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Journal of Materials Science
Erschienen in: Journal of Materials Science 26/2020

14.05.2020 | Energy materials

MoO3 nanoplates: a high-capacity and long-life anode material for sodium-ion batteries

verfasst von: Caihong Yang, Qiankun Xiang, Xuemei Li, Yanqi Xu, Xin Wang, Xiangli Xie, Cunjun Li, Hai Wang, Linjiang Wang

Erschienen in: Journal of Materials Science | Ausgabe 26/2020

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Abstract

MoO3 has become a very promising energy storage material owing to its high theoretical capacity and layered structure. However, MoO3 suffers from low specific capacitance and fast degradation performance due to pulverization caused by volume change during discharge and charge process. Here, we report the MoO3 nanoplates (MoO3 NPs) from Mo-based metal–organic frameworks (Mo-MOFs) via a facile heating treatment. When used as an anode in sodium-ion batteries (SIBs), the material showed 154 mAh g−1 superior discharge capacity at 50 mA g−1 after 1200 cycles. Even at 500 mA g−1, it also showed 217 mAh g−1 high specific capacity after 500 cycles. This specific MoO3 material design strategy offers suitable conditions for relieving the volume expansion and provides multiple channels for Na+ transport and electron transfer in MoO3 during discharge and charge process. This work highlights the importance of MoO3 nanoplates in preventing the pulverization caused by volume expansion in SIBs.
Vorheriger Artikel NH2–MIL-88B–Fe for electrocatalytic N2 fixation to NH3 with high Faradaic efficiency under ambient conditions in neutral electrolyte
Nächster Artikel Direct fabrication of graphene oxide fiber by injection spinning for flexible and wearable electronics

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Metadaten
Titel
MoO3 nanoplates: a high-capacity and long-life anode material for sodium-ion batteries
verfasst von
Caihong Yang
Qiankun Xiang
Xuemei Li
Yanqi Xu
Xin Wang
Xiangli Xie
Cunjun Li
Hai Wang
Linjiang Wang
Publikationsdatum
14.05.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 26/2020
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-04788-z

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