nach oben

Cellulose

Erschienen in:

17.05.2018 | Original Paper

Multi-functional finishing of cotton fabrics by water-based layer-by-layer assembly of metal–organic framework

verfasst von: Lu Lu, Cuicui Hu, Yanjie Zhu, Huanhuan Zhang, Rong Li, Yanjun Xing

Erschienen in: Cellulose | Ausgabe 7/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

A multi-functional cotton fabric with UV resistance, antibacterial and superhydrophobic properties was achieved by immobilizing metal–organic framework ZnBDC on the fabric surface using zinc(II) acetate and 1,4-benzenedicarboxylic acid as raw materials. The immobilization of ZnBDC was performed via water-based layer-by-layer (LbL) deposition based on the concept of self-assemble. The ZnBDC on cotton surface was characterized by XRD, ATR-FTIR, SEM, UV–Vis spectra, TG and adsorption of Rhodamine B. The results indicated the ZnBDC was formed as a partially hydrolyzed phase of MOF-5 on the fabric surface during the LbL deposition. The porous structure of ZnBDC was kept after the deposition. The effect of deposition cycle, deposition temperature and time on the deposition of ZnBDC has been studied. The results showed that the ZnBDC deposited cotton fabric had an excellent anti-UV properties with UPF 50 +, T(UV-A) and T(UV-B) < 5%. The ZnBDC deposited cotton fabric exhibited an excellent antimicrobial effect on gram-positive bacteria Staphylococcus aureus and gram-negative bacteria Escherichia coli. The treatment of sodium stearate further imparted the superhydrophobic property on the ZnBDC deposited cotton fabric with water contact angle > 150°.

Graphical Abstract

Vorheriger Artikel Imparting superhydrophobic and antibacterial properties onto the cotton fabrics: synergistic effect of zinc oxide nanoparticles and octadecanethiol

Nächster Artikel Conductive and durable CNT-cotton ring spun yarns

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Abbasi A, Akhbari K, Morsali A (2012) Dense coating of surface mounted CuBTC metal–organic framework nanostructures on silk fibers, prepared by layer-by-layer method under ultrasound irradiation with antibacterial activity. Ultrason Sonochem 19(4):846–852. https://doi.org/10.1016/j.ultsonch.2011.11.016 CrossRefPubMed

Abdelhameed RM, Abdel-Gawad H, Elshahat M, Emam HE (2016) Cu-BTC@cotton composite: design and removal of ethion insecticide from water. RCS Adv 6(48):42324–42333. https://doi.org/10.1039/C6RA04719J CrossRef

Abdelhameed RM, Emam HE, Rocha E, Silva J (2017a) Cu-BTC metal–organic framework natural fabric composites for fuel purification. Fuel Process Technol 159:306–312. https://doi.org/10.1016/j.fuproc.2017.02.001 CrossRef

Abdelhameed RM, Omhm K, Amr A, Rocha E, Ams S (2017b) Antimosquito activity of titanium-organic framework supported on fabrics. ACS Appl Mater Interface 9(27):22112–22120. https://doi.org/10.1021/acsami.7b03164 CrossRef

Andrea C, Ying Y, Scott S, Bromberg L, Rutledge G, Hatton T (2010) Growth of metal–organic framework on polymer surfaces. J Am Chem Soc 132(44):15687–15691. https://doi.org/10.1021/ja106381x CrossRef

Canivet J, Fateeva A, Guo Y, Coasne B, Farrusseng D (2014) Water adsorption in MOFs: fundamentals and applications. Chem Soc Rev 43(16):5594–5617. https://doi.org/10.1039/C4CS00078A CrossRefPubMed

Cheng YN, Xiao LW, Li HL, Ye Z (2015) Concentration ranges of antibacterial cations for showing the highest antibacterial efficacy but the least cytotoxicity against mammalian cells: implications for a new antibacterial mechanism. Chem Res Toxicol 28(9):1815–1822. https://doi.org/10.1021/acs.chemrestox.5b00258 CrossRef

Emam HE, Abdelhameed RM (2007) In-situ modification of natural fabrics by Cu-BTC MOF for effective release of insect repellent (N, N-diethyl-3-methylbenzamide). J Porous Mater 24:1175–1185. https://doi.org/10.1007/s10934-016-0357-y CrossRef

Emam HE, Abdelhameed RM (2017) Anti-UV radiation textiles designed by embracing with nano-MIL (Ti, In)-metal organic framework. ACS Appl Mater Interface 9(33):28034–28045. https://doi.org/10.1021/acsami.7b07357 CrossRef

French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21(2):885–896. https://doi.org/10.1007/s10570-013-0030-4 CrossRef

French AD, Cintron MS (2013) Cellulose polymorphy, crystallite size, and the Segal Crystallinity Index. Cellulose 20(1):583–588. https://doi.org/10.1007/s10570-012-9833-y CrossRef

Getachew N, Chebude Y, Diaz I, Sanchez-Sanche M (2014) Room temperature synthesis of metal organic framework MOF-2. J Porous Mater 21(5):769–773. https://doi.org/10.1007/s10934-014-9823-6 CrossRef

Haendel S, Rodriguez P, Ochoa-Puentes C, Sierra C, Soto C (2014) Antibacterial activity against Escherichia coil of Cu-BTC (MOF-199) metal–organic framework immobilized onto cellulosic fibers. J Appl Polym Sci 131(19):40815–40820. https://doi.org/10.1002/app.40815 CrossRef

Hafizovic J, Bjørgen M, Olsbye U, Dietzel PDC, Bordiga S, Prestipino C, Lamberti C, Lillerud KP (2007) The inconsistency in adsorption properties and powder XRD data of MOF-5 is rationalized by framework interpenetration and the presence of organic and inorganic species in the nanocavities. J Am Chem Soc 129(12):3612–3620. https://doi.org/10.1021/ja0675447 CrossRefPubMed

Han JS, Morsali A (2014) Ultrasound-promoted coating of MOF-5 on silk fiber and study of adsorptive removal and recovery of hazardous anionic dye “congo red”. Ultrason Sonochem 21(4):1424–1429. https://doi.org/10.1016/j.ultsonch.2013.12.012 CrossRef

Hermes S, Schröder F, Chelmowski R, Wöll C, Fischer RA (2005) Selective nucleation and growth of metal–organic open framework thin films on patterned COOH/CF3-terminated self-assembled monolayers on Au (111). J Am Chem Soc 127(40):13744–13745. https://doi.org/10.1021/ja053523l CrossRefPubMed

Horcajada P, Serre C, Vallet-Regí M, Sebban M, Taulelle F, Férey G (2006) Metal–organic frameworks as efficient materials for drug delivery. Angew Chem Int Ed Engl 45(36):5974–5978. https://doi.org/10.1002/anie.200601878/ CrossRefPubMed

Horcajada P, Serre C, Maurin G, Ramsahye N, Balas F, Vallet-Regí M, Sebban M, Taulelle F, Férey G (2008) Flexible porous metal–organic frameworks for a controlled drug delivery. J Am Chem Soc 130(21):6774–6780. https://doi.org/10.1021/ja710973k CrossRefPubMed

Huang L, Wang H, Chen J, Wang Z, Sun J, Zhao D, Yan Y (2003) Synthesis, morphology control, and properties of porous metal–organic coordination polymers. Microporous Mesoporous Mater 58(2):105–114. https://doi.org/10.1016/S1387-1811(02)00609-1 CrossRef

Hwang YK, Hong DY, Chang JS, Jhung S, Seo Y, Kim J, Vimont A, Daturi M, Serre C, Ferey G (2008) Amine grafting on coordinatively unsaturated metal centers of MOFs: consequences for catalysis and metal encapsulation. Angew Chem Int Ed Engl 47(22):4144–4148. https://doi.org/10.1002/anie.200705998 CrossRefPubMed

Kaewprasit C, Hequet E, Abidi N, Gourlot JP (1998) Application of methylene blue adsorption to cotton fiber specific surface area measurement: Part I. Methodology. J Cotton Sci 2(4):164–173

Kaye SS, Dailly A, Yaghi OM, Long JR (2007) Impact of preparation and handling on the hydrogen storage properties of Zn₄O(1,4-benzenedicarboxylate)₃ (MOF-5). J Am Chem Soc 129(46):14176–14177. https://doi.org/10.1021/ja076877g CrossRefPubMed

Lopez-Maya E, Montoro C, Rodriguez-Albelo L, Cervantes S, Lozano-Pérez A, Cenís J, Barea E, Navarro J (2015) Textile/metal–organic-framework composites as self-detoxifying filters for chemical-warfare agents. Angew Chem Int Ed Engl 54(23):6790–6794. https://doi.org/10.1002/anie.201502094 CrossRefPubMed

Lu A, McEntee M, Browe MA, Hall MG, DeCoste JB, Peterson GW (2017) MOFabric: electrospun nanofiber mats from PVDF/UiO-66-NH₂ for chemical protection and decontamination. ACS Appl Mater Interfaces 9(15):13632–13636. https://doi.org/10.1021/acsami.7b01621 CrossRefPubMed

Makiura R, Kitagawa H (2010) Porous porphyrin nanoarchitectures on surfaces. Eur J Inorg Chem 24:3715–3724. https://doi.org/10.1002/ejic.201000730 CrossRef

Makiura R, Moyoyama S, Umemura Y, Yamanaka H, Sakata O, Kitagawa H (2010) Surface nano-architecture of a metal–organic framework. Nat Mater 9(7):565–571. https://doi.org/10.1038/nmat2769 CrossRefPubMed

Masoomi MY, Morsali A (2012) Applications of metal–organic coordination polymers as precursors for preparation of nano-materials. Coord Chem Rev 256(23–24):2921–2943. https://doi.org/10.1016/j.ccr.2012.05.032 CrossRef

Mcdonald R (1997) Color physics for industry, 2nd edn. Society of Dyers and Colorists, Bradford

Mcinally A, Mather RR, Sing KSW (1991) The porosity of textile fibre surfaces. In: Reinoso R, Rouquerol J, Sing KSW (eds) Characterization of porous solids II. Elsevier, Amsterdam, pp 409–418. https://doi.org/10.1016/s0167-2991(08)61346-4 CrossRef

Moon HR, Kim JH, Suh MP (2005) Redox-active porous metal–organic framework producing silver nanoparticles from AgI ions at room temperature. Angew Chem Int Ed Engl 117(8):1261–1265. https://doi.org/10.1002/ange.200461408 CrossRef

Motoyama S, Makiura R, Sakata O, Kitagawa H (2011) Highly crystalline nanofilm by layering of porphyrin metal–organic framework sheets. J Am Chem Soc 133(15):5640–5643. https://doi.org/10.1021/ja110720f CrossRefPubMed

Neufeld M, Harding J, Reynolds M (2015) Immobilization of metal–organic framework copper(II) benzene-1,3,5-tricarboxylate (CuBTC) onto cotton fabric as a nitric oxide release catalyst. ACS Appl Mater Interface 7(48):26742–26750. https://doi.org/10.1021/acsami.5b08773 CrossRef

Okano T, Sarko A (1985) Mercerization of cellulose II. Alkali–cellulose intermediates and a possible mercerization mechanism. J Appl Polym Sci 30(2):325–332. https://doi.org/10.1002/app.1985.070300128 CrossRef

Ozer R, Hinestroza J (2015) One-step growth of isoreticular luminescent metal–organic frameworks on cotton fibers. RSC Adv 5(20):15198–15204. https://doi.org/10.1039/C4RA15161E CrossRef

Pan CY, Shen L, Shang SM, Xing YJ (2012) Preparation of superhydrophobic and UV blocking cotton fabric via sol–gel method and self-assembly. Appl Surf Sci 259(2):110–117. https://doi.org/10.1016/j.apsusc.2012.07.001 CrossRef

Pan Q, Zhi MS, De J, Wang X, Wu Z, Liu ZD (2013) Application of two reactive water-soluble antibacterials on polyester/cotton blend fabrics. Adv Mater Res 821–822:642–645. https://doi.org/10.4028/www.scientific.net/AMR.821-822.642 CrossRef

Park E, Moon W, Song M, Kim M, Chung K, Yoon J (2001) Antibacterial activity of phenol and benzoic acid derivatives. Int Biodeter Biodegr 47(4):209–214. https://doi.org/10.1016/S0964-8305(01)00058-0 CrossRef

Paul R (2014) Functional finishes for textiles: improving comfort, performance and protection. Woodhead Publishing, Cambridge

Ren J, Rogers D, Segakweng T, Langmi HW, North BC, Mathe M, Bessarabov D (2014) Thermal treatment induced transition from Zn₃(OH)₂(BDC)₂ (MOF-69c) to Zn₄O(BDC)₃ (MOF-5). Int J Mater Res 105(1):89–93. https://doi.org/10.3139/146.110994 CrossRef

Rodriguez NA, Parra R, Grela MA (2015) Structural characterization, optical properties and photocatalytic activity of MOF-5 and its hydrolysis products: implications on their excitation mechanism. RSC Adv 5(89):73112–73118. https://doi.org/10.1039/C5RA11182J CrossRef

Rowen JW, Blaine RL (1947) Sorption of nitrogen and water vapor on textile fibers. Ind Eng Chem 39:1659–1663CrossRef

Sabo M, Henschel A, Frode H, Klemmb E, Kaskel S (2007) Solution infiltration of palladium into MOF-5: synthesis, physisorption and catalytic properties. J Mater Chem 17(36):3827–3832. https://doi.org/10.1039/b706432b CrossRef

Saha D, Deng S, Yang Z (2009) Hydrogen adsorption on metal–organic framework (MOF-5) synthesized by DMF approach. J Porous Mater 16(2):141–149. https://doi.org/10.1007/s10934-007-9178-3 CrossRef

Wang Z, Wang J, Li M, Sun K (2014) Three-dimensional printed acrylonitrile butadiene styrene framework coated with Cu-BTC metal–organic frameworks for removal of methylene blue. Sci Rep 4:5939–5945. https://doi.org/10.1038/srep05939 CrossRefPubMedPubMedCentral

Wu CM, Rathi M, Ahrenkiel SP, Koodali RT, Wang Z (2013) Facile synthesis of MOF-5 confined in SBA-15 hybrid material with enhanced hydrostability. Chem Commun 49(12):1223–1225. https://doi.org/10.1039/C2CC38366G CrossRef

Yaghi OM, O’Keeffe M, Ockwig NW, Chae HK, Eddaoudi M, Kim J (2003) Reticular synthesis and the design of new materials. Nature 423(6941):705–714. https://doi.org/10.1038/nature01650 CrossRefPubMed

Yang C, Wang X, Omary MA (2007) Fluorous metal–organic frameworks for high-density gas adsorption. J Am Chem Soc 129(50):15454–15455. https://doi.org/10.1021/ja0775265 CrossRefPubMed

Zhang L, Hu YH (2010) A systematic investigation of decomposition of nano Zn₄O(C₈H₄O₄)₃ metal–organic framework. J Phys Chem C 114(6):2566–2572. https://doi.org/10.1021/jp911043r CrossRef

Zhao J, Gong B, Nunn W, Lemaire P, Stevens E, Sidi F, Williams P, Oldham C, Walls H, Shepherd S, Browe M, Peterson G, Losego M, Parsons G (2015) Conformal and highly adsorptive metal–organic framework thin films via layer-by-layer growth on ALD-coated fiber mats. J Mater Chem A 3(4):1458–1464. https://doi.org/10.1039/C4TA05501B CrossRef

Titel: Multi-functional finishing of cotton fabrics by water-based layer-by-layer assembly of metal–organic framework
verfasst von: Lu Lu
Cuicui Hu
Yanjie Zhu
Huanhuan Zhang
Rong Li
Yanjun Xing
Publikationsdatum: 17.05.2018
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 7/2018
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-018-1838-8

Springer Professional

Abstract

Graphical Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 7/2018

MWCNTs-COOH/cotton flexible supercapacitor electrode prepared by improvement one-time dipping and carbonization method

Highly efficient visible-light photocatalyst based on cellulose derived carbon nanofiber/BiOBr composites

Synergistic effects of enzyme pretreatment for hemicellulose separation from paper-grade pulp in ionic liquid/water

Biobleaching of waste paper using lignolytic enzyme from Fusarium equiseti VKF2: a mangrove isolate

Fabrication of mechanically robust and UV-resistant aramid fiber-based composite paper by adding nano-TiO2 and nanofibrillated cellulose

Conductive and durable CNT-cotton ring spun yarns