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03.05.2017

Mn₃O₄/carbon nanotube nanocomposites recycled from waste alkaline Zn–MnO₂ batteries as high-performance energy materials

verfasst von: Li-Hua Zhang, Si-Si Wu, Yi Wan, Yi-Feng Huo, Yao-Cong Luo, Ming-Yang Yang, Min-Chan Li, Zhou-Guang Lu

Erschienen in: Rare Metals | Ausgabe 5/2017

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Abstract

Alkaline zinc manganese dioxide (Zn–MnO₂) batteries are widely used in everyday life. Recycling of waste alkaline Zn–MnO₂ batteries has always been a hot environmental concern. In this study, a simple and cost-effective process for synthesizing Mn₃O₄/carbon nanotube (CNT) nanocomposites from recycled alkaline Zn–MnO₂ batteries is presented. Manganese oxide was recovered from spent Zn–MnO₂ battery cathodes. The Mn₃O₄/CNT nanocomposites were produced by ball milling the recovered manganese oxide in a commercial multi-wall carbon nanotubes (MWCNTs) solution. Scanning electron microscopy (SEM) analysis demonstrates that the nanocomposite has a unique three-dimensional (3D) bird nest structure. Mn₃O₄ nanoparticles are homogeneously distributed on MWCNT framework. Mn₃O₄/CNT nanocomposites were evaluated as an anode material for lithium-ion batteries, exhibiting a highly reversible specific capacitance of ~580 mAh·g⁻¹ after 100 cycles. Moreover, Mn₃O₄/CNT nanocomposite also shows a fairly positive onset potential of −0.15 V and quite high oxygen reducibility when considered as an electrocatalyst for oxygen reduction reaction.

Vorheriger Artikel Hierarchical porous carbon derived from animal bone as matric to encapsulated selenium for high performance Li–Se battery

Nächster Artikel Double-activated porous carbons for high-performance supercapacitor electrodes

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Titel: Mn3O4/carbon nanotube nanocomposites recycled from waste alkaline Zn–MnO2 batteries as high-performance energy materials
verfasst von: Li-Hua Zhang
Si-Si Wu
Yi Wan
Yi-Feng Huo
Yao-Cong Luo
Ming-Yang Yang
Min-Chan Li
Zhou-Guang Lu
Publikationsdatum: 03.05.2017
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 5/2017
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-017-0902-0

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