Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science
Erschienen in: Journal of Materials Science 27/2020

15.06.2020 | Energy materials

New design of mesoporous SiO2 combined In2O3-graphene semiconductor nanocomposite for highly effective and selective gas detection

verfasst von: Kamrun Nahar Fatema, Suresh Sagadevan, Yin Liu, Kwang Youn Cho, Chong-Hun Jung, Won-Chun Oh

Erschienen in: Journal of Materials Science | Ausgabe 27/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

We successfully prepared multiple gas sensing devices comprising of a thin-film sensor made with mesoporous silica combined In2O3-graphene semiconductor nanocomposite for sensing CO2, O2, and NH3. We demonstrated that our sensor had high selectivity for CO2 by recognizing O2 and NH3 in the vapor stage with accurate transformation into electrical signals in devices. The mesoporous semiconducting In2O3–GO–SiO2-10% (IGS10) sensor showed quick response/recovery times for detecting gases, including CO2, O2, and NH3. Compared to In2O3, In2O3–GO (IG), and In2O3–GO–SiO2-20% (IGS20), the mesoporous IGS10 showed superior gas sensing ability due to the implied optimum ratio of the synthesized sample. Finally, we proved a facile, low-cost route to attain the multiple gas sensing devices with the potential for vast application.
Vorheriger Artikel A flexible organic–inorganic hybrid for medium-temperature proton conduction over a wide humidity range
Nächster Artikel The multi-metal synergetic mechanism of O3-Na0.5Mn0.65Ni0.15Al0.1Mg0.05Co0.05O2 nanoflower for a high-voltage and long-cycle-life cathode material of sodium-ion batteries

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Yan W, Fan H, Yang C (2011) Ultra-fast synthesis and enhanced photocatalytic properties of alpha-Fe2O3/ZnO core-shell structure. Mater Lett 65(11):1595–1597
2.
Jia X, Fan H (2010) Preparation and ethanol sensing properties of the superstructure SnO2/ZnO composite via alcohol-assisted hydrothermal route. Mater Res Bull 45(10):1496–1500
3.
Fan H, Jia X (2011) Selective detection of acetone and gasoline by temperature modulation in zinc oxide nanosheets sensors. Solid State Ionics 192(1):688–692
4.
Xiang Q, Meng GF, Zhao HB, Zhang Y, Li H, Ma WJ, Xu JQ (2010) Au nanoparticle modified WO3 nanorods with their enhanced properties for photocatalysis and gas sensing. J Phys Chem C 114(5):2049–2055
5.
Li P, Cai Y, Fan H (2013) Porous thin sheet-based α-Fe2O3-doped In2O3 structures: hydrothermal synthesis and enhanced Cl2 sensing performance. RSC Adv 3(44):22239–22245
6.
Haffer S, Waitz T, Tiemann M (2010) Mesoporous In2O3 with regular morphology by nanocasting: a simple relation between defined particle shape and growth mechanism. J Phys Chem C 114(5):2075–2081
7.
Chang SC, Huang MH (2008) Formation of short In2O3 nanorod arrays within mesoporous silica. J Phys Chem C 112(7):2304–2307
8.
Zhang Y, Zheng Z, Yang F (2010) Highly sensitive and selective alcohol sensors based on Ag-doped In2O3 coating. Ind Eng Chem Res 49(8):3539–3543
9.
Lin CY, Fang YY, Lin CW, Tunney JJ, Ho KC (2010) Fabrication of NOx gas sensors using In2O3–ZnO composite films. Sens Actuators B Chem 146(1):28–34
10.
Xu JQ, Wang XH, Shen JN (2006) Sens Actuators, B 115:642–646
11.
Zhan Z, Jiang D, Xu J (2005) Investigation of a new In2O3-based selective H2 gas sensor with low power consumption. Mater Chem Phys 90(2–3):250–254
12.
Lou X, Shi D, Liu S, Peng C (2007) Preparation of CdIn2O4 powder by sol–gel method and its Cl2 sensitivity properties. Sens Actuators B Chem 123(1):114–119
13.
Kim SR, Hong HK, Kwon CH, Yun DH, Lee K, Sung YK (2000) Ozone sensing properties of In2O3-based semiconductor thick films. Sens Actuators B Chem 66(1–3):59–62
14.
Ivanovskaya M, Kotsikau D, Faglia G, Nelli P (2003) Influence of chemical composition and structural factors of Fe2O3/In2O3 sensors on their selectivity and sensitivity to ethanol. Sens Actuators B Chem 96(3):498–503
15.
Zhao Y, Zhang Z, Wu Z, Dang H (2004) Synthesis and characterization of single-crystalline In2O3 nanocrystals via solution dispersion. Langmuir 20(1):27–29
16.
Farvid SS, Dave N, Radovanovic PV (2009) Phase-controlled synthesis of colloidal In2O3 nanocrystals via size-structure correlation. Chem Mater 22(1):9–11
17.
Chen C, Chen D, Jiao X, Chen S (2007) In2O3 nanocrystals with a tunable size in the range of 4–10 nm: one-step synthesis, characterization, and optical properties. J Phys Chem C 111(49):18039–18043
18.
Wang G, Park J, Wexler D, Park MS, Ahn JH (2007) Synthesis, characterization, and optical properties of In2O3 semiconductor nanowires. Inorg Chem 46(12):4778–4780
19.
Siciliano T, Tepore A, Micocci G, Genga A, Siciliano M, Filippo E (2011) Formation of In2O3 microrods in thermal treated InSe single crystal. Cryst Growth Des 11(5):1924–1929
20.
Wang F, Xu CQ, He Q, Cai JP, Li XC, Wang D, Xiong X, Liao YH, Zeng QT, Yang YZ, Cheng X (2011) Genome-wide association identifies a susceptibility locus for coronary artery disease in the Chinese Han population. Nat Genet 43(4):345–349
21.
Geim AK, Novoselov KS (2007) The rise of graphene. Nat Mater 6:183–191
22.
Zhu Y, Murali S, Cai W, Li X, Suk JW, Potts JR, Ruoff RS (2010) Graphene and graphene oxide: synthesis, properties, and applications. Adv Mater 22(35):3906–3924
23.
Kim T, Jung G, Yoo S, Suh KS, Ruoff RS (2013) Activated graphene-based carbons as supercapacitor electrodes with macro-and mesopores. ACS Nano 7(8):6899–6905
24.
Kim KS, Zhao Y, Jang H, Lee SY, Kim JM, Kim KS, Ahn JH, Kim P, Choi JY, Hong BH (2009) Large-scale pattern growth of graphene films for stretchable transparent electrodes. Nature 457(7230):706–710
25.
Schedin F, Geim AK, Morozov SV, Hill EW, Blake P, Katsnelson MI, Novoselov KS (2007) Detection of individual gas molecules adsorbed on graphene. Nat Mater 6(9):652–655
26.
St Leger RJ, Nelson JO, Screen SE (1999) The entomopathogenic fungus Metarhizium anisopliae alters ambient pH, allowing extracellular protease production and activity. Microbiology 145(10):2691–2699
27.
Licyayo DCM, Suzuki A, Matsumoto M (2007) Interactions among ammonia fungi on MY agar medium with varying pH. Mycoscience 48(1):20–28
28.
Ong KG, Zeng K, Grimes CA (2002) A wireless, passive carbon nanotube-based gas sensor. IEEE Sens J 2(2):82–88
29.
Jiang Z, Wang J, Meng L, Huang Y, Liu L (2011) A highly efficient chemical sensor material for ethanol: Al2O3/graphene nanocomposites fabricated from graphene oxide. Chem Commun 47(22):6350–6352
30.
Tournier G, Pijolat C (2005) Selective filter for SnO2-based gas sensor: application to hydrogen trace detection. Sens Actuators B Chem 106(2):553–562
31.
Massad-Ivanir N, Shtenberg G, Segal E (2013) Optical detection of E. coli bacteria by mesoporous silicon biosensors. JoVE (J Vis Exp) 81:50805
32.
Ji H, Zeng W, Li Y (2019) Gas sensing mechanisms of metal oxide semiconductors: a focus review. Nanoscale 11(47):22664–22684
33.
Dowla BMRU, Cho JY, Jang WK, Oh WC (2017) Synthesis of BiVO4-G-PTFE nanocomposite photocatalysts for high efficient visible-light-induced photocatalytic performance for dyes. J Mater Sci Mater Electron 28(20):15106–15117
34.
Dowla BMRU, Oh WC (2018) A review on sensing and functional application of graphene-polymer nanocomposite. J Multifunct Mater Photosci 9(1):49–113
35.
Zhang Y, Li S, Zhang J, Pan Z, Min D, Li X, Song X, Liu J (2013) High-performance gas sensors with temperature measurement. Sci Rep 3:1267
36.
Dowla BMRU, Oh WC (2017) An inclusive review of graphene-polymer nanocomposite: research position and developments. J Multifunct Mater Photosci 8(1):1–8
37.
Biswas MRUD, Oh WC (2018) Synthesis of BiVO4-GO-PVDF nanocomposite: an excellent, newly designed material for high photocatalytic activity towards organic dye degradation by tuning band gap energies. Solid State Sci 80:22–30
38.
39.
Li P, Fan H, Cai Y (2013) In2O3/SnO2 heterojunction microstructures: facile room temperature solid-state synthesis and enhanced Cl2 sensing performance. Sens Actuators B Chem 185:110–116
40.
Biswas MRUD, Oh WC (2019) Comparative study on gas sensing by a Schottky diode electrode prepared with graphene–semiconductor–polymer nanocomposites. RSC advances 9(20):11484–11492
41.
Sobon G, Sotor J, Jagiello J, Kozinski R, Zdrojek M, Holdynski M, Paletko P, Boguslawski J, Lipinska L, Abramski KM (2012) Graphene oxide vs. reduced graphene oxide as saturable absorbers for Er-doped passively mode-locked fiber laser. Opt Express 20(17):19463–19473
42.
Tauc J, Grigorovici R, Vancu A (1966) Optical properties and electronic structure of amorphous germanium. Phys Status Solidi (B) 15(2):627–637
43.
Li X, Li J, Zhou X, Ma Y, Zheng Z, Duan X, Qu Y (2014) Silver nanoparticles protected by monolayer graphene as a stabilized substrate for surface enhanced Raman spectroscopy. Carbon 66:713–719
44.
Poznyak SK, Golubev AN, Kulak AI (2000) Correlation between surface properties and photocatalytic and photoelectrochemical activity of In2O3 nanocrystalline films and powders. Surf Sci 454:396–401
45.
Kim J, Cote LJ, Huang J (2012) Two dimensional soft material: new faces of graphene oxide. Acc Chem Res 45(8):1356–1364
46.
Niu Z, Liu L, Zhang L, Shao Q, Zhou W, Chen X, Xie S (2014) A universal strategy to prepare functional porous graphene hybrid architectures. Adv Mater 26(22):3681–3687
47.
Guan Q, Cheng J, Wang B, Ni W, Gu G, Li X, Huang L, Yang G, Nie F (2014) Needle-like Co3O4 anchored on the graphene with enhanced electrochemical performance for aqueous supercapacitors. ACS Appl Mater Interfaces 6(10):7626–7632
48.
Shanmugasundaram A, Ramireddy B, Basak P, Manorama SV, Srinath S (2014) Hierarchical In(OH)3 as a precursor to mesoporous In2O3 nanocubes: a facile synthesis route, mechanism of self-assembly, and enhanced sensing response toward hydrogen. J Phys Chem C 118(13):6909–6921
49.
Zhu H, Wang X, Yang F, Yang X (2008) Template-free, surfactantless route to fabricate In(OH)3 monocrystalline nanoarchitectures and their conversion to In2O3. Cryst Growth Des 8(3):950–956
50.
Tricoli A, Righettoni M, Teleki A (2010) Semiconductor gas sensors: dry synthesis and application. Angew Chem Int Ed 49(42):7632–7659
51.
Huang J, Xu X, Gu C, Yang M, Yang M, Liu J (2011) Large-scale synthesis of hydrated tungsten oxide 3D architectures by a simple chemical solution route and their gas-sensing properties. J Mater Chem 21(35):13283–13289
52.
Darbandi M, Thomann R, Nann T (2005) Single quantum dots in silica spheres by microemulsion synthesis. Chem Mater 17(23):5720–5725
53.
Darbandi M, Lu W, Fang J, Nann T (2006) Silica encapsulation of hydrophobically ligated PbSe nanocrystals. Langmuir 22(9):4371–4375
54.
Mokari T, Sertchook H, Aharoni A, Ebenstein Y, Avnir D, Banin U (2005) Nano@ micro: general method for entrapment of nanocrystals in sol–gel-derived composite hydrophobic silica spheres. Chem Mater 17(2):258–263
55.
Yang S, Feng X, Wang L, Tang K, Maier J, Müllen K (2010) Graphene-based nanosheets with a sandwich structure. Angew Chem Int Ed 49(28):4795–4799
56.
Wang X, Li Y, Li Z, Zhang S, Deng X, Zhao G, Xu X (2019) Highly sensitive and low working temperature detection of trace triethylamine based on TiO2 nanoparticles decorated CuO nanosheets sensors. Sens Actuators B Chem 301:127019
57.
Wang X, Wang T, Si G, Li Y, Zhang S, Deng X, Xu X (2020) Oxygen vacancy defects engineering on Ce-doped α-Fe2O3 gas sensor for reducing gases. Sens Actuators B Chem 302:127165
58.
Wang X, Zhang S, Shao M, Huang J, Deng X, Hou P, Xu X (2017) Fabrication of ZnO/ZnFe2O4 hollow nanocages through metal organic frameworks route with enhanced gas sensing properties. Sens Actuators B Chem 251:27–33
59.
Shankar P, Rayappan JBB (2015) Gas sensing mechanism of metal oxides: the role of ambient atmosphere, type of semiconductor and gases: a review. Sci Lett J 4(4):126
Metadaten
Titel
New design of mesoporous SiO2 combined In2O3-graphene semiconductor nanocomposite for highly effective and selective gas detection
verfasst von
Kamrun Nahar Fatema
Suresh Sagadevan
Yin Liu
Kwang Youn Cho
Chong-Hun Jung
Won-Chun Oh
Publikationsdatum
15.06.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 27/2020
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-04928-5

Weitere Artikel der Ausgabe 27/2020

Journal of Materials Science 27/2020 Zur Ausgabe

Chemical routes to materials

Preparation and optimization of biomimetic materials simulating solar spectrum reflection characteristics of natural leaves

Energy materials

The multi-metal synergetic mechanism of O3-Na0.5Mn0.65Ni0.15Al0.1Mg0.05Co0.05O2 nanoflower for a high-voltage and long-cycle-life cathode material of sodium-ion batteries

Composites & nanocomposites

In situ TEM oxidation study of Fe thin-film transformation to single-crystal magnetite nanoparticles

Ceramics

In situ synthesis of melt-grown mullite ceramics using directed laser deposition

Metals & corrosion

Monte Carlo simulation of grain refinement during friction stir processing

Chemical routes to materials

Effect of support morphology on the activity and reusability of Pd/SiO2 for NBR hydrogenation

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise