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Cellulose

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28.10.2019 | Original Research

Multifunctional UV-shielding nanocellulose films modified with halloysite nanotubes-zinc oxide nanohybrid

verfasst von: Dechao Hu, Zhilin Zhang, Maolin Liu, Jing Lin, Xiaojun Chen, Wenshi Ma

Erschienen in: Cellulose | Ausgabe 1/2020

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Abstract

The design and fabrication of multifunctional UV-shielding materials based on naturally abundant and biodegradable raw materials have far-reaching significance for various practical applications and sustainable development. In the present work, novel multifunctional cellulose nanofibrils (CNFs)/halloysite nanotubes-zinc oxide (HNTs-ZnO) hybrid films with synergic feature of excellent UV-shielding, superhydrophobic properties and thermal stability were firstly fabricated via vacuum-assisted filtration strategy and following hydrophobic modification. The successful immobilization of ZnO nano-protrusions on HNTs surface effectively suppressed the aggregation of ZnO nanoparticles, giving a positive contribution for the UV-shielding performance. Particularly, the CNFs/HNTs-ZnO hybrid films achieved a high UV-blocking efficiency in both UVA (95.7%), UVB (98.7%) and UVC (99.8%). Besides, the filtration membrane template endowed the CNFs/HNTs-ZnO hybrid films with hierarchical rough architecture, and as-fabricated hybrid films presented superhydrophobicity with a contact angle over 155° and simultaneous self-cleaning function. Moreover, the CNFs/HNTs-ZnO hybrid films also displayed an outstanding thermal and UV stability. The findings conceivably indicate that the CNFs/HNTs-ZnO hybrid films provide a versatile way for the development of sustainable multifunctional UV-shielding films and have promising applications in packaging, intelligent windows and other outdoor UV-sensitive materials areas.

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Vorheriger Artikel Improvement of platelet aggregation and rapid induction of hemostasis in chitosan dressing using silver nanoparticles

Nächster Artikel Synthesizing green carbon dots with exceptionally high yield from biomass hydrothermal carbon

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Titel: Multifunctional UV-shielding nanocellulose films modified with halloysite nanotubes-zinc oxide nanohybrid
verfasst von: Dechao Hu
Zhilin Zhang
Maolin Liu
Jing Lin
Xiaojun Chen
Wenshi Ma
Publikationsdatum: 28.10.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2020
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02796-0

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