nach oben

Journal of Materials Engineering and Performance

Erschienen in:

08.07.2020

Morphology Analysis and Characterization of Clinoptilolite/Polyvinylpyrrolidone-Zeolite Composite Nanofibers

verfasst von: Ehsan Assar, Amirhossein Meysami, Maryam Zare

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 7/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

In this study, clinoptilolite/PVP (Polyvinyl pyrrolidone)-zeolite composite nanofibers were synthesized using the electrospinning method. The effects of process parameters including solution concentration, spinning voltage, and spinning distance were examined on morphology and fibers diameter. Electrospun nanofibers were studied by scanning electron microscope (SEM), x-ray diffraction (XRD), and BET method. SEM images have demonstrated the steady and straight ribbon-shaped fiber from electrospinning solution with 1.8:1.8:6.4 weight ratio of clinoptilolite:PVP:ethanol, respectively. It resulted that the diameter of fabricated nanofibers is about 182 nm at 1.8:1.8:6.4 weight ratios of clinoptilolite:PVP:ethanol at a 20 cm distance and 13 kV voltage as optimal parameters. The average of fibers diameter reduced following the increase in electrospinning distance. By increasing voltage, the average of fiber diameter decreased in 15 cm distance and increased in 20 cm distance. XRD results for both particles and electrospun nanofibers show the clinoptilolite-Ca structure. The BET surface areas are measured to be 20 and 5 m² g⁻¹ for clinoptilolite particles and clinoptilolite/PVP electrospun nanofibers, respectively. Also, BET analysis showed that mesoporosity of clinoptilolite particles was preserved after putting nanoparticles inside the polymer nanofibers.

Vorheriger Artikel Comparison Study of Low-Heat-Input Wire Arc-Fabricated Nickel-Based Alloy by Cold Metal Transfer and Plasma Arc

Nächster Artikel Multipass Friction Stir Processing of Steel/SiC Nanocomposite: Assessment of Microstructure and Tribological Properties

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

M.Zh. Kussainova, R.M. Chernyakova, U.Z. Jussipbekov, and S. Paşa, Structural Investigation of Raw Clinoptilolite over the Pb²⁺ Adsorption Process from Phosphoric Acid, J. Mol. Struct., 2019, 1184, p 49–58. https://doi.org/10.1016/j.molstruc.2019.02.012CrossRef

M. Vocciante, D. De Folly, A. Auris, A. Finocchi, M. Tagliabue, M. Bellettato, A. Ferrucci, A. Reverberi, and S. Ferro, Adsorption of Ammonium on Clinoptilolite in Presence of Competing Cations: Investigation on Groundwater Remediation, J. Clean. Prod., 2018, 198, p 480–487. https://doi.org/10.1016/j.jclepro.2018.07.025CrossRef

M.E. Kouli, G. Banis, P. Tsarabaris, A. Ferraro, and E. Hristoforou, A Study on Magnetic Removal of Sodium, Calcium and Potassium Ions from Seawater Using Magnetite/Clinoptilolite–Na Composite Nanoparticles, J. Magn. Magn. Mater., 2018, 465, p 692–699. https://doi.org/10.1016/j.jmmm.2018.06.064CrossRef

D.A. De Haro-Del Rio, S. Al-Joubori, O. Kontogiannis, D. Papadatos-Gigantes, O. Ajayi, C. Li, and S.M. Holmes, The Removal of Caesium Ions Using Supported Clinoptilolite, J. Hazard. Mater., 2015, 289, p 1–8. https://doi.org/10.1016/j.jhazmat.2015.02.032CrossRef

B.G. Saucedo-Delgado, D.A. De Haro-Del Rio, L.M. González-Rodríguez, H.E. Reynel-Ávila, D.I. Mendoza-Castillo, A. Bonilla-Petriciolet, and J. Rivera de la Rosa, Fluoride Adsorption from Aqueous Solution Using a Protonated Clinoptilolite and Its Modeling with Artificial Neural Network-Based Equations, J. Fluorine Chem., 2017, 204, p 98–106. https://doi.org/10.1016/j.jfluchem.2017.11.002CrossRef

V.O. Vasylechko, G.V. Gryshchouk, V.P. Zakordonskiy, I.O. Patsay, N.V. Len, and O.A. Vyviurska, Sorption of Terbium on Transcarpathian Clinoptilolite, Microporous Mesoporous Mater., 2013, 167, p 155–161. https://doi.org/10.1016/j.micromeso.2012.08.021CrossRef

A. Casadellà, P. Kuntke, O. Schaetzle, and K. Loos, Clinoptilolite-Based Mixed Matrix Membranes for the Selective Recovery of Potassium and Ammonium, Water Res., 2016, 90, p 62–70. https://doi.org/10.1016/j.watres.2015.12.017CrossRef

H. Kazemian and M.H. Mallah, Elimination of Cd²⁺ and Mn²⁺ from Wastewaters Using Natural Clinoptilolite and Synthetic Zeolite P, Iran. J. Chem. Chem. Eng., 2006, 25, p 91–94

S. Fatima-Anis, A. Khalil, Saepurahman, G. Singaravel, and R. Hashaikeh, A Review on the Fabrication of Zeolite and Mesoporous Inorganic Nanofibers Formation for Catalytic Applications, Microporous Mesoporous Mater., 2016, 236, p 176–192. https://doi.org/10.1016/j.micromeso.2016.08.043CrossRef

10.

L. Kong and G.R. Ziegler, Role of Molecular Entanglements in Starch Fiber Formation by Electrospinning, Biomacromol, 2012, 13, p 2247–2253. https://doi.org/10.1016/j.micromeso.2016.08.043CrossRef

11.

L. Fan, M. Xue, Z. Kang, H. Li, and S. Qiu, Electrospinning Technology Applied in Zeolitic Imidazolate Framework Membrane Synthesis, J. Mater. Chem., 2012, 22, p 25272–25276. https://doi.org/10.1039/C2JM35401BCrossRef

12.

J. Di, Y. Zhao, and J. Yu, Fabrication of Molecular Sieve Fibers by Electrospinning, J. Mater. Chem., 2011, 21, p 8511–8520. https://doi.org/10.1039/C1JM10512DCrossRef

13.

S. Fatima Anis and R. Hashaikeh, Electrospun Zeolite-Y Fibers: Fabrication and Morphology Analysis, Microporous Mesoporous Mater., 2016, 233, p 78–86. https://doi.org/10.1016/j.micromeso.2015.11.022CrossRef

14.

A. Bahi, J. Shao, M. Mohseni, and F.K. Ko, Membranes Based on Electrospun Lignin-Zeolite Composite Nanofibers, Sep. Purif. Technol., 2017, 187, p 207–213. https://doi.org/10.1016/j.seppur.2017.06.015CrossRef

15.

S.H. Ji, J.H. Cho, Y.H. Jeong, J.D. Yun, and J.S. Yun, The Synthesis of Flexible Zeolite Nanofibers by a Polymer Surface Thermal Etching Process, Appl. Surf. Sci., 2017, 416, p 178–182. https://doi.org/10.1016/j.apsusc.2017.04.077CrossRef

16.

J.M. Deitzel, J. Kleinmeyer, D. Harris, and N.C. Beck Tan, The Effect of Processing Variables on the Morphology of Electrospun Nanofibers and Textiles, Polymer, 2001, 42, p 261–272. https://doi.org/10.1016/s0032-3861(00)00250-0CrossRef

17.

S. Megelski, J.S. Stephens, D.B. Chase, and J.F. Rabolt, Micro- and Nanostructured Surface Morphology on Electrospun Polymer Fibers, Macromolecules, 2002, 35, p 8456–8466. https://doi.org/10.1021/ma020444aCrossRef

18.

G. Eda and S. Shivkumar, Bead-to-Fiber Transition in Electrospun Polystyrene, J. Appl. Polym. Sci., 2007, 106, p 475–487. https://doi.org/10.1002/app.25907CrossRef

19.

K.H. Lee, H.Y. Kim, H.J. Bang, Y.H. Jung, and S.G. Lee, The Change of Bead Morphology Formed on Electrospun Polystyrene Fibers, Polymer, 2003, 44, p 4029–4034. https://doi.org/10.1016/j.polymer.2008.09.025CrossRef

20.

X. Yuan, Y. Zhang, C. Dong, and J. Sheng, Morphology of Ultrafine Polysulfone Fibers Prepared by Electrospinning, Polym. Int., 2004, 53, p 1704–1710. https://doi.org/10.1002/pi.1538CrossRef

21.

S. Ramakrishna, K. Fujihara, W.E. Teo, T.C. Lim, and Z. Ma, An Introduction to Electrospinning and Nanofibers, 1st ed., World Scietific, Singapore, 2005, p 259–271CrossRef

22.

T. Subbiah, G.S. Bhat, R.W. Tock, S. Parameswaran, and S.S. Ramkumar, Electrospinning of Nanofibers, J. Appl. Polym. Sci., 2005, 96, p 557–569. https://doi.org/10.1002/app.21481CrossRef

23.

C.S. Ki, D.H. Baek, K.D. Gang, K.H. Lee, I.C. Um, and Y.H. Park, Characterization of Gelatin Nanofiber Prepared from Gelatin–Formic Acid Solution, Polymer, 2005, 46, p 5094–5102. https://doi.org/10.1016/j.polymer.2005.04.040CrossRef

Titel: Morphology Analysis and Characterization of Clinoptilolite/Polyvinylpyrrolidone-Zeolite Composite Nanofibers
verfasst von: Ehsan Assar
Amirhossein Meysami
Maryam Zare
Publikationsdatum: 08.07.2020
Verlag: Springer US
Erschienen in: Journal of Materials Engineering and Performance / Ausgabe 7/2020
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI: https://doi.org/10.1007/s11665-020-04943-2

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 7/2020

An Experimental Study of Rolled Friction-Stir-Welded Aluminum 6061-T6 Joints Subjected to Static and Fatigue Loading Conditions

Cruciform Specimen Machining Using EDM and a New Design Verification for Biaxial Testing

Friction and Reciprocating Wear Behavior of Borided AISI H13 Steel Under Dry and Lubricated Conditions

Dry Sliding-Friction and Wear Behavior of Hot-Extruded Al6061/Si3N4/Cf Hybrid Metal Matrix Composite

Rapid Tempering: Opportunities and Challenges

Synthesis and Fabrication of Y-Doped ZnO Nanoparticles and Their Application as a Gas Sensor for the Detection of Ammonia

Premium Partner

Marktübersichten