nach oben

Wood Science and Technology

Erschienen in:

30.07.2018 | Original

Myth versus reality: Do parabolic sorption isotherm models reflect actual wood–water thermodynamics?

verfasst von: Samuel L. Zelinka, Samuel V. Glass, Emil Engelund Thybring

Erschienen in: Wood Science and Technology | Ausgabe 6/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

It has been known for over 35 years that commonly used sorption isotherm models fail to correctly predict wood–water properties such as heat of sorption. Despite this, their use to determine thermodynamic quantities and monolayer moisture contents persists and in fact is increasing in frequency. In this paper, we recommend the use of the “ABC isotherm,” which is mathematically equivalent to sorption isotherm models commonly used for wood but has the added benefits of simplicity, avoidance of a conceptual image of water sorption that is contradicted by measurements, and avoidance of any additional step of identifying quantities that are physically incorrect.

Vorheriger Artikel Chemical composition of lipophilic extractives from six Eucalyptus barks

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Anderson RB (1946) Modifications of the Brunauer, Emmett, and Teller equation. J Am Chem Soc 68:686–691CrossRef

Anderson RB, Hall WK (1948) Modifications of the Brunauer, Emmett, and Teller equation II. J Am Chem Soc 70:1727–1734. https://doi.org/10.1021/ja01185a017 CrossRefPubMed

Araujo CD, Avramidis S, Mackay AL (1994) Behavior of solid wood and bound water as a function of moisture-content a proton magnetic-resonance study. Holzforschung 48:69–74CrossRef

Boquet R, Chirife J, Iglesias HA (1980) Technical note—on the equivalence of isotherm equations. J Food Technol 15:345–349CrossRef

Bratasz Ł, Kozłowska A, Kozłowski R (2012) Analysis of water adsorption by wood using the Guggenheim–Anderson-de Boer equation. Eur J Wood Prod 70:445–451. https://doi.org/10.1007/s00107-011-0571-x CrossRef

Brunauer S, Emmett PH, Teller E (1938) Adsorption of gases in multimolecular layers. J Am Chem Soc 60:309–319CrossRef

Chauhan SS, Aggarwal P, Karmarkar A, Pandey KK (2001) Moisture adsorption behaviour of esterified rubber wood (Hevea brasiliensis). Holz Roh Werkst 59:250–253CrossRef

Chen C-M, Wangaard FF (1968) Wettability and the hysteresis effect in the sorption of water vapor by wood. Wood Sci Technol 2:177–187

De Boer JH (1953) The dynamical character of adsorption. Clarendon Press, Oxford

Dent RW (1977) Multilayer theory for gas sorption. 1 Sorption of a single gas. Text Res J 47:145–152CrossRef

Dieste A, Krause A, Militz H (2008) Modification of Fagus sylvatica (L.) with 1,3-dimethylol-4,5-dihydroxyethylene urea (DMDHEU): Part 1. Estimation of heat adsorption by the isosteric method (Hailwood–Horrobin model) and by solution calorimetry. Holzforschung 62:577–583CrossRef

Esteban LG, Fernandez FG, Casasus AG, De Palacios PD, Gril J (2006) Comparison of the hygroscopic behaviour of 205-year-old and recently cut juvenile wood from Pinus sylvestris L. Ann For Sci 63:309–317CrossRef

Esteban LG, de Palacios P, Fernández FG, Guindeo A, Cano NN (2008a) Sorption and thermodynamic properties of old and new Pinus sylvestris wood. Wood Fiber Sci 40:111–121

Esteban LG, de Palacios P, Fernandez FG, Guindeo A, Conde M, Baonza V (2008b) Sorption and thermodynamic properties of juvenile Pinus sylvestris L. wood after 103 years of submersion. Holzforschung 62:745–751. https://doi.org/10.1515/hf.2008.106 CrossRef

Esteban LG, de Palacios P, Fernandez FG, Martin JA, Genova M, Fernandez-Golfin JI (2009) Sorption and thermodynamic properties of buried juvenile Pinus sylvestris L. wood aged 1,170 ± A 40 BP. Wood Sci Technol 43:679–690. https://doi.org/10.1007/s00226-009-0261-6 CrossRef

Esteban LG, de Palacios P, Fernandez FG, Garcia-Amorena I (2010) Effects of burial of Quercus spp. wood aged 5910 ± 250 BP on sorption and thermodynamic properties. Int Biodeterior Biodegrad 64:371–377. https://doi.org/10.1016/j.ibiod.2010.01.010 CrossRef

Guggenheim EA (1966) Applications of statistical mechanics. Oxford University Press, New York

Hailwood AJ, Horrobin S (1946) Absorption of water by polymers: analysis in terms of a simple model. Trans Faraday Soc 42:B084–B092. https://doi.org/10.1039/TF946420B084 CrossRef

Hartley ID (2000) Application of the GAB sorption isotherm model to Klinki Pine (Araucaria klinkii Lauterb.). Holzforschung 54:661–663. https://doi.org/10.1515/hf.2000.111 CrossRef

Hill CAS, Norton A, Newman G (2009) The water vapor sorption behavior of natural fibers. J Appl Polym Sci 112:1524–1537. https://doi.org/10.1002/app.29725 CrossRef

Hill CAS, Norton A, Newman G (2010) The water vapour sorption properties of Sitka spruce determined using a dynamic vapour sorption apparatus. Wood Sci Technol 44:497–514CrossRef

Jalaludin Z, Hill CAS, Samsi HW, Husain H, Xie Y (2010a) Analysis of water vapour sorption of oleo-thermal modified wood of Acacia mangium and Endospermum malaccense by a parallel exponential kinetics model and according to the Hailwood–Horrobin model. Holzforschung 64:763–770CrossRef

Jalaludin Z, Hill CAS, Xie Y, Samsi HW, Husain H, Awang K, Curling SF (2010b) Analysis of the water vapour sorption isotherms of thermally modified acacia and sesendok. Wood Mater Sci Eng 5:194–203CrossRef

Kelsey K (1957) The sorption of water vapour by wood Aust J Appl Sci 8

Krupińska B, Strømmen I, Pakowski Z, Eikevik TM (2007) Modeling of sorption isotherms of various kinds of wood at different temperature conditions. Dry Technol 25:1463–1470. https://doi.org/10.1080/07373930701537062 CrossRef

Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40:1361–1403CrossRef

Murata K, Watanabe Y, Nakano T (2013) Effect of thermal treatment on fracture properties and adsorption properties of spruce wood. Materials 6:4186–4197. https://doi.org/10.3390/ma6094186 CrossRefPubMedPubMedCentral

Olek W, Majka J, Czajkowski L (2013) Sorption isotherms of thermally modified wood. Holzforschung 67:183–191. https://doi.org/10.1515/hf-2011-0260 CrossRef

Papadopoulos AN (2005) Moisture adsorption isotherms of two esterified Greek hardwoods. Holz Roh Werkst 63:123–128CrossRef

Papadopoulos A (2011) Sorption studies of chemically modified elm wood with acetic or maleic anhydride. J Indian Acad Wood Sci 8:32–36. https://doi.org/10.1007/s13196-011-0020-9 CrossRef

Papadopoulos AN (2012) Sorption of acetylated pine wood decayed by brown rot, white rot and soft rot: different fungi—different behaviours. Wood Sci Technol 46:919–926. https://doi.org/10.1007/s00226-011-0450-y CrossRef

Papadopoulos A, Hill C (2003) The sorption of water vapour by anhydride modified softwood. Wood Sci Technol 37:221–231CrossRef

Papadopoulos AN, Avramidis S, Elustondo D (2005) The sorption of water vapour by chemically modified softwood: analysis using various sorption models. Wood Sci Technol 39:99–112CrossRef

Popper R, Bariska M (1972) Acylation of wood. 1. Sorption behavior of water vapor. Holz Roh Werkst 30:289–294CrossRef

Popper R, Niemz P, Eberle G (2005) Untersuchungen zum Sorptions- und Quellungsverhalten von thermisch behandeltem Holz (Investigations on the sorption and swelling properties of thermally treated wood). Holz Roh Werkst 63:135–148. https://doi.org/10.1007/s00107-004-0554-2 (in German) CrossRef

Popper R, Niemz P, Torres M (2006) Influence of the extractives of selected extraneous woods on the equilibrium moisture content. Holz Roh Werkst 64:491–496CrossRef

Scott J (2007) Ferroelectrics go bananas. J Phys Condens Matter 20:021001CrossRef

Siau JF (1995) Wood: influence of moisture on physical properties. Department of Wood Science and Forest Products, Virginia Polytechnic Institute and State University, Blacksburg

Simón C, Esteban LG, de Palacios P, Fernández FG, García-Iruela A, Martín-Sampedro R, Eugenio ME (2017) Sorption and thermodynamic properties of wood of Pinus canariensis C. Sm. ex DC. buried in volcanic ash during eruption. Wood Sci Technol 51:517–534. https://doi.org/10.1007/s00226-016-0884-3 CrossRef

Simpson W (1980) Sorption theories applied to wood. Wood Fiber Sci 12:183–195

Skaar C (1988) Wood–water relations. Springer, New YorkCrossRef

Spalt H (1958) The fundamentals of water vapor sorption by wood. For Prod J 8:288–295

Willems W (2015) A critical review of the multilayer sorption models and comparison with the sorption site occupancy (SSO) model for wood moisture sorption isotherm analysis. Holzforschung 69:67–75CrossRef

Xie YJ, Hill CAS, Xiao ZF, Jalaludin Z, Militz H, Mai C (2010) Water vapor sorption kinetics of wood modified with glutaraldehyde. J Appl Polym Sci 117:1674–1682

Yasuda R, Minato K, Norimoto M (1994) Chemical modification of wood by nonformaldehyde cross-linking reagents. 2 Moisture adsorption and creep-properties. Wood Sci Technol 28:209–218CrossRef

Zaihan J, Hill CAS, Curling S, Hashim WS, Hamdan H (2009) Moisture adsorption isotherms of Acacia mangium and Endospermum malaccense using dynamic vapour sorption. J Trop For Sci 21:277–285

Zaihan J, Hill CAS, Hashim WS, Dahlan JM, Sun DY (2011) Analysis of the water vapour sorption isotherms of oil palm trunk and rubberwood. J Trop For Sci 23:97–105

Zelinka SL, Glass SV (2010) Water vapor sorption isotherms for southern pine treated with several waterborne preservatives ASTM. J Test Eval 38:80–88

Titel: Myth versus reality: Do parabolic sorption isotherm models reflect actual wood–water thermodynamics?
verfasst von: Samuel L. Zelinka
Samuel V. Glass
Emil Engelund Thybring
Publikationsdatum: 30.07.2018
Verlag: Springer Berlin Heidelberg
Erschienen in: Wood Science and Technology / Ausgabe 6/2018
Print ISSN: 0043-7719
Elektronische ISSN: 1432-5225
DOI: https://doi.org/10.1007/s00226-018-1035-9

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 6/2018

News from the IAWS

Decrease of the surface pH of maple and the production of nitrate by three pulsed dielectric barrier discharges

How does phosphoric acid interact with cherry stones? A discussion on overlooked aspects of chemical activation

Air-coupled ferroelectret ultrasonic transducers for nondestructive testing of wood-based materials

Wood polymer nanocomposites from functionalized soybean oil and nanoclay

Methodology for comparing wood adhesive bond load transfer using digital volume correlation