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Polymer Bulletin
Erschienen in: Polymer Bulletin 10/2018

13.02.2018 | Original Paper

Migration of the plasticizer in the compatibilized PP/PVB blends: characterization and thermodynamic calculations

verfasst von: Ali Reza Zanjanijam, Shokoufeh Hakim, Hamed Azizi

Erschienen in: Polymer Bulletin | Ausgabe 10/2018

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Abstract

This work reports migration and distribution of the plasticizer of PVB phase during processing of the PP/waste PVB blends. Storage modulus of the blends and glass transition temperature of the PP and PVB phases revealed that some part of the plasticizer of the waste PVB migrated to PP matrix and interface. This observation was further investigated from thermodynamic points of view. The calculations of solubility parameter, surface tension, and interfacial tension for the blend components helped to interpret the migration phenomenon. The obtained data confirmed relative tendency of the plasticizer to migrate to PP phase and interface. Furthermore, the effects of plasticizer migration on behavior of the blends were studied. It was shown that plasticizer can significantly affect the rheological properties of the compatibilized PP/PVB blends.
Vorheriger Artikel Preparation, analyses and application of cobalt–manganese oxides/nylon 6,6 nanocomposites
Nächster Artikel Easy fabrication and characterization of gelatin nanocarriers and in vitro investigation of swelling controlled release dynamics of paclitaxel

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Metadaten
Titel
Migration of the plasticizer in the compatibilized PP/PVB blends: characterization and thermodynamic calculations
verfasst von
Ali Reza Zanjanijam
Shokoufeh Hakim
Hamed Azizi
Publikationsdatum
13.02.2018
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 10/2018
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-018-2288-z

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