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Erschienen in: Journal of Materials Science 13/2020

01.05.2020 | Chemical routes to materials

Mn0.3Cd0.7S nanorods modified with NiS clusters as photocatalysts for the H2 evolution reaction

Erschienen in: Journal of Materials Science | Ausgabe 13/2020

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Abstract

The intimate contact of co-catalyst and host photocatalyst benefits the separation and transfer of carriers in time, hindering the recombination of e and h+ during the photocatalytic process. Herein, a facile one-pot solvothermal methodology was applied to fabricate NiS clusters-modified Mn0.3Cd0.7S p–n heterojunction photocatalyst. Compared with NiS@Mn0.3Cd0.7S synthesized by the two-step approach, the symbiosis of NiS and Mn0.3Cd0.7S during one-pot synthesis induced the highly dispersed NiS clusters on the surface of Mn0.3Cd0.7S nanorods and the stronger intimate contact between NiS and Mn0.3Cd0.7S, giving rise to better H2 production of 65.81 mmol g−1 h−1. The apparent quantum yield reached 20.19%. The study presented a feasible route for the synthesis of cheap and efficient p–n heterostructure photocatalysts.

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Metadaten
Titel
Mn0.3Cd0.7S nanorods modified with NiS clusters as photocatalysts for the H2 evolution reaction
Publikationsdatum
01.05.2020
Erschienen in
Journal of Materials Science / Ausgabe 13/2020
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-04405-z

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