles

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Banfield JF, Welch SA, Zhang H, Ebert TT, Penn RL (2000) Aggregation-based crystal growth and microstructure development in natural iron oxyhydroxide biomineralization products. Science 289:751–754CrossRef

Baruwati B, Polshettiwar V, Varma RS (2009) Glutathione promoted expeditious green synthesis of silver nanoparticles in water using microwaves. Green Chem 11:926–930CrossRef

Brelle MC, Zhang JZ, Nguyen L, Mehra RK (1999) Synthesis and ultrafast study of cysteine- and glutathione-capped Ag₂S semiconductor colloidal nanoparticles. J Phys Chem A 103:10194–10201CrossRef

Chen C–C, Herhold AB, Johnson CS, Alivisatos AP (1997) Size dependence of structural metastability in semiconductor nanocrystals. Science 276:398–401CrossRef

Choi SH, An K, Kim EG, Yu JH, Kim JH, Hyeon T (2009) Simple and generalized synthesis of semiconducting metal sulfide nanocrystals. Adv Funct Mater 19:1645–1649CrossRef

Du YP, Xu B, Fu T, Cai M, Li F, Zhang Y, Wang QB (2010) Near-infrared photoluminescent Ag₂S quantum dots from a single source precursor. J Am Chem Soc 132:1470–1471CrossRef

Jang K, Kim SY, Park KH, Jang E, Jun S, Son SU (2007) Shape-controlled synthesis of silver sulfide nanocrystals by understanding the origin of mixed-shape evolution. Chem Commun 4474–4476

Liao ZM, Hou C, Zhao Q, Wang DS, Li YD, Yu DP (2009) Resistive switching and metallic-filament formation in Ag₂S nanowire transistors. Small 5:2377–2381CrossRef

Lim WP, Zhang Z, Low HY, Chin WS (2004) Preparation of Ag₂S nanocrystals of predictable shape and size. Angew Chem Int Ed 43:5685–5689CrossRef

Liu SH, Qian XF, Yin J, Hong L, Wang XL, Zhu ZK (2002) Synthesis and characterization of Ag₂S nanocrystals in hyperbranched polyurethane at room temperature. J Solid State Chem 168:259–262CrossRef

Liu ZP, Liang JB, Xu D, Lu J, Qian YT (2004) A facile chemical route to semiconductor metal sulfide nanocrystal superlattices. Chem Commun 2724–2725

Liu SH, Lu F, Zhu JJ (2011a) Highly fluorescent Ag nanoclusters: microwave-assisted green synthesis and Cr³⁺ sensing. Chem Commun 47:2661–2663CrossRef

Liu SH, Lu F, Jia X, Cheng F, Jiang L, Zhu JJ (2011b) Microwave-assisted synthesis of a biocompatible polyacid-conjugated Fe₃O₄ superparamagnetic hybrid. CrystEngComm 13:2425–2429CrossRef

Lu QY, Gao F, Zhao DY (2002) Creation of a unique self-supported pattern of radially aligned semiconductor Ag₂S nanorods. Angew Chem Int Ed 41:1932–1934CrossRef

Mamedova NN, Kotov NA, Rogach AL, Studer J (2001) Albumin–CdTe nanoparticle bioconjugates: preparation, structure, and interunit energy transfer with antenna effect. Nano Lett 1:281–286CrossRef

Mao CJ, Geng J, Wu XC, Zhu JJ (2010) Selective synthesis and luminescence properties of self-assembled SrMoO₄ superstructures via a facile sonochemical route. J Phys Chem C 114:1982–1988CrossRef

Niu X, Liu S, Xing R, Wang X, Zhang B, Chen J, Yang L (2007) Synthesis of single-crystalline silver sulfide nanowires by diffusion in porous anodic aluminium oxide template. Mater Lett 61:5098–5101CrossRef

Pal A, Shah S, Devi S (2009) Microwave-assisted synthesis of silver nanoparticles using ethanol as a reducing agent. Mater Chem Phys 114:530–532CrossRef

Pan HC, Tao XC, Mao CJ, Zhu JJ, Liang FP (2007) Aminopolycarboxyl-modified Ag₂S nanoparticles: synthesis, characterization and resonance light scattering sensing for bovine serum albumin. Talanta 71:276–281CrossRef

Pastoriza-Santos I, Liz-Marzán LM (2002) Formation of PVP-protected metal nanoparticles in DMF. Langmuir 18:2888–2894CrossRef

Penn RL, Banfield JF (1998) Imperfect oriented attachment: dislocation generation in defect-free nanocrystals. Science 281:969–971CrossRef

Qin DZ, Ma XM, Yang L, Zhang L, Ma ZJ, Zhang J (2008) Biomimetic synthesis of HgS nanoparticles in the bovine serum albumin solution. J Nanopart Res 10:559–566CrossRef

Reches M, Gazit E (2003) Casting metal nanowires within discrete self-assembled peptide nanotubes. Science 300:625–627CrossRef

Sadtler B, Demchenko DO, Zheng H et al (2009) Selective facet reactivity during cation exchange in cadmium sulfide nanorods. J Am Chem Soc 131:5285–5293CrossRef

Song Q, Ai X, Topuria T et al (2010) Microwave-assisted synthesis of monodispersed CdTe nanocrystals. Chem Commun 46:4971–4973CrossRef

Teranishi T, Saruyama M, Kanehara M (2009) Seed-mediated synthesis of metal sulfide patchy nanoparticles. Nanoscale 1:225–228CrossRef

Wang HL, Qi LM (2008) Controlled synthesis of Ag₂S, Ag₂Se, and Ag nanofibers using a general sacrificial template and their application in electronic device fabrication. Adv Funct Mater 18:1249–1256CrossRef

Wang DS, Xie T, Peng Q, Li YD (2008) Ag, Ag₂S, and Ag₂Se nanocrystals: synthesis, assembly, and construction of mesoporous structures. J Am Chem Soc 130:4016–4022CrossRef

Wang DS, Zheng W, Hao CH, Peng Q, Li YD (2009) A synthetic method for transition-metal chalcogenide nanocrystals. Chem Eur J 15:1870–1875CrossRef

Wu CC, Shiau CY, Ayele DW, Su WN, Cheng MY, Chiu CY, Hwang BJ (2010) Rapid microwave-enhanced solvothermal process for synthesis of CuInSe₂ particles and its morphologic manipulation. Chem Mater 22:4185–4190CrossRef

Xing RM, Wang XY, Yan LL, Zhang CL, Yang Z, Wang XH, Guo ZJ (2009a) Fabrication of water soluble and biocompatible CdSe nanoparticles in apoferritin with the aid of EDTA. Dalton Trans 1710–1713

Xing RM, Wang XY, Zhang CL, Zhang YM, Wang Q, Yang Z, Guo ZJ (2009b) Characterization and cellular uptake of platinum anticancer drugs encapsulated in apoferritin. J Inorg Biochem 103:1039–1044CrossRef

Xu Z, Bando Y, Wang WL, Bai XD, Golberg D (2010) Real-time in situ HRTEM-resolved resistance switching of Ag₂S nanoscale ionic conductor. ACS Nano 4:2515–2522CrossRef

Yang L, Xing RM, Shen QM, Jiang K, Ye F, Wang JY, Ren QS (2006) Fabrication of protein-conjugated silver sulfide nanorods in the bovine serum albumin solution. J Phys Chem B 110:10534–10539CrossRef

Yang L, Yang HY, Yang ZX, Cao YX, Ma XM, Lu ZS, Zheng Z (2008) Observation of rotated-oriented attachment during the growth of Ag₂S nanorods under mediation of protein. J Phys Chem B 112:9795–9801CrossRef

Yang L, Liu SH, Zhang BF, Xing RM, Wang HJ, Zhou JG (2010) The synthesis and crystallization mechanism of protein-conjugated silver sulfide nanowires with hierarchical structure. Mater Lett 64:1598–1600CrossRef

Zhang WX, Zhang L, Hui ZH, Zhang XM, Qian YT (2000) Synthesis of nanocrystalline Ag₂S in aqueous solution. Solid State Ion 130:111–114CrossRef

Zhu J, Palchik O, Chen S, Gedanken A (2000) Microwave assisted preparation of CdSe, PbSe, and Cu_2-xSe nanoparticles. J Phys Chem B 104:7344–7347CrossRef

Zhu YJ, Wang WW, Qi RJ, Hu XL (2004) Microwave-assisted synthesis of single-crystalline tellurium nanorods and nanowires in ionic liquids. Angew Chem Int Ed 43:1410–1414CrossRef

Titel: Microwave-assisted hydrothermal synthesis of biocompatible silver sulfide nanoworms
verfasst von: Ruimin Xing
Shanhu Liu
Shufang Tian
Publikationsdatum: 01.10.2011
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 10/2011
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-011-0462-4

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