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13.11.2024 | Engine and Emissions, Fuels and Lubricants

Model-Based Two-Stage SCR Urea Injection Strategy for Diesel Engine to Meet Low NOX Emission Regulation

verfasst von: Jincheng Li, Haibo Sun, Gang Li, Zunqing Zheng, Mingfa Yao

Erschienen in: International Journal of Automotive Technology

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Abstract

Diesel engine emission regulations are becoming stringent regarding nitrogen oxide (NOX) limits. The challenge is to improve the NOX conversion efficiency of the after treatment system under low temperatures. Although the two-stage selective catalytic reduction (SCR) has become a hot research topic, developing the urea injection strategy faces two challenges of accurately predicting ammonia (NH3) coverage and the complexity of two-stage SCR co-control. Therefore, first, control-oriented close-coupled SCR (ccSCR) and SCR models were established based on chemical reaction kinetic mechanism, mass conservation, and continuous stirred tank reactor law. The integrated model was established by coupling them with a control-oriented diesel oxidation catalyst model. Second, the effects of temperature, exhaust mass flow rate, oxygen concentration, NOX concentration, and nitrogen dioxide ratio on the NH3 coverage target value were investigated based on the integrated model. Third, a two-stage SCR co-control strategy was proposed. The NH3 coverage initial value and the threshold temperature for ccSCR to stop urea injection of the control strategy were optimized under the world harmonized transient cycle (WHTC). The results show that the NH3 coverage target value is most sensitive to temperature and decreases with increasing temperature. The composite tailpipe NOX under the WHTC is as low as 0.2 g/(kW·h).

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Literatur
Zurück zum Zitat Bai, S. Z., Han, J. L., Liu, M., Qin, S. S., Wang, G. H., & Li, G. X. (2018). Experimental investigation of exhaust thermal management on NOX emissions of heavy-duty diesel engine under the world harmonized transient cycle (WHTC). Applied Thermal Engineering, 142, 421–432.CrossRef Bai, S. Z., Han, J. L., Liu, M., Qin, S. S., Wang, G. H., & Li, G. X. (2018). Experimental investigation of exhaust thermal management on NOX emissions of heavy-duty diesel engine under the world harmonized transient cycle (WHTC). Applied Thermal Engineering, 142, 421–432.CrossRef
Zurück zum Zitat Bakhchin, D., Ravi, R., Faqir, M., & Essadiqi, E. (2023). A technical review on low temperature combustion alternatives for ultra-low emission vehicles. Journal of the Energy Institute, 111, 101410.CrossRef Bakhchin, D., Ravi, R., Faqir, M., & Essadiqi, E. (2023). A technical review on low temperature combustion alternatives for ultra-low emission vehicles. Journal of the Energy Institute, 111, 101410.CrossRef
Zurück zum Zitat Bonfils, A., Creff, Y., Lepreux, O., & Petit, N. (2014). Closed-loop control of a SCR system using a NOX sensor cross-sensitive to NH3. Journal of Process Control, 24, 368–378.CrossRef Bonfils, A., Creff, Y., Lepreux, O., & Petit, N. (2014). Closed-loop control of a SCR system using a NOX sensor cross-sensitive to NH3. Journal of Process Control, 24, 368–378.CrossRef
Zurück zum Zitat Choi, S., Kim, C., Cho, J. (2022). A development of SCR model and its applications. SAE Paper 2022-01-0557. Choi, S., Kim, C., Cho, J. (2022). A development of SCR model and its applications. SAE Paper 2022-01-0557.
Zurück zum Zitat Choi, B., Lee, K., & Son, G. (2020). Review of recent after-treatment technologies for de-NOX process in diesel engines. International Journal of Automotive Technology, 21(6), 1597–1618.CrossRef Choi, B., Lee, K., & Son, G. (2020). Review of recent after-treatment technologies for de-NOX process in diesel engines. International Journal of Automotive Technology, 21(6), 1597–1618.CrossRef
Zurück zum Zitat Feng, T., & Lyu, L. (2015). The characteristics of ammonia storage and the development of model-based control for diesel engine urea-SCR system. Journal of Industrial and Engineering Chemistry, 28, 97–109.CrossRef Feng, T., & Lyu, L. (2015). The characteristics of ammonia storage and the development of model-based control for diesel engine urea-SCR system. Journal of Industrial and Engineering Chemistry, 28, 97–109.CrossRef
Zurück zum Zitat Frobert, A., Raux, S., Creff, Y., = Jeudy, E. (2013). About cross-sensitives of NOX sensors in SCR operation. SAE Paper 2013-01-1512. Frobert, A., Raux, S., Creff, Y., = Jeudy, E. (2013). About cross-sensitives of NOX sensors in SCR operation. SAE Paper 2013-01-1512.
Zurück zum Zitat Gao, Z. M., Pihl, J., LaClair, T., & Fricke, B. (2021). Global kinetic modeling of NH3-SCR with two sites of NH3 storage on Cu-SSZ-13. Chemical Engineering Journal, 406, 127120.CrossRef Gao, Z. M., Pihl, J., LaClair, T., & Fricke, B. (2021). Global kinetic modeling of NH3-SCR with two sites of NH3 storage on Cu-SSZ-13. Chemical Engineering Journal, 406, 127120.CrossRef
Zurück zum Zitat Gu, Y., & Epling, W. S. (2019). Passive NOX adsorber: An overview of catalyst performance and reaction chemistry. Applied Catalysis, a: General, 570, 1–14.CrossRef Gu, Y., & Epling, W. S. (2019). Passive NOX adsorber: An overview of catalyst performance and reaction chemistry. Applied Catalysis, a: General, 570, 1–14.CrossRef
Zurück zum Zitat Haga, H., Kojima, H., Fukushi, N., Ohya, N., -Mito, T. (2015). Optimized NH3 storage control for next generation urea-SCR system. SAE Paper 2015-01-1024. Haga, H., Kojima, H., Fukushi, N., Ohya, N., -Mito, T. (2015). Optimized NH3 storage control for next generation urea-SCR system. SAE Paper 2015-01-1024.
Zurück zum Zitat Harris, T. M., McPherson, K., Rezaei, R., Kovacs, D., Rauch, H., -Huang, Y. Y. (2019). Modeling of close-coupled SCR concepts to meet future cold start requirements for heavy-duty engines. SAE Paper 2019-01-0984. Harris, T. M., McPherson, K., Rezaei, R., Kovacs, D., Rauch, H., -Huang, Y. Y. (2019). Modeling of close-coupled SCR concepts to meet future cold start requirements for heavy-duty engines. SAE Paper 2019-01-0984.
Zurück zum Zitat Hsieh, M. F., & Wang, J. M. (2011). Development and experimental studies of a control-oriented SCR model for a two-catalyst urea-SCR system. Control Engineering Practice, 19, 409–422.CrossRef Hsieh, M. F., & Wang, J. M. (2011). Development and experimental studies of a control-oriented SCR model for a two-catalyst urea-SCR system. Control Engineering Practice, 19, 409–422.CrossRef
Zurück zum Zitat Joshi, A. (2021). Review of vehicle engine efficiency and emissions. SAE Paper 2021-01-0575. Joshi, A. (2021). Review of vehicle engine efficiency and emissions. SAE Paper 2021-01-0575.
Zurück zum Zitat Kang, L. L., Lou, D. M., Zhang, Y. H., Fang, L., Zhao, Z. G., Tan, P. Q., Hu, Z. Y., Zhao, Y. K., & Hong, S. M. (2024). Effects of different EHC on times on gaseous particulate pollutants and energy consumption of PNA+DOC+SDPF system under low temperature and WHTC conditions. Applied Energy, 373, 123889.CrossRef Kang, L. L., Lou, D. M., Zhang, Y. H., Fang, L., Zhao, Z. G., Tan, P. Q., Hu, Z. Y., Zhao, Y. K., & Hong, S. M. (2024). Effects of different EHC on times on gaseous particulate pollutants and energy consumption of PNA+DOC+SDPF system under low temperature and WHTC conditions. Applied Energy, 373, 123889.CrossRef
Zurück zum Zitat Lehtoranta, K., Vesala, H., Koponen, P., Maunula, T., -Happonen, M. (2022). Emission performance of closed-coupled SCR catalysts to be applied for double-SCR systems. SAE Paper 2022-01-1016. Lehtoranta, K., Vesala, H., Koponen, P., Maunula, T., -Happonen, M. (2022). Emission performance of closed-coupled SCR catalysts to be applied for double-SCR systems. SAE Paper 2022-01-1016.
Zurück zum Zitat Liu, S. Y., Wang, B. Y., Guo, Z. X., Wang, B. Y., Zhang, Z. H., Ma, X., Chang, C. T., Wang, P., He, X., Sun, X. Y., & Shuai, S. J. (2022). Experimental investigation of urea injection strategy for close-coupled SCR aftertreatment system to meet ultra-low NOX emission regulation. Applied Thermal Engineering, 205, 117994.CrossRef Liu, S. Y., Wang, B. Y., Guo, Z. X., Wang, B. Y., Zhang, Z. H., Ma, X., Chang, C. T., Wang, P., He, X., Sun, X. Y., & Shuai, S. J. (2022). Experimental investigation of urea injection strategy for close-coupled SCR aftertreatment system to meet ultra-low NOX emission regulation. Applied Thermal Engineering, 205, 117994.CrossRef
Zurück zum Zitat Liu, S. Y., Zhang, Z. H., Guo, Z. X., Wang, B. Y., Wang, B. Y., Ma, X., & Shuai, S. J. (2024). Ammonia storage and slip under steady and transient state in close-coupled SCR. Journal of Environmental Sciences, 138, 470–481.CrossRef Liu, S. Y., Zhang, Z. H., Guo, Z. X., Wang, B. Y., Wang, B. Y., Ma, X., & Shuai, S. J. (2024). Ammonia storage and slip under steady and transient state in close-coupled SCR. Journal of Environmental Sciences, 138, 470–481.CrossRef
Zurück zum Zitat McCarthy, J., Jr., Matheaus, A., Zavala, B., Sharp, C., & Harris, T. (2022). Meeting future NOX emissions over various cycles using a fuel burner and conventional aftertreatment system. SAE International Journal of Advances and Current Practices in Mobility, 4(6), 2220–2234.CrossRef McCarthy, J., Jr., Matheaus, A., Zavala, B., Sharp, C., & Harris, T. (2022). Meeting future NOX emissions over various cycles using a fuel burner and conventional aftertreatment system. SAE International Journal of Advances and Current Practices in Mobility, 4(6), 2220–2234.CrossRef
Zurück zum Zitat Ministry of Ecology and Environment of the People’s Republic of China (2023). China mobile source environmental management annual report. Ministry of Ecology and Environment of the People’s Republic of China (2023). China mobile source environmental management annual report.
Zurück zum Zitat Okeleye, S. A., Thiruvengadam, A., Besch, M. C., Pradhan, S., & Carder, D. (2023). Performance characterization of a selective catalytic reduction on filter aftertreatment system in a heavy-duty diesel engine tested on a laboratory dynamometer. Journal of the Energy Institute, 110, 101330.CrossRef Okeleye, S. A., Thiruvengadam, A., Besch, M. C., Pradhan, S., & Carder, D. (2023). Performance characterization of a selective catalytic reduction on filter aftertreatment system in a heavy-duty diesel engine tested on a laboratory dynamometer. Journal of the Energy Institute, 110, 101330.CrossRef
Zurück zum Zitat Olsson, L., Blint, R. J., & Fridell, E. (2005). Global kinetic model for lean NOX traps. Industrial and Engineering Chemistry Research, 44, 3021–3032.CrossRef Olsson, L., Blint, R. J., & Fridell, E. (2005). Global kinetic model for lean NOX traps. Industrial and Engineering Chemistry Research, 44, 3021–3032.CrossRef
Zurück zum Zitat Olsson, L., Sjovall, H., & Blint, R. J. (2008). A kinetic model for ammonia selective catalytic reduction over Cu-ZSM-5. Applied Catalysis b: Environmental, 81, 203–217.CrossRef Olsson, L., Sjovall, H., & Blint, R. J. (2008). A kinetic model for ammonia selective catalytic reduction over Cu-ZSM-5. Applied Catalysis b: Environmental, 81, 203–217.CrossRef
Zurück zum Zitat Praveena, V., & Martin, M. L. J. (2018). A review on various after treatment techniques to reduce NOX emissions in a CI engine. Journal of the Energy Institute, 91, 704–720.CrossRef Praveena, V., & Martin, M. L. J. (2018). A review on various after treatment techniques to reduce NOX emissions in a CI engine. Journal of the Energy Institute, 91, 704–720.CrossRef
Zurück zum Zitat Rao, S., Sarlashkar, J., Rengarajan, S., Sharp, C., Neely, G. (2020). A controls overview on achieving ultra-low NOX. SAE Paper 2020-01-1404. Rao, S., Sarlashkar, J., Rengarajan, S., Sharp, C., Neely, G. (2020). A controls overview on achieving ultra-low NOX. SAE Paper 2020-01-1404.
Zurück zum Zitat Rauch, D., Kubinski, D., Simon, U., & Moos, R. (2014). Detection of the ammonia loading of a Cu chabazite SCR catalyst by a radio frequency-based method. Sensors and Actuators, b: Chemical, 205, 88–93.CrossRef Rauch, D., Kubinski, D., Simon, U., & Moos, R. (2014). Detection of the ammonia loading of a Cu chabazite SCR catalyst by a radio frequency-based method. Sensors and Actuators, b: Chemical, 205, 88–93.CrossRef
Zurück zum Zitat Sharp, C., Neely, G., Zavala, B., & Rao, S. (2021). CARB low NOX stage 3 program—final results and summary. SAE International Journal of Advances and Current Practices in Mobility, 3(4), 1508–1525.CrossRef Sharp, C., Neely, G., Zavala, B., & Rao, S. (2021). CARB low NOX stage 3 program—final results and summary. SAE International Journal of Advances and Current Practices in Mobility, 3(4), 1508–1525.CrossRef
Zurück zum Zitat Villafuerte, P. M., Demuynck, J., Bosteels, D., Recker, P., Wilkes, T., & Robb, L. M. (2021). Ultra-low NOX emissions with a close-coupled emission control system on a heavy-duty truck application. SAE International Journal of Advances and Current Practices in Mobility, 4(2), 602–609.CrossRef Villafuerte, P. M., Demuynck, J., Bosteels, D., Recker, P., Wilkes, T., & Robb, L. M. (2021). Ultra-low NOX emissions with a close-coupled emission control system on a heavy-duty truck application. SAE International Journal of Advances and Current Practices in Mobility, 4(2), 602–609.CrossRef
Zurück zum Zitat Wang, D. Y., Yao, S., Shost, M., Yoo, J. H., Cabush, D., Racine, D., Cloudt, R., & Willems, F. (2009). Ammonia sensor for closed-loop SCR control. SAE International Journal of Passenger Cars: Electronic and Electrical Systems, 1(1), 323–333. Wang, D. Y., Yao, S., Shost, M., Yoo, J. H., Cabush, D., Racine, D., Cloudt, R., & Willems, F. (2009). Ammonia sensor for closed-loop SCR control. SAE International Journal of Passenger Cars: Electronic and Electrical Systems, 1(1), 323–333.
Zurück zum Zitat Wei, L., Yan, F. W., Hu, J., Xi, G. W., Liu, B., & Zeng, J. W. (2017). NOX conversion efficiency optimization based on NSGA-II and state-feedback nonlinear model predictive control of selective catalytic reduction system in diesel engine. Applied Energy, 206, 959–971.CrossRef Wei, L., Yan, F. W., Hu, J., Xi, G. W., Liu, B., & Zeng, J. W. (2017). NOX conversion efficiency optimization based on NSGA-II and state-feedback nonlinear model predictive control of selective catalytic reduction system in diesel engine. Applied Energy, 206, 959–971.CrossRef
Zurück zum Zitat Willems, F., Cloudt, R., van den Eijnden, E., van Genderen, M., Verbeek, R., de Jager, B., Boomsma, W., van den Heuvel, I. (2007). Is closed-loop SCR control required to meet future emission targets? SAE Paper 2007-01-1574. Willems, F., Cloudt, R., van den Eijnden, E., van Genderen, M., Verbeek, R., de Jager, B., Boomsma, W., van den Heuvel, I. (2007). Is closed-loop SCR control required to meet future emission targets? SAE Paper 2007-01-1574.
Zurück zum Zitat Zavala, B., Sharp, C., Neely, G., Rao, S. (2020). CARB low NOX stage 3 program—aftertreatment evaluation and down selection. SAE Paper 2020-01-1402. Zavala, B., Sharp, C., Neely, G., Rao, S. (2020). CARB low NOX stage 3 program—aftertreatment evaluation and down selection. SAE Paper 2020-01-1402.
Zurück zum Zitat Zhong, C., Liang, J. W., Zhu, Y., Zuo, H. Y., Wang, S. L., Chen, B., Wu, X., & Wu, C. X. (2022). Effects analysis on soot oxidation performance in the diesel particulate filter based on synergetic passive-active composite regeneration methods. Chemical Engineering Science, 262, 118013.CrossRef Zhong, C., Liang, J. W., Zhu, Y., Zuo, H. Y., Wang, S. L., Chen, B., Wu, X., & Wu, C. X. (2022). Effects analysis on soot oxidation performance in the diesel particulate filter based on synergetic passive-active composite regeneration methods. Chemical Engineering Science, 262, 118013.CrossRef
Metadaten
Titel
Model-Based Two-Stage SCR Urea Injection Strategy for Diesel Engine to Meet Low NOX Emission Regulation
verfasst von
Jincheng Li
Haibo Sun
Gang Li
Zunqing Zheng
Mingfa Yao
Publikationsdatum
13.11.2024
Verlag
The Korean Society of Automotive Engineers
Erschienen in
International Journal of Automotive Technology
Print ISSN: 1229-9138
Elektronische ISSN: 1976-3832
DOI
https://doi.org/10.1007/s12239-024-00175-8