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17.02.2018

New hybrid composite honeycomb monolith with 13X zeolite and activated carbon for CO₂ capture

verfasst von: Maria João Regufe, Alexandre F. P. Ferreira, José Miguel Loureiro, Yixiang Shi, Alírio Rodrigues, Ana Mafalda Ribeiro

Erschienen in: Adsorption | Ausgabe 3/2018

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Abstract

Due to the industrialization, it is urgent to reduce the carbon dioxide emissions. For that, diverse technologies can be applied. In adsorption processes, the development of new materials is an emerging challenge in order to increase the CO₂ adsorption capacity of materials and the efficiency of the processes. In this work, a new hybrid honeycomb monolith composed by zeolite and activated carbon was produced by extrusion process. Single adsorption equilibrium isotherms of carbon dioxide and nitrogen were measured by a gravimetric method using a Rubotherm® magnetic suspension balance at three temperatures, 303, 333 and 373 K. The experimental points were well described by Dual-Site Langmuir model. The material presented a carbon dioxide adsorption capacity of 2.63 mol kg⁻¹ at 1 bar and 303 K. Binary breakthrough curves were obtained at 298 K and 2.4 bar with different feed mixtures. The experimental results of adsorption equilibrium were validated with the Dual-Site Langmuir isotherm extended to multicomponent mixtures. A mathematical model was applied to predict the dynamic behaviour of the adsorption bed.

Vorheriger Artikel Chloride adsorption on Fe- and Al-(hydr)oxide: estimation of Gibbs free energies

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Titel: New hybrid composite honeycomb monolith with 13X zeolite and activated carbon for CO2 capture
verfasst von: Maria João Regufe
Alexandre F. P. Ferreira
José Miguel Loureiro
Yixiang Shi
Alírio Rodrigues
Ana Mafalda Ribeiro
Publikationsdatum: 17.02.2018
Verlag: Springer US
Erschienen in: Adsorption / Ausgabe 3/2018
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI: https://doi.org/10.1007/s10450-018-9938-1

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